Item type |
学術雑誌論文 / Journal Article(1) |
公開日 |
2016-04-22 |
タイトル |
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タイトル |
Towards Implantable Bio-Supercapacitors: Pseudocapacitance of Ruthenium Oxide Nanoparticles and Nanosheets in Acids, Buffered Solutions, and Bioelectrolytes |
言語 |
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言語 |
eng |
DOI |
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関連識別子 |
https://doi.org/10.1149/2.0021505jes |
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関連名称 |
10.1149/2.0021505jes |
資源タイプ |
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資源 |
http://purl.org/coar/resource_type/c_6501 |
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タイプ |
journal article |
著者 |
Makino, Sho
Ban, Takayuki
Sugimoto, Wataru
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信州大学研究者総覧へのリンク |
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氏名 |
Sugimoto, Wataru |
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URL |
http://soar-rd.shinshu-u.ac.jp/profile/ja.WaTFjekV.html |
出版者 |
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出版者 |
ELECTROCHEMICAL SOC INC |
引用 |
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内容記述 |
JOURNAL OF THE ELECTROCHEMICAL SOCIETY. 162(5):A5001-A5006 (2015) |
書誌情報 |
JOURNAL OF THE ELECTROCHEMICAL SOCIETY
巻 162,
号 5,
p. A5001-A5006,
発行日 2015-01-09
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抄録 |
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内容記述 |
Metal oxides, in particular ruthenium-based oxides, are promising electrode materials for aqueous pseudocapacitors. Strong acids or bases are favored over neutral electrolytes owing to the higher capacitance. Here we explore the pseudocapacitive behavior of ruthenium oxide nanoparticles and nanosheets in near neutral pH as an environmentally benign electrolyte. The pseudocapacitive charge storage in poorly-crystalline hydrous RuO2 nanoparticles, and highly-crystalline RuO2 nanosheets were investigated in acetic acid-lithium acetate (AcOH-AcOLi) buffered solutions. It is shown that capacitance values as high as 1,038 F g(-1) can be achieved in AcOH-AcOLi buffered solutions with RuO2 nanosheets, which is 44% higher than the benchmark RuO2 nH(2)O in H2SO4 electrolyte (720 F g(-1)). Furthermore, comparable performance was obtained in phosphate buffered saline and fetal bovine serum. The mechanism of the pseudocapacitive properties is discussed based on the difference in the surface redox behavior of different RuO2 nanomaterials in acid, neutral, buffered solutions, and in weak acid. (C) The Author(s) 2015. Published by ECS. This is an open access article distributed under the terms of the Creative Commons Attribution 4.0 License (CC BY, http://creativecommons.org/licenses/by/4.0/), which permits unrestricted reuse of the work in any medium, provided the original work is properly cited. All rights reserved. |
資源タイプ(コンテンツの種類) |
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ISSN |
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収録物識別子タイプ |
ISSN |
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収録物識別子 |
0013-4651 |
書誌レコードID |
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収録物識別子タイプ |
NCID |
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収録物識別子 |
AA00697016 |
権利 |
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権利情報 |
Copyright © The Author(s) 2015. Published by ECS. This is an open access article distributed under the terms of the Creative Commons Attribution 4.0 License (CC BY, http://creativecommons.org/licenses/by/4.0/), which permits unrestricted reuse of the work in any medium, provided the original work is properly cited. |
出版タイプ |
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出版タイプ |
VoR |
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出版タイプResource |
http://purl.org/coar/version/c_970fb48d4fbd8a85 |
WoS |
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URL |
http://gateway.isiknowledge.com/gateway/Gateway.cgi?&GWVersion=2&SrcAuth=ShinshuUniv&SrcApp=ShinshuUniv&DestLinkType=FullRecord&DestApp=WOS&KeyUT=000351976200002 |