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  1. 080 繊維学部
  2. 0801 学術論文

Discotic liquid crystals of transition metal complexes 51(dagger): Synthesis and mesomorphism of flat-pumpkin-shaped phthalocyanine-fullerene dyads

http://hdl.handle.net/10091/00019969
2558a622-f434-4aa2-b23c-3b9cccb2df55
名前 / ファイル ライセンス アクション
Discotic_liquid_crystals_of_transition_metal_complexes_51.pdf Discotic_liquid_crystals_of_transition_metal_complexes_51.pdf (1.3 MB)
Item type 学術雑誌論文 / Journal Article(1)
公開日 2017-09-26
タイトル
言語 en
タイトル Discotic liquid crystals of transition metal complexes 51(dagger): Synthesis and mesomorphism of flat-pumpkin-shaped phthalocyanine-fullerene dyads
言語
言語 eng
キーワード
主題Scheme Other
主題 discotic liquid crystal
キーワード
主題Scheme Other
主題 phthalocyanine
キーワード
主題Scheme Other
主題 fullerene
キーワード
主題Scheme Other
主題 dyad
キーワード
主題Scheme Other
主題 cubic mesophase
キーワード
主題Scheme Other
主題 columnar mesophase
資源タイプ
資源 http://purl.org/coar/resource_type/c_6501
タイプ journal article
著者 Yoshioka, Miho

× Yoshioka, Miho

WEKO 104216

Yoshioka, Miho

Search repository
Ohta, Kazuchika

× Ohta, Kazuchika

WEKO 104217

Ohta, Kazuchika

Search repository
Miwa, Yohei

× Miwa, Yohei

WEKO 104218

Miwa, Yohei

Search repository
Kutsumizu, Shoichi

× Kutsumizu, Shoichi

WEKO 104219

Kutsumizu, Shoichi

Search repository
Yasutake, Mikio

× Yasutake, Mikio

WEKO 104220

Yasutake, Mikio

Search repository
信州大学研究者総覧へのリンク
氏名 Ohta, Kazuchika
URL http://soar-rd.shinshu-u.ac.jp/profile/ja.yVLFjekV.html
出版者
出版者 WORLD SCI PUBL CO INC
引用
内容記述タイプ Other
内容記述 JOURNAL OF PORPHYRINS AND PHTHALOCYANINES. 18(10-11):856-868 (2014)
書誌情報 JOURNAL OF PORPHYRINS AND PHTHALOCYANINES

巻 18, 号 10-11, p. 856-868, 発行日 2014
抄録
内容記述タイプ Abstract
内容記述 We have synthesized a novel type of donor-acceptor liquid crystalline material, phthalocyanine-fullerene (Pc-C-60) dyad, [m,p,m'-(C14O)(3)PhO](6)PcCu-C-60 (7), and the Pc precursors, [m,p,m'-(C14O)(3)PhO](6)PcCu-OFBA (6) and [m,p,m'-(C14O)(3)PhO](6)PcCu-OH (5), and established their mesomorphism by using a polarizing optical microscope, a differential scanning calorimeter and a small angle X-ray diffractometer. Very interestingly, their corresponding previous parent Pc derivative, [m,p,m'-(C14O)(3)PhO](8)PcCu (4), shows a very wide temperature region ca. 90 degrees C of a bicontinuous Cub(Pn3m) mesophase, whereas the present children Pc precursors (5 and 6) and Pc-C-60 dyad 7 show not the Cub mesophase but a Col(ho) mesophase. It is also noteworthy that the staking distance in the Col(ho) mesophase of the Pc-C-60 dyad 7 was a very big value of ca. 9.1 angstrom, which is the biggest in discotic liquid crystals to our best knowledge. It may be originated from the biggest excluded volume caused by thermal fluctuation of peripheral long alkoxy chains at m, m'-positions. The excluded volume caused by thermal fluctuation of the peripheral long chains is so big that the molecular shape of the Pc derivative 4 and the Pc-C-60 dyad 7 very resembles a flat pumpkin.
資源タイプ(コンテンツの種類)
内容記述タイプ Other
内容記述 Article
ISSN
収録物識別子タイプ ISSN
収録物識別子 1088-4246
書誌レコードID
収録物識別子タイプ NCID
収録物識別子 AA11202421
DOI
関連識別子
識別子タイプ DOI
関連識別子 https://doi.org/10.1142/S1088424614500643
関連名称
関連名称 10.1142/S1088424614500643
権利
権利情報 Electronic version of an article published as Journal of porphyrins and phthalocyanines, Volume: 18, Issues: 10-11(2014) pp. 856-868, DOI: 10.1142/S1088424614500643 © 2014 World Scientific Publishing Copmpany, http://www.worldscientific.com/worldscinet/jpp
出版タイプ
出版タイプ AM
出版タイプResource http://purl.org/coar/version/c_ab4af688f83e57aa
WoS
表示名 Web of Science
URL http://gateway.isiknowledge.com/gateway/Gateway.cgi?&GWVersion=2&SrcAuth=ShinshuUniv&SrcApp=ShinshuUniv&DestLinkType=FullRecord&DestApp=WOS&KeyUT=000346189500003
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