Item type |
学術雑誌論文 / Journal Article(1) |
公開日 |
2016-02-04 |
タイトル |
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タイトル |
Radical scavenging reaction kinetics with multiwalled carbon nanotubes |
言語 |
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言語 |
eng |
DOI |
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関連識別子 |
https://doi.org/10.1016/j.carbon.2014.10.009 |
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関連名称 |
10.1016/j.carbon.2014.10.009 |
資源タイプ |
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資源 |
http://purl.org/coar/resource_type/c_6501 |
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タイプ |
journal article |
著者 |
Tsuruoka, Shuji
Matsumoto, Hidetoshi
Koyama, Kenichi
Akiba, Eiji
Yanagisawa, Takashi
Cassee, Flemming R.
Saito, Naoto
Usui, Yuki
Kobayashi, Shinsuke
Porter, Dale W.
Castranova, Vincent
Endo, Morinobu
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信州大学研究者総覧へのリンク |
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氏名 |
Tsuruoka, Shuji |
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URL |
http://soar-rd.shinshu-u.ac.jp/profile/ja.WpDUOeyC.html |
信州大学研究者総覧へのリンク |
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氏名 |
Saito, Naoto |
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URL |
http://soar-rd.shinshu-u.ac.jp/profile/ja.WpkhuUkh.html |
信州大学研究者総覧へのリンク |
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氏名 |
Endo, Morinobu |
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URL |
http://soar-rd.shinshu-u.ac.jp/profile/ja.uUTmZhkh.html |
出版者 |
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出版者 |
PERGAMON-ELSEVIER SCIENCE LTD |
引用 |
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内容記述 |
CARBON. 83:232-239 (2015) |
書誌情報 |
CARBON
巻 83,
p. 232-239,
発行日 2015-03
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抄録 |
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内容記述 |
Progress in the development of carbon nanotubes (CNTs) has stimulated great interest among industries providing new applications. Meanwhile, toxicological evaluations on nanomaterials are advancing leading to a predictive exposure limit for CNTs, which implies the possibility of designing safer CNTs. To pursue safety by design, the redox potential in reactions with CNTs has been contemplated recently. However, the chemical reactivity of CNTs has not been explored kinetically, so that there is no scheme to express a redox reaction with CNTs, though it has been investigated and reported. In addition, the reactivity of CNTs is discussed with regard to impurities that consist of transition metals in CNTs, which obfuscates the contribution of CNTs to the reaction. The present work aimed at modeling CNT scavenging in aqueous solution using a kinetic approach and a simple first-order reaction scheme. The results show that CNTs follow the redox reaction assumption in a simple chemical system. As a result, the reaction with multiwalled CNTs is semiquantitatively denoted as redox potential, which suggests that their biological reactions may also be evaluated using a redox potential scheme. (C) 2014 Elsevier Ltd. All rights reserved. |
資源タイプ(コンテンツの種類) |
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内容記述 |
Article |
ISSN |
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収録物識別子タイプ |
PISSN |
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収録物識別子 |
0008-6223 |
書誌レコードID |
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収録物識別子タイプ |
NCID |
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収録物識別子 |
AA00598943 |
権利 |
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権利情報 |
© 2015. This manuscript version is made available under the CC-BY-NC-ND 4.0 license http://creativecommons.org/licenses/by-nc-nd/4.0/ |
出版タイプ |
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出版タイプ |
AM |
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出版タイプResource |
http://purl.org/coar/version/c_ab4af688f83e57aa |
WoS |
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URL |
http://gateway.isiknowledge.com/gateway/Gateway.cgi?&GWVersion=2&SrcAuth=ShinshuUniv&SrcApp=ShinshuUniv&DestLinkType=FullRecord&DestApp=WOS&KeyUT=000348951800027 |