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  1. 060 工学部
  2. 0601 学術論文

Crystal architectures of a layered silicate on monodisperse spherical silica particles cause the topochemical expansion of the core-shell particles

http://hdl.handle.net/10091/00018611
http://hdl.handle.net/10091/00018611
cc87ace3-b1ef-4810-8925-eb0985e2f864
名前 / ファイル ライセンス アクション
Crystal_architectures_layered_silicate.pdf Crystal_architectures_layered_silicate.pdf (3.5 MB)
Item type 学術雑誌論文 / Journal Article(1)
公開日 2016-02-03
タイトル
タイトル Crystal architectures of a layered silicate on monodisperse spherical silica particles cause the topochemical expansion of the core-shell particles
言語
言語 eng
DOI
関連識別子 https://doi.org/10.1016/j.micromeso.2015.05.018
関連名称 10.1016/j.micromeso.2015.05.018
キーワード
主題 Colloidal silica, Layered silicate, Cation exchange, Layer charge density, Hierarchical hybridization
資源タイプ
資源 http://purl.org/coar/resource_type/c_6501
タイプ journal article
著者 Okada, Tomohiko

× Okada, Tomohiko

Okada, Tomohiko

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Suzuki, Asuka

× Suzuki, Asuka

Suzuki, Asuka

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Yoshido, Shiho

× Yoshido, Shiho

Yoshido, Shiho

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Minamisawa, Hikari M.

× Minamisawa, Hikari M.

Minamisawa, Hikari M.

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信州大学研究者総覧へのリンク
氏名 Okada, Tomohiko
URL http://soar-rd.shinshu-u.ac.jp/profile/ja.WpDFbpkh.html
出版者
出版者 ELSEVIER SCIENCE BV
引用
内容記述 MICROPOROUS AND MESOPOROUS MATERIALS. 215:168-174 (2015)
書誌情報 MICROPOROUS AND MESOPOROUS MATERIALS

巻 215, p. 168-174, 発行日 2015-10-01
抄録
内容記述 Anisotropic structural changes in an expandable layered silicate (directed towards the c-axis) occurring on isotropic and monodisperse microspheres were detected by measurable increases in the grain size. The hierarchical changes were observed through pursing the sophisticated growth of expandable layered silicate crystals on monodisperse spherical silica particles with diameters of 1.0 mu m; the core-shell hybrids with a quite uniform grain size were successfully produced using a rotating Teflon-lined autoclave by reacting spherical silica particles in a colloidal suspension with lithium and magnesium ions under alkaline conditions at 373 K. The size distribution of the core-shell particles tended to be uniform when the amount of lithium ions in the initial mixture decreased. The intercalation of dioctadecyldimethylammonium ions into the small crystals through cation-exchange reactions expanded the interlayer space, topochemically increasing the grain size without any change occurring in the shapes of the core-shell particles. (C) 2015 Elsevier Inc. All rights reserved.
資源タイプ(コンテンツの種類)
ISSN
収録物識別子タイプ ISSN
収録物識別子 1387-1811
書誌レコードID
収録物識別子タイプ NCID
収録物識別子 AA11160707
権利
権利情報 © 2015. This manuscript version is made available under the CC-BY-NC-ND 4.0 license http://creativecommons.org/licenses/by-nc-nd/4.0/
出版タイプ
出版タイプ AM
出版タイプResource http://purl.org/coar/version/c_ab4af688f83e57aa
WoS
URL http://gateway.isiknowledge.com/gateway/Gateway.cgi?&GWVersion=2&SrcAuth=ShinshuUniv&SrcApp=ShinshuUniv&DestLinkType=FullRecord&DestApp=WOS&KeyUT=000358393900020
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Cite as

Okada, Tomohiko, Suzuki, Asuka, Yoshido, Shiho, Minamisawa, Hikari M., 2015, Crystal architectures of a layered silicate on monodisperse spherical silica particles cause the topochemical expansion of the core-shell particles: ELSEVIER SCIENCE BV, 168–174 p.

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