{"_buckets": {"deposit": "a3ed5442-2045-4b4b-a28a-6f6f7d0fda6d"}, "_deposit": {"id": "19209", "owners": [], "pid": {"revision_id": 0, "type": "depid", "value": "19209"}, "status": "published"}, "_oai": {"id": "oai:soar-ir.repo.nii.ac.jp:00019209"}, "item_6_biblio_info_6": {"attribute_name": "\u66f8\u8a8c\u60c5\u5831", "attribute_value_mlt": [{"bibliographicIssueDates": {"bibliographicIssueDate": "2015-05", "bibliographicIssueDateType": "Issued"}, "bibliographicIssueNumber": "5", "bibliographicPageEnd": "650", "bibliographicPageStart": "639", "bibliographicVolumeNumber": "19", "bibliographic_titles": [{"bibliographic_title": "JOURNAL OF PORPHYRINS AND PHTHALOCYANINES"}]}]}, "item_6_description_20": {"attribute_name": "\u6284\u9332", "attribute_value_mlt": [{"subitem_description": "We have synthesized three novel flying-seed-like liquid crystals based on phthalocyaninato copper(II) (abbreviated as PcCu) substituted by bulky groups {(o-C-1)PhS (i), (m-C-1)PhS (j), [m, p(C-1)(2)]PhS (k)} instead of using long alkyl chains, in order to investigate their mesomorphism. Their phase transition behavior and the mesophase structures have been established by using a polarizing optical microscope, a differential scanning calorimeter, and a temperature-dependent small angle X-ray diffractometer. As the results, [(o-C-1)PhS](8)PcCu (8i), [(m-C-1)PhS](8)PcCu (8j) and {[m,p-(C-1)(2)]PhS}(8)PcCu (8k) show a Col tet. o mesophase at 314.9 similar to 362.9 degrees C, a Col(ro) (P2m) mesophase at 287.4 similar to 334.2 degrees C and a Col(ro) (P2m) mesophase at 331.8 similar to 386.8 degrees C, respectively. Very interestingly, each of the derivatives thus exhibits a columnar mesophase at very high temperatures. The mesomorphism is apparently originated from the novel bulky groups (i similar to k). It is also noteworthy that the Q-bands of the present PhScontaining Pc derivatives 8i similar to 8k in THF significantly red-shift by about 35 nm in comparison with those of the corresponding PhO-containing derivatives in THF.", "subitem_description_type": "Abstract"}]}, "item_6_description_30": {"attribute_name": "\u8cc7\u6e90\u30bf\u30a4\u30d7\uff08\u30b3\u30f3\u30c6\u30f3\u30c4\u306e\u7a2e\u985e\uff09", "attribute_value_mlt": [{"subitem_description": "Article", "subitem_description_type": "Other"}]}, "item_6_description_5": {"attribute_name": "\u5f15\u7528", "attribute_value_mlt": [{"subitem_description": "JOURNAL OF PORPHYRINS AND PHTHALOCYANINES. 19(5):639-650 (2015)", "subitem_description_type": "Other"}]}, "item_6_link_3": {"attribute_name": "\u4fe1\u5dde\u5927\u5b66\u7814\u7a76\u8005\u7dcf\u89a7\u3078\u306e\u30ea\u30f3\u30af", "attribute_value_mlt": [{"subitem_link_text": "Ohta, Kazuchika", "subitem_link_url": "http://soar-rd.shinshu-u.ac.jp/profile/ja.yVLFjekV.html"}]}, "item_6_link_67": {"attribute_name": "WoS", "attribute_value_mlt": [{"subitem_link_text": "Web of Science", "subitem_link_url": "http://gateway.isiknowledge.com/gateway/Gateway.cgi?\u0026GWVersion=2\u0026SrcAuth=ShinshuUniv\u0026SrcApp=ShinshuUniv\u0026DestLinkType=FullRecord\u0026DestApp=WOS\u0026KeyUT=000355750500001"}]}, "item_6_publisher_4": {"attribute_name": "\u51fa\u7248\u8005", "attribute_value_mlt": [{"subitem_publisher": "WORLD SCI PUBL CO INC"}]}, "item_6_relation_48": {"attribute_name": "DOI", "attribute_value_mlt": [{"subitem_relation_name": [{"subitem_relation_name_text": "10.1142/S1088424615500479"}], "subitem_relation_type_id": {"subitem_relation_type_id_text": "http://dx.doi.org/10.1142/S1088424615500479", "subitem_relation_type_select": "DOI"}}]}, "item_6_rights_62": {"attribute_name": "\u6a29\u5229", "attribute_value_mlt": [{"subitem_rights": "Electronic version of an article published as Journal of porphyrins and phthalocyanines, Volume: 19, Issues: 5(2015) pp. 639-650, DOI: 10.1142/S1088424615500479 \u00a9 2015 World Scientific Publishing Copmpany, http://www.worldscientific.com/worldscinet/jpp"}]}, "item_6_select_64": {"attribute_name": "\u8457\u8005\u7248\u30d5\u30e9\u30b0", "attribute_value_mlt": [{"subitem_select_item": "author"}]}, "item_6_source_id_35": {"attribute_name": "ISSN", "attribute_value_mlt": [{"subitem_source_identifier": "1088-4246", "subitem_source_identifier_type": "ISSN"}]}, "item_6_source_id_39": {"attribute_name": "NII ISSN", "attribute_value_mlt": [{"subitem_source_identifier": "1088-4246", "subitem_source_identifier_type": "ISSN"}]}, "item_6_source_id_40": {"attribute_name": "\u66f8\u8a8c\u30ec\u30b3\u30fc\u30c9ID", "attribute_value_mlt": [{"subitem_source_identifier": "AA11202421", "subitem_source_identifier_type": "NCID"}]}, "item_6_text_69": {"attribute_name": "wosonly authkey", "attribute_value_mlt": [{"subitem_text_value": "flying-seed-like liquid crystals; metallomesogen; phthalocyanine; columnar mesophase"}]}, "item_6_text_70": {"attribute_name": "wosonly keywords", "attribute_value_mlt": [{"subitem_text_value": "PHTHALOCYANINE-FULLERENE DYADS; ALKALI BRANCHED ALKANOATES; LONG ALKYL CHAINS; METAL-COMPLEXES; SUPRAMOLECULAR STRUCTURE; BULKY SUBSTITUENTS; THERMAL-BEHAVIOR; MESOMORPHISM"}]}, "item_6_textarea_68": {"attribute_name": "wosonly abstract", "attribute_value_mlt": [{"subitem_textarea_value": "We have synthesized three novel flying-seed-like liquid crystals based on phthalocyaninato copper(II) (abbreviated as PcCu) substituted by bulky groups {(o-C-1)PhS (i), (m-C-1)PhS (j), [m, p(C-1)(2)]PhS (k)} instead of using long alkyl chains, in order to investigate their mesomorphism. Their phase transition behavior and the mesophase structures have been established by using a polarizing optical microscope, a differential scanning calorimeter, and a temperature-dependent small angle X-ray diffractometer. As the results, [(o-C-1)PhS](8)PcCu (8i), [(m-C-1)PhS](8)PcCu (8j) and {[m,p-(C-1)(2)]PhS}(8)PcCu (8k) show a Col tet. o mesophase at 314.9 similar to 362.9 degrees C, a Col(ro) (P2m) mesophase at 287.4 similar to 334.2 degrees C and a Col(ro) (P2m) mesophase at 331.8 similar to 386.8 degrees C, respectively. Very interestingly, each of the derivatives thus exhibits a columnar mesophase at very high temperatures. The mesomorphism is apparently originated from the novel bulky groups (i similar to k). It is also noteworthy that the Q-bands of the present PhScontaining Pc derivatives 8i similar to 8k in THF significantly red-shift by about 35 nm in comparison with those of the corresponding PhO-containing derivatives in THF."}]}, "item_creator": {"attribute_name": "\u8457\u8005", "attribute_type": "creator", "attribute_value_mlt": [{"creatorNames": [{"creatorName": "Ishikawa, Aya"}], "nameIdentifiers": [{"nameIdentifier": "104224", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Ohta, Kazuchika"}], "nameIdentifiers": [{"nameIdentifier": "104225", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Yasutake, Mikio"}], "nameIdentifiers": [{"nameIdentifier": "104226", "nameIdentifierScheme": "WEKO"}]}]}, "item_files": {"attribute_name": "\u30d5\u30a1\u30a4\u30eb\u60c5\u5831", "attribute_type": "file", "attribute_value_mlt": [{"accessrole": "open_date", "date": [{"dateType": "Available", "dateValue": "2017-09-26"}], "displaytype": "detail", "download_preview_message": "", "file_order": 0, "filename": "Flying-seed-like_liquid_crystals_5.pdf", "filesize": [{"value": "723.5 kB"}], "format": "application/pdf", "future_date_message": "", "is_thumbnail": false, "licensefree": "Electronic version of an article published as Journal of porphyrins and phthalocyanines, Volume: 19, Issues: 5(2015) pp. 639-650, DOI: 10.1142/S1088424615500479 \u00a9 2015 World Scientific Publishing Copmpany, http://www.worldscientific.com/worldscinet/jpp", "licensetype": "license_free", "mimetype": "application/pdf", "size": 723500.0, "url": {"label": "Flying-seed-like_liquid_crystals_5.pdf", "url": "https://soar-ir.repo.nii.ac.jp/record/19209/files/Flying-seed-like_liquid_crystals_5.pdf"}, "version_id": "39207384-45f2-4425-930d-5cac8e08a182"}]}, "item_keyword": {"attribute_name": "\u30ad\u30fc\u30ef\u30fc\u30c9", "attribute_value_mlt": [{"subitem_subject": "flying-seed-like liquid crystals", "subitem_subject_scheme": "Other"}, {"subitem_subject": "metallomesogen", "subitem_subject_scheme": "Other"}, {"subitem_subject": "phthalocyanine", "subitem_subject_scheme": "Other"}, {"subitem_subject": "columnar mesophase", "subitem_subject_scheme": "Other"}]}, "item_language": {"attribute_name": "\u8a00\u8a9e", "attribute_value_mlt": [{"subitem_language": "eng"}]}, "item_resource_type": {"attribute_name": "\u8cc7\u6e90\u30bf\u30a4\u30d7", "attribute_value_mlt": [{"resourcetype": "journal article", "resourceuri": "http://purl.org/coar/resource_type/c_6501"}]}, "item_title": "Flying-seed-like liquid crystals 5: Liquid crystals based on octakisphenylthiophthalocyanine and their optical properties", "item_titles": {"attribute_name": "\u30bf\u30a4\u30c8\u30eb", "attribute_value_mlt": [{"subitem_title": "Flying-seed-like liquid crystals 5: Liquid crystals based on octakisphenylthiophthalocyanine and their optical properties"}]}, "item_type_id": "6", "owner": "1", "path": ["1309/1310"], "permalink_uri": "http://hdl.handle.net/10091/00019971", "pubdate": {"attribute_name": "\u516c\u958b\u65e5", "attribute_name_i18n": "\u516c\u958b\u65e5", "attribute_value": "2017-09-26"}, "publish_date": "2017-09-26", "publish_status": "0", "recid": "19209", "relation": {}, "relation_version_is_last": true, "title": ["Flying-seed-like liquid crystals 5: Liquid crystals based on octakisphenylthiophthalocyanine and their optical properties"], "weko_shared_id": 3}