Item type |
学術雑誌論文 / Journal Article(1) |
公開日 |
2017-09-26 |
タイトル |
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タイトル |
Discotic liquid crystals of transition metal complexes 50(dagger): spiranthes-like supramolecular structure of phthalocyanine-fullerene dyads |
言語 |
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言語 |
eng |
DOI |
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関連識別子 |
https://doi.org/10.1142/S1088424614500072 |
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関連名称 |
10.1142/S1088424614500072 |
キーワード |
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主題 |
discotic liquid crystal, phthalocyanine, fullerene, dyad, homeotropic alignment, spiranthes-like supramolecular structure |
資源タイプ |
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資源 |
http://purl.org/coar/resource_type/c_6501 |
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タイプ |
journal article |
著者 |
Ishikawa, Aya
Ono, Kenta
Ohta, Kazuchika
Yasutake, Mikio
Ichikawa, Musubu
Itoh, Eiji
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信州大学研究者総覧へのリンク |
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氏名 |
Ohta, Kazuchika |
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URL |
http://soar-rd.shinshu-u.ac.jp/profile/ja.yVLFjekV.html |
信州大学研究者総覧へのリンク |
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氏名 |
Ichikawa, Musubu |
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URL |
http://soar-rd.shinshu-u.ac.jp/profile/ja.WenUjFkV.html |
信州大学研究者総覧へのリンク |
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氏名 |
Itoh, Eiji |
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URL |
http://soar-rd.shinshu-u.ac.jp/profile/ja.Zmymbpkh.html |
出版者 |
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出版者 |
WORLD SCI PUBL CO INC |
引用 |
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内容記述 |
JOURNAL OF PORPHYRINS AND PHTHALOCYANINES. 18(5):366-379 (2014) |
書誌情報 |
JOURNAL OF PORPHYRINS AND PHTHALOCYANINES
巻 18,
号 5,
p. 366-379,
発行日 2014-05
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抄録 |
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内容記述 |
We have synthesized novel liquid crystalline Pc-C-60 dyads (CnS)(6)PcCu-C-60 (n = 14, 16, 18: 1a-1c) by using our developed synthetic method in order to investigate the mesomorphism and alignment behavior. Each of the (CnS)(6)PcCu-C-60 dyads shows perfect homeotropic alignment in the Col(ho) mesophase between two glass plates for n = 14, 16, 18 and also on a glass plate for n = 14, although none of the parent Pc compounds (CnS)(8)PcCu and the Pc precursors (CnS)(6)PcCu-OH and (CnS)(6)PcCu-OFBA shows homeotropic alignment. It may be attributed to the strong affinity between fullerene and glass surface. Although the reason is not so clear at the present time, this is very useful guideline for the molecular design to prepare homeotropic alignment-showing discotic liquid crystals. Very interestingly, the spherical C-60 parts form a helical structure around the column formed by the disk-like Pc parts. This supramolecular structure very resembles spiranthes. The spiranthes-like supramolecular structure is compatible with one-dimensional nano-array expecting the high conversion efficiency of solar cells. |
資源タイプ(コンテンツの種類) |
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内容記述 |
Article |
ISSN |
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収録物識別子タイプ |
ISSN |
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収録物識別子 |
1088-4246 |
書誌レコードID |
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収録物識別子タイプ |
NCID |
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収録物識別子 |
AA11202421 |
権利 |
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権利情報 |
Electronic version of an article published as Journal of porphyrins and phthalocyanines, Volume: 18, Issues: 5(2014) pp. 366-379, DOI: 10.1142/S1088424614500072 © 2014 World Scientific Publishing Copmpany, http://www.worldscientific.com/worldscinet/jpp |
出版タイプ |
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出版タイプ |
AM |
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出版タイプResource |
http://purl.org/coar/version/c_ab4af688f83e57aa |
WoS |
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URL |
http://gateway.isiknowledge.com/gateway/Gateway.cgi?&GWVersion=2&SrcAuth=ShinshuUniv&SrcApp=ShinshuUniv&DestLinkType=FullRecord&DestApp=WOS&KeyUT=000339010300003 |