{"_buckets": {"deposit": "eb00d017-a0d2-4065-8749-2de4ae0fb497"}, "_deposit": {"id": "19203", "owners": [], "pid": {"revision_id": 0, "type": "depid", "value": "19203"}, "status": "published"}, "_oai": {"id": "oai:soar-ir.repo.nii.ac.jp:00019203"}, "item_6_biblio_info_6": {"attribute_name": "\u66f8\u8a8c\u60c5\u5831", "attribute_value_mlt": [{"bibliographicIssueDates": {"bibliographicIssueDate": "2013-11", "bibliographicIssueDateType": "Issued"}, "bibliographicIssueNumber": "11", "bibliographicPageEnd": "1093", "bibliographicPageStart": "1080", "bibliographicVolumeNumber": "17", "bibliographic_titles": [{"bibliographic_title": "JOURNAL OF PORPHYRINS AND PHTHALOCYANINES"}]}]}, "item_6_description_20": {"attribute_name": "\u6284\u9332", "attribute_value_mlt": [{"subitem_description": "A homologous series of the phthalocyanine-fullerene dyads, C-n-PcM(OFbaC60) (n = 6, 8, 10, 12; M = Cu, Ni, Co: 3a-3f), have been synthesized to obtain homeotropic alignment at rt and investigate the effects of spacer chain length (n = 6, 8, 10, 12) and central metal (M = Cu, Ni, Co) on the mesomorphism. Interestingly, the shorter-spacer-substituted (n = 6, 8; M = Cu) dyads 3a and 3b showed a hexagonal columnar mesophase (Col(h)), whereas the longer-spacer-substituted (n = 10, 12; M = Cu, Ni, Co) dyads 3c-3f showed a tetragonal columnar mesophase (Col(tet)). Moreover, each of the homologs 3a-3e shows perfect homeotropic alignment in both the Col(h) and Col(tet) mesophases at rt. More interestingly, these columnar mesophases gave a very unique XRD reflection peak denoted as Peak H in a very small angle region of 0.8 \u003c 2 theta \u003c 2.0 degree. We have established at the first time from our developed two new XRD sample preparation techniques that the Peak H is due to the helical structure of fullerenes around columns formed by one-dimensionally stacked Pc cores. 1D nano array structure of donor and acceptor between two electrodes is recently proposed to obtain higher photoelectric conversion efficiency for organic thin film solar cells. This 1D nano array structure is almost compatible with the present homeotropically aligned Pc-C-60 dyads 3a-3f between two glass plates. Hence, these novel Pc-C-60 dyads 3a-3f may be very suitable to organic thin film solar cells.", "subitem_description_type": "Abstract"}]}, "item_6_description_30": {"attribute_name": "\u8cc7\u6e90\u30bf\u30a4\u30d7\uff08\u30b3\u30f3\u30c6\u30f3\u30c4\u306e\u7a2e\u985e\uff09", "attribute_value_mlt": [{"subitem_description": "Article", "subitem_description_type": "Other"}]}, "item_6_description_5": {"attribute_name": "\u5f15\u7528", "attribute_value_mlt": [{"subitem_description": "JOURNAL OF PORPHYRINS AND PHTHALOCYANINES. 17(11):1080-1093 (2013)", "subitem_description_type": "Other"}]}, "item_6_link_3": {"attribute_name": "\u4fe1\u5dde\u5927\u5b66\u7814\u7a76\u8005\u7dcf\u89a7\u3078\u306e\u30ea\u30f3\u30af", "attribute_value_mlt": [{"subitem_link_text": "Itoh, Eiji", "subitem_link_url": "http://soar-rd.shinshu-u.ac.jp/profile/ja.Zmymbpkh.html"}, {"subitem_link_text": "Ohta, Kazuchika", "subitem_link_url": "http://soar-rd.shinshu-u.ac.jp/profile/ja.yVLFjekV.html"}]}, "item_6_link_67": {"attribute_name": "WoS", "attribute_value_mlt": [{"subitem_link_text": "Web of Science", "subitem_link_url": "http://gateway.isiknowledge.com/gateway/Gateway.cgi?\u0026GWVersion=2\u0026SrcAuth=ShinshuUniv\u0026SrcApp=ShinshuUniv\u0026DestLinkType=FullRecord\u0026DestApp=WOS\u0026KeyUT=000327741900004"}]}, "item_6_publisher_4": {"attribute_name": "\u51fa\u7248\u8005", "attribute_value_mlt": [{"subitem_publisher": "WORLD SCI PUBL CO INC"}]}, "item_6_relation_48": {"attribute_name": "DOI", "attribute_value_mlt": [{"subitem_relation_name": [{"subitem_relation_name_text": "10.1142/S1088424613500752"}], "subitem_relation_type_id": {"subitem_relation_type_id_text": "http://dx.doi.org/10.1142/S1088424613500752", "subitem_relation_type_select": "DOI"}}]}, "item_6_rights_62": {"attribute_name": "\u6a29\u5229", "attribute_value_mlt": [{"subitem_rights": "Electronic version of an article published as Journal of porphyrins and phthalocyanines, Volume: 17, Issues: 11(2013) pp. 1080-1093, DOI: 10.1142/S1088424613500752 \u00a9 2013 World Scientific Publishing Copmpany, http://www.worldscientific.com/worldscinet/jpp"}]}, "item_6_select_64": {"attribute_name": "\u8457\u8005\u7248\u30d5\u30e9\u30b0", "attribute_value_mlt": [{"subitem_select_item": "author"}]}, "item_6_source_id_35": {"attribute_name": "ISSN", "attribute_value_mlt": [{"subitem_source_identifier": "1088-4246", "subitem_source_identifier_type": "ISSN"}]}, "item_6_source_id_39": {"attribute_name": "NII ISSN", "attribute_value_mlt": [{"subitem_source_identifier": "1088-4246", "subitem_source_identifier_type": "ISSN"}]}, "item_6_source_id_40": {"attribute_name": "\u66f8\u8a8c\u30ec\u30b3\u30fc\u30c9ID", "attribute_value_mlt": [{"subitem_source_identifier": "AA11202421", "subitem_source_identifier_type": "NCID"}]}, "item_6_text_69": {"attribute_name": "wosonly authkey", "attribute_value_mlt": [{"subitem_text_value": "discotic liquid crystal; phthalocyanine; fullerene; phthalocyanine-fullerene dyad; homeotropic alignment; organic thin film solar cell"}]}, "item_6_text_70": {"attribute_name": "wosonly keywords", "attribute_value_mlt": [{"subitem_text_value": "HOMEOTROPIC ALIGNMENT; BLOCK-COPOLYMERS; BAND-GAP; HETEROJUNCTION; POLYMER; TRANSPORT"}]}, "item_6_textarea_68": {"attribute_name": "wosonly abstract", "attribute_value_mlt": [{"subitem_textarea_value": "A homologous series of the phthalocyanine-fullerene dyads, C-n-PcM(OFbaC60) (n = 6, 8, 10, 12; M = Cu, Ni, Co: 3a-3f), have been synthesized to obtain homeotropic alignment at rt and investigate the effects of spacer chain length (n = 6, 8, 10, 12) and central metal (M = Cu, Ni, Co) on the mesomorphism. Interestingly, the shorter-spacer-substituted (n = 6, 8; M = Cu) dyads 3a and 3b showed a hexagonal columnar mesophase (Col(h)), whereas the longer-spacer-substituted (n = 10, 12; M = Cu, Ni, Co) dyads 3c-3f showed a tetragonal columnar mesophase (Col(tet)). Moreover, each of the homologs 3a-3e shows perfect homeotropic alignment in both the Col(h) and Col(tet) mesophases at rt. More interestingly, these columnar mesophases gave a very unique XRD reflection peak denoted as Peak H in a very small angle region of 0.8 \u003c 2 theta \u003c 2.0 degree. We have established at the first time from our developed two new XRD sample preparation techniques that the Peak H is due to the helical structure of fullerenes around columns formed by one-dimensionally stacked Pc cores. 1D nano array structure of donor and acceptor between two electrodes is recently proposed to obtain higher photoelectric conversion efficiency for organic thin film solar cells. This 1D nano array structure is almost compatible with the present homeotropically aligned Pc-C-60 dyads 3a-3f between two glass plates. Hence, these novel Pc-C-60 dyads 3a-3f may be very suitable to organic thin film solar cells."}]}, "item_creator": {"attribute_name": "\u8457\u8005", "attribute_type": "creator", "attribute_value_mlt": [{"creatorNames": [{"creatorName": "Tauchi, Lisa"}], "nameIdentifiers": [{"nameIdentifier": "104191", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Nakagaki, Takahiro"}], "nameIdentifiers": [{"nameIdentifier": "104192", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Shimizu, Masahiro"}], "nameIdentifiers": [{"nameIdentifier": "104193", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Itoh, Eiji"}], "nameIdentifiers": [{"nameIdentifier": "104194", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Yasutake, Mikio"}], "nameIdentifiers": [{"nameIdentifier": "104195", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Ohta, Kazuchika"}], "nameIdentifiers": [{"nameIdentifier": "104196", "nameIdentifierScheme": "WEKO"}]}]}, "item_files": {"attribute_name": "\u30d5\u30a1\u30a4\u30eb\u60c5\u5831", "attribute_type": "file", "attribute_value_mlt": [{"accessrole": "open_date", "date": [{"dateType": "Available", "dateValue": "2017-09-26"}], "displaytype": "detail", "download_preview_message": "", "file_order": 0, "filename": "Discotic_liquid_crystals_of_transition_metal_complexes_49.pdf", "filesize": [{"value": "2.3 MB"}], "format": "application/pdf", "future_date_message": "", "is_thumbnail": false, "licensefree": "Electronic version of an article published as Journal of porphyrins and phthalocyanines, Volume: 17, Issues: 11(2013) pp. 1080-1093, DOI: 10.1142/S1088424613500752 \u00a9 2013 World Scientific Publishing Copmpany, http://www.worldscientific.com/worldscinet/jpp", "licensetype": "license_free", "mimetype": "application/pdf", "size": 2300000.0, "url": {"label": "Discotic_liquid_crystals_of_transition_metal_complexes_49.pdf", "url": "https://soar-ir.repo.nii.ac.jp/record/19203/files/Discotic_liquid_crystals_of_transition_metal_complexes_49.pdf"}, "version_id": "8b1e153e-8680-4802-898d-111cc57377c8"}]}, "item_keyword": {"attribute_name": "\u30ad\u30fc\u30ef\u30fc\u30c9", "attribute_value_mlt": [{"subitem_subject": "discotic liquid crystal", "subitem_subject_scheme": "Other"}, {"subitem_subject": "phthalocyanine", "subitem_subject_scheme": "Other"}, {"subitem_subject": "fullerene", "subitem_subject_scheme": "Other"}, {"subitem_subject": "phthalocyanine-fullerene dyad", "subitem_subject_scheme": "Other"}, {"subitem_subject": "homeotropic alignment", "subitem_subject_scheme": "Other"}, {"subitem_subject": "organic thin film solar cell", "subitem_subject_scheme": "Other"}]}, "item_language": {"attribute_name": "\u8a00\u8a9e", "attribute_value_mlt": [{"subitem_language": "eng"}]}, "item_resource_type": {"attribute_name": "\u8cc7\u6e90\u30bf\u30a4\u30d7", "attribute_value_mlt": [{"resourcetype": "journal article", "resourceuri": "http://purl.org/coar/resource_type/c_6501"}]}, "item_title": "Discotic liquid crystals of transition metal complexes 49: establishment of helical structure of fullerene moieties in columnar mesophase of phthalocyanine-fullerene dyads", "item_titles": {"attribute_name": "\u30bf\u30a4\u30c8\u30eb", "attribute_value_mlt": [{"subitem_title": "Discotic liquid crystals of transition metal complexes 49: establishment of helical structure of fullerene moieties in columnar mesophase of phthalocyanine-fullerene dyads"}]}, "item_type_id": "6", "owner": "1", "path": ["1309/1310"], "permalink_uri": "http://hdl.handle.net/10091/00019965", "pubdate": {"attribute_name": "\u516c\u958b\u65e5", "attribute_value": "2017-09-26"}, "publish_date": "2017-09-26", "publish_status": "0", "recid": "19203", "relation": {}, "relation_version_is_last": true, "title": ["Discotic liquid crystals of transition metal complexes 49: establishment of helical structure of fullerene moieties in columnar mesophase of phthalocyanine-fullerene dyads"], "weko_shared_id": 3}