{"_buckets": {"deposit": "019bf5f3-2860-4ee0-8bcc-7d42031b7e42"}, "_deposit": {"id": "19207", "owners": [], "pid": {"revision_id": 0, "type": "depid", "value": "19207"}, "status": "published"}, "_oai": {"id": "oai:soar-ir.repo.nii.ac.jp:00019207"}, "item_6_biblio_info_6": {"attribute_name": "\u66f8\u8a8c\u60c5\u5831", "attribute_value_mlt": [{"bibliographicIssueDates": {"bibliographicIssueDate": "2014", "bibliographicIssueDateType": "Issued"}, "bibliographicIssueNumber": "10-11", "bibliographicPageEnd": "868", "bibliographicPageStart": "856", "bibliographicVolumeNumber": "18", "bibliographic_titles": [{"bibliographic_title": "JOURNAL OF PORPHYRINS AND PHTHALOCYANINES"}]}]}, "item_6_description_20": {"attribute_name": "\u6284\u9332", "attribute_value_mlt": [{"subitem_description": "We have synthesized a novel type of donor-acceptor liquid crystalline material, phthalocyanine-fullerene (Pc-C-60) dyad, [m,p,m\u0027-(C14O)(3)PhO](6)PcCu-C-60 (7), and the Pc precursors, [m,p,m\u0027-(C14O)(3)PhO](6)PcCu-OFBA (6) and [m,p,m\u0027-(C14O)(3)PhO](6)PcCu-OH (5), and established their mesomorphism by using a polarizing optical microscope, a differential scanning calorimeter and a small angle X-ray diffractometer. Very interestingly, their corresponding previous parent Pc derivative, [m,p,m\u0027-(C14O)(3)PhO](8)PcCu (4), shows a very wide temperature region ca. 90 degrees C of a bicontinuous Cub(Pn3m) mesophase, whereas the present children Pc precursors (5 and 6) and Pc-C-60 dyad 7 show not the Cub mesophase but a Col(ho) mesophase. It is also noteworthy that the staking distance in the Col(ho) mesophase of the Pc-C-60 dyad 7 was a very big value of ca. 9.1 angstrom, which is the biggest in discotic liquid crystals to our best knowledge. It may be originated from the biggest excluded volume caused by thermal fluctuation of peripheral long alkoxy chains at m, m\u0027-positions. The excluded volume caused by thermal fluctuation of the peripheral long chains is so big that the molecular shape of the Pc derivative 4 and the Pc-C-60 dyad 7 very resembles a flat pumpkin.", "subitem_description_type": "Abstract"}]}, "item_6_description_30": {"attribute_name": "\u8cc7\u6e90\u30bf\u30a4\u30d7\uff08\u30b3\u30f3\u30c6\u30f3\u30c4\u306e\u7a2e\u985e\uff09", "attribute_value_mlt": [{"subitem_description": "Article", "subitem_description_type": "Other"}]}, "item_6_description_5": {"attribute_name": "\u5f15\u7528", "attribute_value_mlt": [{"subitem_description": "JOURNAL OF PORPHYRINS AND PHTHALOCYANINES. 18(10-11):856-868 (2014)", "subitem_description_type": "Other"}]}, "item_6_link_3": {"attribute_name": "\u4fe1\u5dde\u5927\u5b66\u7814\u7a76\u8005\u7dcf\u89a7\u3078\u306e\u30ea\u30f3\u30af", "attribute_value_mlt": [{"subitem_link_text": "Ohta, Kazuchika", "subitem_link_url": "http://soar-rd.shinshu-u.ac.jp/profile/ja.yVLFjekV.html"}]}, "item_6_link_67": {"attribute_name": "WoS", "attribute_value_mlt": [{"subitem_link_text": "Web of Science", "subitem_link_url": "http://gateway.isiknowledge.com/gateway/Gateway.cgi?\u0026GWVersion=2\u0026SrcAuth=ShinshuUniv\u0026SrcApp=ShinshuUniv\u0026DestLinkType=FullRecord\u0026DestApp=WOS\u0026KeyUT=000346189500003"}]}, "item_6_publisher_4": {"attribute_name": "\u51fa\u7248\u8005", "attribute_value_mlt": [{"subitem_publisher": "WORLD SCI PUBL CO INC"}]}, "item_6_relation_48": {"attribute_name": "DOI", "attribute_value_mlt": [{"subitem_relation_name": [{"subitem_relation_name_text": "10.1142/S1088424614500643"}], "subitem_relation_type_id": {"subitem_relation_type_id_text": "http://dx.doi.org/10.1142/S1088424614500643", "subitem_relation_type_select": "DOI"}}]}, "item_6_rights_62": {"attribute_name": "\u6a29\u5229", "attribute_value_mlt": [{"subitem_rights": "Electronic version of an article published as Journal of porphyrins and phthalocyanines, Volume: 18, Issues: 10-11(2014) pp. 856-868, DOI: 10.1142/S1088424614500643 \u00a9 2014 World Scientific Publishing Copmpany, http://www.worldscientific.com/worldscinet/jpp"}]}, "item_6_select_64": {"attribute_name": "\u8457\u8005\u7248\u30d5\u30e9\u30b0", "attribute_value_mlt": [{"subitem_select_item": "author"}]}, "item_6_source_id_35": {"attribute_name": "ISSN", "attribute_value_mlt": [{"subitem_source_identifier": "1088-4246", "subitem_source_identifier_type": "ISSN"}]}, "item_6_source_id_39": {"attribute_name": "NII ISSN", "attribute_value_mlt": [{"subitem_source_identifier": "1088-4246", "subitem_source_identifier_type": "ISSN"}]}, "item_6_source_id_40": {"attribute_name": "\u66f8\u8a8c\u30ec\u30b3\u30fc\u30c9ID", "attribute_value_mlt": [{"subitem_source_identifier": "AA11202421", "subitem_source_identifier_type": "NCID"}]}, "item_6_text_69": {"attribute_name": "wosonly authkey", "attribute_value_mlt": [{"subitem_text_value": "discotic liquid crystal; phthalocyanine; fullerene; dyad; cubic mesophase; columnar mesophase"}]}, "item_6_text_70": {"attribute_name": "wosonly keywords", "attribute_value_mlt": [{"subitem_text_value": "UNIFORM HOMEOTROPIC ALIGNMENT; THERMOTROPIC CUBIC MESOPHASE; COLUMNAR MESOPHASES; CHARGE-TRANSPORT; PHASE; METALLOMESOGENS; DERIVATIVES; BEHAVIOR; SERIES; ORDER"}]}, "item_6_textarea_68": {"attribute_name": "wosonly abstract", "attribute_value_mlt": [{"subitem_textarea_value": "We have synthesized a novel type of donor-acceptor liquid crystalline material, phthalocyanine-fullerene (Pc-C-60) dyad, [m,p,m\u0027-(C14O)(3)PhO](6)PcCu-C-60 (7), and the Pc precursors, [m,p,m\u0027-(C14O)(3)PhO](6)PcCu-OFBA (6) and [m,p,m\u0027-(C14O)(3)PhO](6)PcCu-OH (5), and established their mesomorphism by using a polarizing optical microscope, a differential scanning calorimeter and a small angle X-ray diffractometer. Very interestingly, their corresponding previous parent Pc derivative, [m,p,m\u0027-(C14O)(3)PhO](8)PcCu (4), shows a very wide temperature region ca. 90 degrees C of a bicontinuous Cub(Pn3m) mesophase, whereas the present children Pc precursors (5 and 6) and Pc-C-60 dyad 7 show not the Cub mesophase but a Col(ho) mesophase. It is also noteworthy that the staking distance in the Col(ho) mesophase of the Pc-C-60 dyad 7 was a very big value of ca. 9.1 angstrom, which is the biggest in discotic liquid crystals to our best knowledge. It may be originated from the biggest excluded volume caused by thermal fluctuation of peripheral long alkoxy chains at m, m\u0027-positions. The excluded volume caused by thermal fluctuation of the peripheral long chains is so big that the molecular shape of the Pc derivative 4 and the Pc-C-60 dyad 7 very resembles a flat pumpkin."}]}, "item_creator": {"attribute_name": "\u8457\u8005", "attribute_type": "creator", "attribute_value_mlt": [{"creatorNames": [{"creatorName": "Yoshioka, Miho"}], "nameIdentifiers": [{"nameIdentifier": "104216", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Ohta, Kazuchika"}], "nameIdentifiers": [{"nameIdentifier": "104217", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Miwa, Yohei"}], "nameIdentifiers": [{"nameIdentifier": "104218", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Kutsumizu, Shoichi"}], "nameIdentifiers": [{"nameIdentifier": "104219", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Yasutake, Mikio"}], "nameIdentifiers": [{"nameIdentifier": "104220", "nameIdentifierScheme": "WEKO"}]}]}, "item_files": {"attribute_name": "\u30d5\u30a1\u30a4\u30eb\u60c5\u5831", "attribute_type": "file", "attribute_value_mlt": [{"accessrole": "open_date", "date": [{"dateType": "Available", "dateValue": "2017-09-26"}], "displaytype": "detail", "download_preview_message": "", "file_order": 0, "filename": "Discotic_liquid_crystals_of_transition_metal_complexes_51.pdf", "filesize": [{"value": "1.3 MB"}], "format": "application/pdf", "future_date_message": "", "is_thumbnail": false, "licensefree": "Electronic version of an article published as Journal of porphyrins and phthalocyanines, Volume: 18, Issues: 10-11(2014) pp. 856-868, DOI: 10.1142/S1088424614500643 \u00a9 2014 World Scientific Publishing Copmpany, http://www.worldscientific.com/worldscinet/jpp", "licensetype": "license_free", "mimetype": "application/pdf", "size": 1300000.0, "url": {"label": "Discotic_liquid_crystals_of_transition_metal_complexes_51.pdf", "url": "https://soar-ir.repo.nii.ac.jp/record/19207/files/Discotic_liquid_crystals_of_transition_metal_complexes_51.pdf"}, "version_id": "5fe35839-582c-4fab-b965-565e682dc50f"}]}, "item_keyword": {"attribute_name": "\u30ad\u30fc\u30ef\u30fc\u30c9", "attribute_value_mlt": [{"subitem_subject": "discotic liquid crystal", "subitem_subject_scheme": "Other"}, {"subitem_subject": "phthalocyanine", "subitem_subject_scheme": "Other"}, {"subitem_subject": "fullerene", "subitem_subject_scheme": "Other"}, {"subitem_subject": "dyad", "subitem_subject_scheme": "Other"}, {"subitem_subject": "cubic mesophase", "subitem_subject_scheme": "Other"}, {"subitem_subject": "columnar mesophase", "subitem_subject_scheme": "Other"}]}, "item_language": {"attribute_name": "\u8a00\u8a9e", "attribute_value_mlt": [{"subitem_language": "eng"}]}, "item_resource_type": {"attribute_name": "\u8cc7\u6e90\u30bf\u30a4\u30d7", "attribute_value_mlt": [{"resourcetype": "journal article", "resourceuri": "http://purl.org/coar/resource_type/c_6501"}]}, "item_title": "Discotic liquid crystals of transition metal complexes 51(dagger): Synthesis and mesomorphism of flat-pumpkin-shaped phthalocyanine-fullerene dyads", "item_titles": {"attribute_name": "\u30bf\u30a4\u30c8\u30eb", "attribute_value_mlt": [{"subitem_title": "Discotic liquid crystals of transition metal complexes 51(dagger): Synthesis and mesomorphism of flat-pumpkin-shaped phthalocyanine-fullerene dyads"}]}, "item_type_id": "6", "owner": "1", "path": ["1309/1310"], "permalink_uri": "http://hdl.handle.net/10091/00019969", "pubdate": {"attribute_name": "\u516c\u958b\u65e5", "attribute_value": "2017-09-26"}, "publish_date": "2017-09-26", "publish_status": "0", "recid": "19207", "relation": {}, "relation_version_is_last": true, "title": ["Discotic liquid crystals of transition metal complexes 51(dagger): Synthesis and mesomorphism of flat-pumpkin-shaped phthalocyanine-fullerene dyads"], "weko_shared_id": 3}