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While all ethylenes and ethenes gave the solutions containing both E- and Z-isomers in the manner of the mutual photoisomerization, the ethylenes having at least one hydrogen atom on the sp(2) carbons underwent unidirectional photoisomerization from the Z-isomers to the E-isomers in the solid-state even at low temperature. On the other hand, both the E- and Z-ethenes having no hydrogen atom on the double bonds did not change when irradiated in the solid-state even at room temperature. These different photochemical behaviors can be explained by the Hula-twist (HT) mechanism in such confined environments. (c) 2006 Elsevier B.V. All rights reserved."}]}, "item_creator": {"attribute_name": "著者", "attribute_type": "creator", "attribute_value_mlt": [{"creatorNames": [{"creatorName": "Zhu, FQ"}], "nameIdentifiers": [{"nameIdentifier": "41441", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Motoyoshiya, J"}], "nameIdentifiers": [{"nameIdentifier": "41442", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Nishii, Y"}], "nameIdentifiers": [{"nameIdentifier": "41443", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Aoyama, H"}], "nameIdentifiers": [{"nameIdentifier": "41444", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Kakehi, A"}], "nameIdentifiers": [{"nameIdentifier": "41445", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Shiro, M"}], "nameIdentifiers": [{"nameIdentifier": "41446", "nameIdentifierScheme": "WEKO"}]}]}, "item_files": {"attribute_name": "ファイル情報", "attribute_type": "file", "attribute_value_mlt": [{"accessrole": "open_date", "date": [{"dateType": "Available", "dateValue": "2015-09-28"}], "displaytype": "detail", "download_preview_message": "", "file_order": 0, "filename": "J.Photobiol.Photochem, 2006.pdf", "filesize": [{"value": "291.9 kB"}], "format": "application/pdf", "future_date_message": "", "is_thumbnail": false, "licensetype": "license_note", "mimetype": "application/pdf", "size": 291900.0, "url": {"label": "J.Photobiol.Photochem, 2006.pdf", "url": "https://soar-ir.repo.nii.ac.jp/record/13547/files/J.Photobiol.Photochem, 2006.pdf"}, "version_id": "f191c60b-e922-4a0c-b1d7-51529fd3dd2f"}]}, "item_language": {"attribute_name": "言語", "attribute_value_mlt": [{"subitem_language": "eng"}]}, "item_resource_type": {"attribute_name": "資源タイプ", "attribute_value_mlt": [{"resourcetype": "journal article", "resourceuri": "http://purl.org/coar/resource_type/c_6501"}]}, "item_title": "Different photochemical behavior of bis(biphenyl)ethylenes and ethenes in solution and in the solid-state: Structurally controlled Z/E-photoisomerization in the solid-state", "item_titles": {"attribute_name": "タイトル", "attribute_value_mlt": [{"subitem_title": "Different photochemical behavior of bis(biphenyl)ethylenes and ethenes in solution and in the solid-state: Structurally controlled Z/E-photoisomerization in the solid-state", "subitem_title_language": "en"}]}, "item_type_id": "6", "owner": "1", "path": ["1310"], "permalink_uri": "http://hdl.handle.net/10091/612", "pubdate": {"attribute_name": "PubDate", "attribute_value": "2007-11-21"}, "publish_date": "2007-11-21", "publish_status": "0", "recid": "13547", "relation": {}, "relation_version_is_last": true, "title": ["Different photochemical behavior of bis(biphenyl)ethylenes and ethenes in solution and in the solid-state: Structurally controlled Z/E-photoisomerization in the solid-state"], "weko_shared_id": -1}
Different photochemical behavior of bis(biphenyl)ethylenes and ethenes in solution and in the solid-state: Structurally controlled Z/E-photoisomerization in the solid-state
http://hdl.handle.net/10091/612
http://hdl.handle.net/10091/612160190c7-a102-4dba-9ee2-305779d8808a
名前 / ファイル | ライセンス | アクション |
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J.Photobiol.Photochem, 2006.pdf (291.9 kB)
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Item type | 学術雑誌論文 / Journal Article(1) | |||||
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公開日 | 2007-11-21 | |||||
タイトル | ||||||
言語 | en | |||||
タイトル | Different photochemical behavior of bis(biphenyl)ethylenes and ethenes in solution and in the solid-state: Structurally controlled Z/E-photoisomerization in the solid-state | |||||
言語 | ||||||
言語 | eng | |||||
DOI | ||||||
識別子タイプ | DOI | |||||
関連識別子 | https://doi.org/10.1016/j.jphotochem.2006.03.022 | |||||
関連名称 | 10.1016/j.jphotochem.2006.03.022 | |||||
資源タイプ | ||||||
資源 | http://purl.org/coar/resource_type/c_6501 | |||||
タイプ | journal article | |||||
著者 |
Zhu, FQ
× Zhu, FQ× Motoyoshiya, J× Nishii, Y× Aoyama, H× Kakehi, A× Shiro, M |
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信州大学研究者総覧へのリンク | ||||||
氏名 | Motoyoshiya, J | |||||
URL | http://soar-rd.shinshu-u.ac.jp/profile/ja.WeymjekV.html | |||||
信州大学研究者総覧へのリンク | ||||||
氏名 | Nishii, Y | |||||
URL | http://soar-rd.shinshu-u.ac.jp/profile/ja.yeSUjFkV.html | |||||
出版者 | ||||||
出版者 | ELSEVIER SCIENCE SA | |||||
引用 | ||||||
内容記述タイプ | Other | |||||
内容記述 | JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY A-CHEMISTRY. 184(1-2): 44-49 (2006) | |||||
書誌情報 |
JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY A-CHEMISTRY 巻 184, 号 1-2, p. 44-49, 発行日 2006-11-15 |
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資源タイプ(コンテンツの種類) | ||||||
内容記述タイプ | Other | |||||
内容記述 | Article | |||||
ISSN | ||||||
収録物識別子タイプ | ISSN | |||||
収録物識別子 | 1010-6030 | |||||
書誌レコードID | ||||||
収録物識別子タイプ | NCID | |||||
収録物識別子 | AA10684407 | |||||
出版タイプ | ||||||
出版タイプ | AM | |||||
出版タイプResource | http://purl.org/coar/version/c_ab4af688f83e57aa | |||||
WoS | ||||||
表示名 | Web of Science | |||||
URL | http://gateway.isiknowledge.com/gateway/Gateway.cgi?&GWVersion=2&SrcAuth=ShinshuUniv&SrcApp=ShinshuUniv&DestLinkType=FullRecord&DestApp=WOS&KeyUT=000243145200005 |