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  1. 080 繊維学部
  2. 0801 学術論文

Flying-seed-like liquid crystals 5: Liquid crystals based on octakisphenylthiophthalocyanine and their optical properties

http://hdl.handle.net/10091/00019971
8bf5944d-413e-48bc-9f3a-493df046e90c
名前 / ファイル ライセンス アクション
Flying-seed-like_liquid_crystals_5.pdf Flying-seed-like_liquid_crystals_5.pdf (723.5 kB)
Item type 学術雑誌論文 / Journal Article(1)
公開日 2017-09-26
タイトル
言語 en
タイトル Flying-seed-like liquid crystals 5: Liquid crystals based on octakisphenylthiophthalocyanine and their optical properties
言語
言語 eng
キーワード
主題Scheme Other
主題 flying-seed-like liquid crystals
キーワード
主題Scheme Other
主題 metallomesogen
キーワード
主題Scheme Other
主題 phthalocyanine
キーワード
主題Scheme Other
主題 columnar mesophase
資源タイプ
資源 http://purl.org/coar/resource_type/c_6501
タイプ journal article
著者 Ishikawa, Aya

× Ishikawa, Aya

WEKO 104224

Ishikawa, Aya

Search repository
Ohta, Kazuchika

× Ohta, Kazuchika

WEKO 104225

Ohta, Kazuchika

Search repository
Yasutake, Mikio

× Yasutake, Mikio

WEKO 104226

Yasutake, Mikio

Search repository
信州大学研究者総覧へのリンク
氏名 Ohta, Kazuchika
URL http://soar-rd.shinshu-u.ac.jp/profile/ja.yVLFjekV.html
出版者
出版者 WORLD SCI PUBL CO INC
引用
内容記述タイプ Other
内容記述 JOURNAL OF PORPHYRINS AND PHTHALOCYANINES. 19(5):639-650 (2015)
書誌情報 JOURNAL OF PORPHYRINS AND PHTHALOCYANINES

巻 19, 号 5, p. 639-650, 発行日 2015-05
抄録
内容記述タイプ Abstract
内容記述 We have synthesized three novel flying-seed-like liquid crystals based on phthalocyaninato copper(II) (abbreviated as PcCu) substituted by bulky groups {(o-C-1)PhS (i), (m-C-1)PhS (j), [m, p(C-1)(2)]PhS (k)} instead of using long alkyl chains, in order to investigate their mesomorphism. Their phase transition behavior and the mesophase structures have been established by using a polarizing optical microscope, a differential scanning calorimeter, and a temperature-dependent small angle X-ray diffractometer. As the results, [(o-C-1)PhS](8)PcCu (8i), [(m-C-1)PhS](8)PcCu (8j) and {[m,p-(C-1)(2)]PhS}(8)PcCu (8k) show a Col tet. o mesophase at 314.9 similar to 362.9 degrees C, a Col(ro) (P2m) mesophase at 287.4 similar to 334.2 degrees C and a Col(ro) (P2m) mesophase at 331.8 similar to 386.8 degrees C, respectively. Very interestingly, each of the derivatives thus exhibits a columnar mesophase at very high temperatures. The mesomorphism is apparently originated from the novel bulky groups (i similar to k). It is also noteworthy that the Q-bands of the present PhScontaining Pc derivatives 8i similar to 8k in THF significantly red-shift by about 35 nm in comparison with those of the corresponding PhO-containing derivatives in THF.
資源タイプ(コンテンツの種類)
内容記述タイプ Other
内容記述 Article
ISSN
収録物識別子タイプ ISSN
収録物識別子 1088-4246
書誌レコードID
収録物識別子タイプ NCID
収録物識別子 AA11202421
DOI
関連識別子
識別子タイプ DOI
関連識別子 https://doi.org/10.1142/S1088424615500479
関連名称
関連名称 10.1142/S1088424615500479
権利
権利情報 Electronic version of an article published as Journal of porphyrins and phthalocyanines, Volume: 19, Issues: 5(2015) pp. 639-650, DOI: 10.1142/S1088424615500479 © 2015 World Scientific Publishing Copmpany, http://www.worldscientific.com/worldscinet/jpp
出版タイプ
出版タイプ AM
出版タイプResource http://purl.org/coar/version/c_ab4af688f83e57aa
WoS
表示名 Web of Science
URL http://gateway.isiknowledge.com/gateway/Gateway.cgi?&GWVersion=2&SrcAuth=ShinshuUniv&SrcApp=ShinshuUniv&DestLinkType=FullRecord&DestApp=WOS&KeyUT=000355750500001
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