ログイン
言語:

WEKO3

  • トップ
  • ランキング
To
lat lon distance
To

Field does not validate



インデックスリンク

インデックスツリー

メールアドレスを入力してください。

WEKO

One fine body…

WEKO

One fine body…

アイテム

{"_buckets": {"deposit": "5830b250-29e1-4c6e-86c8-7f05ba209546"}, "_deposit": {"id": "19208", "owners": [], "pid": {"revision_id": 0, "type": "depid", "value": "19208"}, "status": "published"}, "_oai": {"id": "oai:soar-ir.repo.nii.ac.jp:00019208", "sets": ["1310"]}, "author_link": ["104221", "104222", "104223"], "item_1628147817048": {"attribute_name": "出版タイプ", "attribute_value_mlt": [{"subitem_version_resource": "http://purl.org/coar/version/c_ab4af688f83e57aa", "subitem_version_type": "AM"}]}, "item_6_biblio_info_6": {"attribute_name": "書誌情報", "attribute_value_mlt": [{"bibliographicIssueDates": {"bibliographicIssueDate": "2015", "bibliographicIssueDateType": "Issued"}, "bibliographicIssueNumber": "18", "bibliographicPageEnd": "13839", "bibliographicPageStart": "13828", "bibliographicVolumeNumber": "5", "bibliographic_titles": [{"bibliographic_title": "RSC ADVANCES"}]}]}, "item_6_description_20": {"attribute_name": "抄録", "attribute_value_mlt": [{"subitem_description": "We synthesized a novel series of flying-seed-like derivatives (3a-g) based on phthalocyaninato copper(II) (abbreviated as PcCu) substituted by bulky groups {PhO (a), (o-C-1)PhO (b), (m-C-1)PhO (c), (p-C-1)PhO (d), [m, p-(C-1)(2)]PhO (e), [m, m\u0027-(C-1)(2)]PhO (f), and [m,p,m\u0027-(C-1)(3)]PhO (g)} instead of using long alkyl chains, in order to investigate their mesomorphism. Their phase transition behaviour and the mesophase structures were established using a polarizing optical microscope, a differential scanning calorimeter, a thermogravimetry analyser and a temperature-dependent small angle X-ray diffractometer. It was demonstrated that (PhO)(8)PcCu (3a) and [(p-C-1)PhO](8)PcCu (3d) show no mesophase, whereas [(m-C-1)PhO](8)PcCu (3c), {[m,p-(C-1)(2)]PhO}(8)PcCu (3e), {[m,m\u0027-(C-1)(2)]PhO}(8)PcCu (3f), and {[m, p, m\u0027-(C-1)(3)] PhO}(8)PcCu (3g) show various kinds of columnar mesophases of Col(ro)(P2(1)/a), Col(ro)(P2(1)/a), Col(ro)(C2/m) and Col(tet.o), respectively, while [(o-C-1)PhO](8)PcCu (3b) shows a monotropic Col(ro)(P2m) mesophase. Thus, we revealed that mesomorphism could be induced by these novel bulky substituents instead of using long alkyl chains, and that the mesophase structures were greatly affected by the number and position of the methoxy groups. In particular, it is very interesting that the derivatives with methoxy group(s) at the meta position(s), namely, 3c, 3e, 3f and 3g, tend to show enantiotropic mesophase(s), whereas neither the derivative with no methoxy group, 3a, nor the derivative with a methoxy group at the para position, 3d, show a mesophase.", "subitem_description_type": "Abstract"}]}, "item_6_description_30": {"attribute_name": "資源タイプ(コンテンツの種類)", "attribute_value_mlt": [{"subitem_description": "Article", "subitem_description_type": "Other"}]}, "item_6_description_5": {"attribute_name": "引用", "attribute_value_mlt": [{"subitem_description": "RSC ADVANCES. 5(18):13828-13839 (2015)", "subitem_description_type": "Other"}]}, "item_6_link_3": {"attribute_name": "信州大学研究者総覧へのリンク", "attribute_value_mlt": [{"subitem_link_text": "Ohta, Kazuchika", "subitem_link_url": "http://soar-rd.shinshu-u.ac.jp/profile/ja.yVLFjekV.html"}]}, "item_6_link_67": {"attribute_name": "WoS", "attribute_value_mlt": [{"subitem_link_text": "Web of Science", "subitem_link_url": "http://gateway.isiknowledge.com/gateway/Gateway.cgi?\u0026GWVersion=2\u0026SrcAuth=ShinshuUniv\u0026SrcApp=ShinshuUniv\u0026DestLinkType=FullRecord\u0026DestApp=WOS\u0026KeyUT=000349434300071"}]}, "item_6_publisher_4": {"attribute_name": "出版者", "attribute_value_mlt": [{"subitem_publisher": "ROYAL SOC CHEMISTRY"}]}, "item_6_relation_48": {"attribute_name": "DOI", "attribute_value_mlt": [{"subitem_relation_name": [{"subitem_relation_name_text": "10.1039/c4ra13474e"}], "subitem_relation_type_id": {"subitem_relation_type_id_text": "https://doi.org/10.1039/c4ra13474e", "subitem_relation_type_select": "DOI"}}]}, "item_6_rights_62": {"attribute_name": "権利", "attribute_value_mlt": [{"subitem_rights": "RSC Adv., 2015,5, 13828-13839 - Reproduced by permission of The Royal Society of Chemistry"}]}, "item_6_select_64": {"attribute_name": "著者版フラグ", "attribute_value_mlt": [{"subitem_select_item": "author"}]}, "item_6_source_id_35": {"attribute_name": "ISSN", "attribute_value_mlt": [{"subitem_source_identifier": "2046-2069", "subitem_source_identifier_type": "ISSN"}]}, "item_6_source_id_39": {"attribute_name": "NII ISSN", "attribute_value_mlt": [{"subitem_source_identifier": "2046-2069", "subitem_source_identifier_type": "ISSN"}]}, "item_6_text_70": {"attribute_name": "wosonly keywords", "attribute_value_mlt": [{"subitem_text_value": "TRANSITION-METAL-COMPLEXES; ALKALI BRANCHED ALKANOATES; COLUMNAR MESOPHASES; THERMAL-BEHAVIOR; PHASE; ORDER; SALTS; ACIDS"}]}, "item_6_textarea_68": {"attribute_name": "wosonly abstract", "attribute_value_mlt": [{"subitem_textarea_value": "We synthesized a novel series of flying-seed-like derivatives (3a-g) based on phthalocyaninato copper(II) (abbreviated as PcCu) substituted by bulky groups {PhO (a), (o-C-1)PhO (b), (m-C-1)PhO (c), (p-C-1)PhO (d), [m, p-(C-1)(2)]PhO (e), [m, m\u0027-(C-1)(2)]PhO (f), and [m,p,m\u0027-(C-1)(3)]PhO (g)} instead of using long alkyl chains, in order to investigate their mesomorphism. Their phase transition behaviour and the mesophase structures were established using a polarizing optical microscope, a differential scanning calorimeter, a thermogravimetry analyser and a temperature-dependent small angle X-ray diffractometer. It was demonstrated that (PhO)(8)PcCu (3a) and [(p-C-1)PhO](8)PcCu (3d) show no mesophase, whereas [(m-C-1)PhO](8)PcCu (3c), {[m,p-(C-1)(2)]PhO}(8)PcCu (3e), {[m,m\u0027-(C-1)(2)]PhO}(8)PcCu (3f), and {[m, p, m\u0027-(C-1)(3)] PhO}(8)PcCu (3g) show various kinds of columnar mesophases of Col(ro)(P2(1)/a), Col(ro)(P2(1)/a), Col(ro)(C2/m) and Col(tet.o), respectively, while [(o-C-1)PhO](8)PcCu (3b) shows a monotropic Col(ro)(P2m) mesophase. Thus, we revealed that mesomorphism could be induced by these novel bulky substituents instead of using long alkyl chains, and that the mesophase structures were greatly affected by the number and position of the methoxy groups. In particular, it is very interesting that the derivatives with methoxy group(s) at the meta position(s), namely, 3c, 3e, 3f and 3g, tend to show enantiotropic mesophase(s), whereas neither the derivative with no methoxy group, 3a, nor the derivative with a methoxy group at the para position, 3d, show a mesophase."}]}, "item_creator": {"attribute_name": "著者", "attribute_type": "creator", "attribute_value_mlt": [{"creatorNames": [{"creatorName": "Yoshioka, Miho"}], "nameIdentifiers": [{"nameIdentifier": "104221", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Ohta, Kazuchika"}], "nameIdentifiers": [{"nameIdentifier": "104222", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Yasutake, Mikio"}], "nameIdentifiers": [{"nameIdentifier": "104223", "nameIdentifierScheme": "WEKO"}]}]}, "item_files": {"attribute_name": "ファイル情報", "attribute_type": "file", "attribute_value_mlt": [{"accessrole": "open_date", "date": [{"dateType": "Available", "dateValue": "2017-09-26"}], "displaytype": "detail", "download_preview_message": "", "file_order": 0, "filename": "Flying-seed-like_liquid_crystals_4.pdf", "filesize": [{"value": "895.9 kB"}], "format": "application/pdf", "future_date_message": "", "is_thumbnail": false, "licensefree": "RSC Adv., 2015,5, 13828-13839 - Reproduced by permission of The Royal Society of Chemistry", "licensetype": "license_note", "mimetype": "application/pdf", "size": 895900.0, "url": {"label": "Flying-seed-like_liquid_crystals_4.pdf", "url": "https://soar-ir.repo.nii.ac.jp/record/19208/files/Flying-seed-like_liquid_crystals_4.pdf"}, "version_id": "5ac54966-a256-424d-81e8-bafe09bd55b8"}]}, "item_language": {"attribute_name": "言語", "attribute_value_mlt": [{"subitem_language": "eng"}]}, "item_resource_type": {"attribute_name": "資源タイプ", "attribute_value_mlt": [{"resourcetype": "journal article", "resourceuri": "http://purl.org/coar/resource_type/c_6501"}]}, "item_title": "Flying-seed-like liquid crystals. Part 4:dagger a novel series of bulky substituents inducing mesomorphism instead of using long alkyl chains", "item_titles": {"attribute_name": "タイトル", "attribute_value_mlt": [{"subitem_title": "Flying-seed-like liquid crystals. Part 4:dagger a novel series of bulky substituents inducing mesomorphism instead of using long alkyl chains", "subitem_title_language": "en"}]}, "item_type_id": "6", "owner": "1", "path": ["1310"], "permalink_uri": "http://hdl.handle.net/10091/00019970", "pubdate": {"attribute_name": "PubDate", "attribute_value": "2017-09-26"}, "publish_date": "2017-09-26", "publish_status": "0", "recid": "19208", "relation": {}, "relation_version_is_last": true, "title": ["Flying-seed-like liquid crystals. Part 4:dagger a novel series of bulky substituents inducing mesomorphism instead of using long alkyl chains"], "weko_shared_id": -1}
  1. 080 繊維学部
  2. 0801 学術論文

Flying-seed-like liquid crystals. Part 4:dagger a novel series of bulky substituents inducing mesomorphism instead of using long alkyl chains

http://hdl.handle.net/10091/00019970
http://hdl.handle.net/10091/00019970
b02dd5c7-3514-4232-86d9-25388c7cf238
名前 / ファイル ライセンス アクション
Flying-seed-like_liquid_crystals_4.pdf Flying-seed-like_liquid_crystals_4.pdf (895.9 kB)
Item type 学術雑誌論文 / Journal Article(1)
公開日 2017-09-26
タイトル
言語 en
タイトル Flying-seed-like liquid crystals. Part 4:dagger a novel series of bulky substituents inducing mesomorphism instead of using long alkyl chains
言語
言語 eng
資源タイプ
資源 http://purl.org/coar/resource_type/c_6501
タイプ journal article
著者 Yoshioka, Miho

× Yoshioka, Miho

WEKO 104221

Yoshioka, Miho

Search repository
Ohta, Kazuchika

× Ohta, Kazuchika

WEKO 104222

Ohta, Kazuchika

Search repository
Yasutake, Mikio

× Yasutake, Mikio

WEKO 104223

Yasutake, Mikio

Search repository
信州大学研究者総覧へのリンク
氏名 Ohta, Kazuchika
URL http://soar-rd.shinshu-u.ac.jp/profile/ja.yVLFjekV.html
出版者
出版者 ROYAL SOC CHEMISTRY
引用
内容記述タイプ Other
内容記述 RSC ADVANCES. 5(18):13828-13839 (2015)
書誌情報 RSC ADVANCES

巻 5, 号 18, p. 13828-13839, 発行日 2015
抄録
内容記述タイプ Abstract
内容記述 We synthesized a novel series of flying-seed-like derivatives (3a-g) based on phthalocyaninato copper(II) (abbreviated as PcCu) substituted by bulky groups {PhO (a), (o-C-1)PhO (b), (m-C-1)PhO (c), (p-C-1)PhO (d), [m, p-(C-1)(2)]PhO (e), [m, m'-(C-1)(2)]PhO (f), and [m,p,m'-(C-1)(3)]PhO (g)} instead of using long alkyl chains, in order to investigate their mesomorphism. Their phase transition behaviour and the mesophase structures were established using a polarizing optical microscope, a differential scanning calorimeter, a thermogravimetry analyser and a temperature-dependent small angle X-ray diffractometer. It was demonstrated that (PhO)(8)PcCu (3a) and [(p-C-1)PhO](8)PcCu (3d) show no mesophase, whereas [(m-C-1)PhO](8)PcCu (3c), {[m,p-(C-1)(2)]PhO}(8)PcCu (3e), {[m,m'-(C-1)(2)]PhO}(8)PcCu (3f), and {[m, p, m'-(C-1)(3)] PhO}(8)PcCu (3g) show various kinds of columnar mesophases of Col(ro)(P2(1)/a), Col(ro)(P2(1)/a), Col(ro)(C2/m) and Col(tet.o), respectively, while [(o-C-1)PhO](8)PcCu (3b) shows a monotropic Col(ro)(P2m) mesophase. Thus, we revealed that mesomorphism could be induced by these novel bulky substituents instead of using long alkyl chains, and that the mesophase structures were greatly affected by the number and position of the methoxy groups. In particular, it is very interesting that the derivatives with methoxy group(s) at the meta position(s), namely, 3c, 3e, 3f and 3g, tend to show enantiotropic mesophase(s), whereas neither the derivative with no methoxy group, 3a, nor the derivative with a methoxy group at the para position, 3d, show a mesophase.
資源タイプ(コンテンツの種類)
内容記述タイプ Other
内容記述 Article
ISSN
収録物識別子タイプ ISSN
収録物識別子 2046-2069
DOI
識別子タイプ DOI
関連識別子 https://doi.org/10.1039/c4ra13474e
関連名称 10.1039/c4ra13474e
権利
権利情報 RSC Adv., 2015,5, 13828-13839 - Reproduced by permission of The Royal Society of Chemistry
出版タイプ
出版タイプ AM
出版タイプResource http://purl.org/coar/version/c_ab4af688f83e57aa
WoS
表示名 Web of Science
URL http://gateway.isiknowledge.com/gateway/Gateway.cgi?&GWVersion=2&SrcAuth=ShinshuUniv&SrcApp=ShinshuUniv&DestLinkType=FullRecord&DestApp=WOS&KeyUT=000349434300071
戻る
0
views
See details
Views

Versions

Ver.1 2021-03-01 08:48:38.554724
Show All versions

Share

Mendeley Twitter Facebook Print Addthis

Cite as

エクスポート

OAI-PMH
  • OAI-PMH JPCOAR
  • OAI-PMH DublinCore
  • OAI-PMH DDI
Other Formats
  • JSON
  • BIBTEX

Confirm


Powered by WEKO3


Powered by WEKO3