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Conducting linear chains of sulphur inside carbon nanotubes
http://hdl.handle.net/10091/17561
http://hdl.handle.net/10091/175615b1774a5-0ec4-440e-a074-ce2826adbe07
名前 / ファイル | ライセンス | アクション |
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Conducting_linear_chains_sulphur_inside_carbon_nanotubes.pdf (2.1 MB)
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Item type | 学術雑誌論文 / Journal Article(1) | |||||
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公開日 | 2014-06-02 | |||||
タイトル | ||||||
言語 | en | |||||
タイトル | Conducting linear chains of sulphur inside carbon nanotubes | |||||
言語 | ||||||
言語 | eng | |||||
DOI | ||||||
識別子タイプ | DOI | |||||
関連識別子 | https://doi.org/10.1038/ncomms3162 | |||||
関連名称 | 10.1038/ncomms3162 | |||||
資源タイプ | ||||||
資源 | http://purl.org/coar/resource_type/c_6501 | |||||
タイプ | journal article | |||||
著者 |
Fujimori, Toshihiko
× Fujimori, Toshihiko× Morelos-Gomez, Aaron× Zhu, Zhen× Muramatsu, Hiroyuki× Futamura, Ryusuke× Urita, Koki× Terrones, Mauricio× Hayashi, Takuya× Endo, Morinobu× Hong, Sang Young× Choi, Young Chul× Tomanek, David× Kaneko, Katsumi |
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信州大学研究者総覧へのリンク | ||||||
氏名 | Hayashi, Takuya | |||||
URL | http://soar-rd.shinshu-u.ac.jp/profile/ja.jmLUbpkh.html | |||||
信州大学研究者総覧へのリンク | ||||||
氏名 | Endo, Morinobu | |||||
URL | http://soar-rd.shinshu-u.ac.jp/profile/ja.uUTmZhkh.html | |||||
信州大学研究者総覧へのリンク | ||||||
氏名 | Kaneko, Katsumi | |||||
URL | http://soar-rd.shinshu-u.ac.jp/profile/ja.HafNZVyC.html | |||||
出版者 | ||||||
出版者 | NATURE PUBLISHING GROUP | |||||
引用 | ||||||
内容記述タイプ | Other | |||||
内容記述 | NATURE COMMUNICATIONS. 4:2162 (2013) | |||||
書誌情報 |
NATURE COMMUNICATIONS 巻 4, p. 2162, 発行日 2013-07 |
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抄録 | ||||||
内容記述タイプ | Abstract | |||||
内容記述 | Despite extensive research for more than 200 years, the experimental isolation of monatomic sulphur chains, which are believed to exhibit a conducting character, has eluded scientists. Here we report the synthesis of a previously unobserved composite material of elemental sulphur, consisting of monatomic chains stabilized in the constraining volume of a carbon nanotube. This one-dimensional phase is confirmed by high-resolution transmission electron microscopy and synchrotron X-ray diffraction. Interestingly, these one-dimensional sulphur chains exhibit long domain sizes of up to 160 nm and high thermal stability (similar to 800 K). Synchrotron X-ray diffraction shows a sharp structural transition of the one-dimensional sulphur occurring at similar to 450-650 K. Our observations, and corresponding electronic structure and quantum transport calculations, indicate the conducting character of the one-dimensional sulphur chains under ambient pressure. This is in stark contrast to bulk sulphur that needs ultrahigh pressures exceeding similar to 90 GPa to become metallic. | |||||
資源タイプ(コンテンツの種類) | ||||||
内容記述タイプ | Other | |||||
内容記述 | Article | |||||
ISSN | ||||||
収録物識別子タイプ | EISSN | |||||
収録物識別子 | 2041-1723 | |||||
書誌レコードID | ||||||
収録物識別子タイプ | NCID | |||||
収録物識別子 | AA12645905 | |||||
PubMed | ||||||
識別子タイプ | PMID | |||||
関連識別子 | https://pubmed.ncbi.nlm.nih.gov/23851903/ | |||||
関連名称 | 23851903 | |||||
出版タイプ | ||||||
出版タイプ | VoR | |||||
出版タイプResource | http://purl.org/coar/version/c_970fb48d4fbd8a85 | |||||
WoS | ||||||
表示名 | Web of Science | |||||
URL | http://gateway.isiknowledge.com/gateway/Gateway.cgi?&GWVersion=2&SrcAuth=ShinshuUniv&SrcApp=ShinshuUniv&DestLinkType=FullRecord&DestApp=WOS&KeyUT=000323716300032 |