{"_buckets": {"deposit": "793b79f4-8fce-4080-a8a6-74bc832119a8"}, "_deposit": {"id": "14621", "owners": [], "pid": {"revision_id": 0, "type": "depid", "value": "14621"}, "status": "published"}, "_oai": {"id": "oai:soar-ir.repo.nii.ac.jp:00014621", "sets": ["1462"]}, "author_link": ["44008"], "item_11_alternative_title_1": {"attribute_name": "その他（別言語等）のタイトル", "attribute_value_mlt": [{"subitem_alternative_title": "光･電気応答性巨大分子の研究"}]}, "item_11_biblio_info_6": {"attribute_name": "書誌情報", "attribute_value_mlt": [{"bibliographicIssueDates": {"bibliographicIssueDate": "2004-03-31", "bibliographicIssueDateType": "Issued"}, "bibliographicPageEnd": "105", "bibliographicPageStart": "104", "bibliographicVolumeNumber": "10", "bibliographic_titles": [{"bibliographic_title": "先進ファイバー工学研究教育拠点研究成果報告書"}]}]}, "item_11_description_20": {"attribute_name": "抄録", "attribute_value_mlt": [{"subitem_description": "Fullerenes and carbon nanotubes are allotropes consisting of a large number of carbon atoms. Because of their extended conjugations of the 1r-electron, their applications to the functional materials are expected. Optical and electronic properties of molecules strongly reflect natures of molecular electronic states, in general. In this work, electronic states of some kinds of fullerenes and nonotubes are theoretically analyzed and their optical and electronic properties are examined. For the tube-like fullerenes C60+10n, several groups theoretically showed that their HOMO-LUMO gaps periodically vary. Moreover, we also showed that the π-conjugations are regularly localized at the central cylindrical parts of the tubes and concluded that the periodicity originates in the localizations. Making CNDO/S-SECI calculations on the C60+10n molecules, we have obtained their ground and excited states and simulated the absorption spectra. In each spectrum, we see the weak longest edge and the prominent peak with a large oscillator strength value. Both positions of the longest edge and of the prominent peak move periodically. These periodicities are similar to the periodicity of the HOMO-LUMO gaps. Analyzing the CNDO/S-SECI data, it is shown that two electronic excited states corresponding to the longest edge and the prominent state are described by the linear combinations of two singly-excited configurations which the HOMO and LUMO participate in. It is also shown that the intensity of the prominent peak almost linearly increases with the tube length. Study on other types of nanotubes is in progress.", "subitem_description_type": "Abstract"}]}, "item_11_description_30": {"attribute_name": "資源タイプ（コンテンツの種類）", "attribute_value_mlt": [{"subitem_description": "Article", "subitem_description_type": "Other"}]}, "item_11_description_5": {"attribute_name": "引用", "attribute_value_mlt": [{"subitem_description": "先進ファイバー工学研究教育拠点研究成果報告書 10: 104-105(2004)", "subitem_description_type": "Other"}]}, "item_11_link_3": {"attribute_name": "信州大学研究者総覧へのリンク", "attribute_value_mlt": [{"subitem_link_text": "野村, 泰志", "subitem_link_url": "http://soar-rd.shinshu-u.ac.jp/profile/ja.OVcmjekV.html"}]}, "item_11_publisher_4": {"attribute_name": "出版者", "attribute_value_mlt": [{"subitem_publisher": "信州大学繊維学部"}]}, "item_11_select_64": {"attribute_name": "著者版フラグ", "attribute_value_mlt": [{"subitem_select_item": "publisher"}]}, "item_11_source_id_40": {"attribute_name": "書誌レコードID", "attribute_value_mlt": [{"subitem_source_identifier": "AA1200368X", "subitem_source_identifier_type": "NCID"}]}, "item_11_text_66": {"attribute_name": "sortkey", "attribute_value_mlt": [{"subitem_text_value": "059"}]}, "item_1627890728808": {"attribute_name": "出版タイプ", "attribute_value_mlt": [{"subitem_version_resource": "http://purl.org/coar/version/c_970fb48d4fbd8a85", "subitem_version_type": "VoR"}]}, "item_creator": {"attribute_name": "著者", "attribute_type": "creator", "attribute_value_mlt": [{"creatorNames": [{"creatorName": "野村,  泰志"}], "nameIdentifiers": [{"nameIdentifier": "44008", "nameIdentifierScheme": "WEKO"}]}]}, "item_files": {"attribute_name": "ファイル情報", "attribute_type": "file", "attribute_value_mlt": [{"accessrole": "open_date", "date": [{"dateType": "Available", "dateValue": "2015-09-28"}], "displaytype": "detail", "download_preview_message": "", "file_order": 0, "filename": "AFSTT10-406.pdf", "filesize": [{"value": "816.5 kB"}], "format": "application/pdf", "future_date_message": "", "is_thumbnail": false, "licensetype": "license_note", "mimetype": "application/pdf", "size": 816500.0, "url": {"label": "AFSTT10-406.pdf", "url": "https://soar-ir.repo.nii.ac.jp/record/14621/files/AFSTT10-406.pdf"}, "version_id": "10eb957a-5522-4f48-bbe9-104a63187f06"}]}, "item_language": {"attribute_name": "言語", "attribute_value_mlt": [{"subitem_language": "jpn"}]}, "item_resource_type": {"attribute_name": "資源タイプ", "attribute_value_mlt": [{"resourcetype": "research report", "resourceuri": "http://purl.org/coar/resource_type/c_18ws"}]}, "item_title": "15-4-6 :光学的および電気的諸機能を持つ巨大分子の分子設計", "item_titles": {"attribute_name": "タイトル", "attribute_value_mlt": [{"subitem_title": "15-4-6 :光学的および電気的諸機能を持つ巨大分子の分子設計", "subitem_title_language": "ja"}]}, "item_type_id": "11", "owner": "1", "path": ["1462"], "permalink_uri": "http://hdl.handle.net/10091/13541", "pubdate": {"attribute_name": "PubDate", "attribute_value": "2012-02-23"}, "publish_date": "2012-02-23", "publish_status": "0", "recid": "14621", "relation": {}, "relation_version_is_last": true, "title": ["15-4-6 :光学的および電気的諸機能を持つ巨大分子の分子設計"], "weko_shared_id": -1}