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Preparation of surfactant-free vinyl polymers by conventional emulsion polymerization using hydrolysable emulsifiers
http://hdl.handle.net/10091/16181
http://hdl.handle.net/10091/16181a1b924fe-ac9e-45df-aece-a5fd419796b8
| 名前 / ファイル | ライセンス | アクション |
|---|---|---|
Preparation_surfactant-free_vinyl_polymers_conventional.pdf (117.0 kB)
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| Item type | 学術雑誌論文 / Journal Article(1) | |||||
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| 公開日 | 2013-01-15 | |||||
| タイトル | ||||||
| タイトル | Preparation of surfactant-free vinyl polymers by conventional emulsion polymerization using hydrolysable emulsifiers | |||||
| 言語 | ||||||
| 言語 | eng | |||||
| DOI | ||||||
| 関連識別子 | https://doi.org/10.1007/s00289-011-0462-7 | |||||
| 関連名称 | 10.1007/s00289-011-0462-7 | |||||
| キーワード | ||||||
| 主題 | Emulsion polymerization, Latices, Cleavable surfactant, Hydrolysis, Betaine ester | |||||
| 資源タイプ | ||||||
| 資源タイプ識別子 | http://purl.org/coar/resource_type/c_6501 | |||||
| 資源タイプ | journal article | |||||
| 著者 |
Itoh, Yoshihiro
× Itoh, Yoshihiro× Sahara, Fumiya× Ozaki, Kaori× Akasaka, Ryo× Teramoto, Akira |
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| 信州大学研究者総覧へのリンク | ||||||
| 表示名 | Itoh, Yoshihiro | |||||
| URL | http://soar-rd.shinshu-u.ac.jp/profile/ja.yeLmjekV.html | |||||
| 信州大学研究者総覧へのリンク | ||||||
| 表示名 | Teramoto, Akira | |||||
| URL | http://soar-rd.shinshu-u.ac.jp/profile/ja.OecUjekV.html | |||||
| 出版者 | ||||||
| 出版者 | SPRINGER | |||||
| 引用 | ||||||
| 内容記述タイプ | Other | |||||
| 内容記述 | POLYMER BULLETIN. 67(8):1455-1462 (2011) | |||||
| 書誌情報 |
POLYMER BULLETIN 巻 67, 号 8, p. 1455-1462, 発行日 2011-11 |
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| 抄録 | ||||||
| 内容記述タイプ | Abstract | |||||
| 内容記述 | Emulsion polymerizations of several vinyl monomers, styrene, methyl methacrylate, butyl methacrylate, butyl acrylate, and vinyl acetate, in water using alkali-hydrolysable cationic surfactants with a betaine ester group (1-alkoxycarbonylmethyl)trimethylammonium chlorides, as emulsifiers were carried out and properties of the resulting latices and the polymers recovered by hydrolysis and salting out were investigated. There were little influences of the surfactants and monomers used here on the polymerizations, forming stable and monodisperse latices with a mean diameter of ca. 70 nm and giving a high molecular weight of polymers at high yields. All polymers were precipitated and recovered by adding a small amount of sodium hydroxide into the latex solutions contained little amount of ionic species. Solvent-cast films of the polymers were found to have surfaces as hydrophobic as those for the corresponding pure polymers prepared by bulk polymerization. | |||||
| 資源タイプ（コンテンツの種類） | ||||||
| 内容記述タイプ | Other | |||||
| 内容記述 | Article | |||||
| ISSN | ||||||
| 収録物識別子タイプ | ISSN | |||||
| 収録物識別子 | 0170-0839 | |||||
| 書誌レコードID | ||||||
| 収録物識別子タイプ | NCID | |||||
| 収録物識別子 | AA00362798 | |||||
| 権利 | ||||||
| 権利情報 | The original publication is available at www.springerlink.com | |||||
| 出版タイプ | ||||||
| 出版タイプ | AM | |||||
| 出版タイプResource | http://purl.org/coar/version/c_ab4af688f83e57aa | |||||
| WoS | ||||||
| 表示名 | Web of Science | |||||
| URL | http://gateway.isiknowledge.com/gateway/Gateway.cgi?&GWVersion=2&SrcAuth=ShinshuUniv&SrcApp=ShinshuUniv&DestLinkType=FullRecord&DestApp=WOS&KeyUT=000296005700005 | |||||
