{"_buckets": {"deposit": "a78fb72c-44b5-4849-b1de-0beef62f20fd"}, "_deposit": {"id": "17448", "owners": [], "pid": {"revision_id": 0, "type": "depid", "value": "17448"}, "status": "published"}, "_oai": {"id": "oai:soar-ir.repo.nii.ac.jp:00017448", "sets": []}, "author_link": ["49314"], "item_10_biblio_info_6": {"attribute_name": "書誌情報", "attribute_value_mlt": [{"bibliographicIssueDates": {"bibliographicIssueDate": "1992-03-15", "bibliographicIssueDateType": "Issued"}, "bibliographicPageEnd": "162", "bibliographicPageStart": "157", "bibliographicVolumeNumber": "26", "bibliographic_titles": [{"bibliographic_title": "信州大学教養部紀要."}]}]}, "item_10_description_20": {"attribute_name": "抄録", "attribute_value_mlt": [{"subitem_description": "The second-order rate constants for the base-catalysed reactions of methanol with 3-methoxy- and 3-methylthio-acrylophenones (MeOAcr and MeSAcr) have been determined in methanol and in methanol-OD at 25℃. Non-catalytic terms were not detected. Inverse kinetic solvent isotope effects on attack of methoxide ion on MeOAcr and MeSAcr of 0.62 and 0.57, respectively, are compared with earlier data for attack of methoxide ion on a substituted N -benzylideneaniline. The rate constants depend on electrophiles, but the solvent isotope effects, ca. 0.6, are fairly constant, irrespective of the 10⁴ fold variance of the rate constants. The results are discussed in terms of solvent reorganisation. The solvent isotope effect for the reaction of hydroxide ion in water was also determined.", "subitem_description_type": "Abstract"}]}, "item_10_description_30": {"attribute_name": "資源タイプ（コンテンツの種類）", "attribute_value_mlt": [{"subitem_description": "Article", "subitem_description_type": "Other"}]}, "item_10_description_31": {"attribute_name": "フォーマット：mimeタイプ", "attribute_value_mlt": [{"subitem_description": "application/pdf", "subitem_description_type": "Other"}]}, "item_10_description_5": {"attribute_name": "引用", "attribute_value_mlt": [{"subitem_description": "信州大学教養部紀要. 26: 157-162(1992)", "subitem_description_type": "Other"}]}, "item_10_publisher_4": {"attribute_name": "出版者", "attribute_value_mlt": [{"subitem_publisher": "信州大学教養部"}]}, "item_10_select_64": {"attribute_name": "著者版フラグ", "attribute_value_mlt": [{"subitem_select_item": "publisher"}]}, "item_10_source_id_35": {"attribute_name": "ISSN", "attribute_value_mlt": [{"subitem_source_identifier": "1340-9972", "subitem_source_identifier_type": "ISSN"}]}, "item_10_source_id_39": {"attribute_name": "NII ISSN", "attribute_value_mlt": [{"subitem_source_identifier": "1340-9972", "subitem_source_identifier_type": "ISSN"}]}, "item_10_source_id_40": {"attribute_name": "書誌レコードID", "attribute_value_mlt": [{"subitem_source_identifier": "AN10176022", "subitem_source_identifier_type": "NCID"}]}, "item_10_text_66": {"attribute_name": "sortkey", "attribute_value_mlt": [{"subitem_text_value": "11"}]}, "item_1627890569677": {"attribute_name": "出版タイプ", "attribute_value_mlt": [{"subitem_version_resource": "http://purl.org/coar/version/c_970fb48d4fbd8a85", "subitem_version_type": "VoR"}]}, "item_creator": {"attribute_name": "著者", "attribute_type": "creator", "attribute_value_mlt": [{"creatorNames": [{"creatorName": "KAWASAKI,  Atsushi", "creatorNameLang": "en"}], "nameIdentifiers": [{"nameIdentifier": "49314", "nameIdentifierScheme": "WEKO"}]}]}, "item_files": {"attribute_name": "ファイル情報", "attribute_type": "file", "attribute_value_mlt": [{"accessrole": "open_date", "date": [{"dateType": "Available", "dateValue": "2015-09-28"}], "displaytype": "detail", "download_preview_message": "", "file_order": 0, "filename": "Liberal_arts26-11.pdf", "filesize": [{"value": "320.7 kB"}], "format": "application/pdf", "future_date_message": "", "is_thumbnail": false, "licensetype": "license_note", "mimetype": "application/pdf", "size": 320700.0, "url": {"label": "Liberal_arts26-11.pdf", "url": "https://soar-ir.repo.nii.ac.jp/record/17448/files/Liberal_arts26-11.pdf"}, "version_id": "75ab3108-e561-4b1f-845d-36d7906d6fad"}]}, "item_language": {"attribute_name": "言語", "attribute_value_mlt": [{"subitem_language": "eng"}]}, "item_resource_type": {"attribute_name": "資源タイプ", "attribute_value_mlt": [{"resourcetype": "departmental bulletin paper", "resourceuri": "http://purl.org/coar/resource_type/c_6501"}]}, "item_title": "SOLVENT ISOTOPE EFFECT ON NUCLEOPHILIC ATTACK OF METHOXIDE ION ON sp² CARBON ATOM OF trans-3- METHOXY OR trans-3- METHYLTHIO-ACRYLOPHENONES", "item_titles": {"attribute_name": "タイトル", "attribute_value_mlt": [{"subitem_title": "SOLVENT ISOTOPE EFFECT ON NUCLEOPHILIC ATTACK OF METHOXIDE ION ON sp² CARBON ATOM OF trans-3- METHOXY OR trans-3- METHYLTHIO-ACRYLOPHENONES", "subitem_title_language": "en"}]}, "item_type_id": "10", "owner": "1", "path": ["1707"], "permalink_uri": "http://hdl.handle.net/10091/4463", "pubdate": {"attribute_name": "PubDate", "attribute_value": "2010-02-12"}, "publish_date": "2010-02-12", "publish_status": "0", "recid": "17448", "relation": {}, "relation_version_is_last": true, "title": ["SOLVENT ISOTOPE EFFECT ON NUCLEOPHILIC ATTACK OF METHOXIDE ION ON sp² CARBON ATOM OF trans-3- METHOXY OR trans-3- METHYLTHIO-ACRYLOPHENONES"], "weko_shared_id": -1}