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Their phase transition behavior and the mesophase structures have been established by using a polarizing optical microscope, a differential scanning calorimeter, and a temperature-dependent small angle X-ray diffractometer. As the results, [(o-C-1)PhS](8)PcCu (8i), [(m-C-1)PhS](8)PcCu (8j) and {[m,p-(C-1)(2)]PhS}(8)PcCu (8k) show a Col tet. o mesophase at 314.9 similar to 362.9 degrees C, a Col(ro) (P2m) mesophase at 287.4 similar to 334.2 degrees C and a Col(ro) (P2m) mesophase at 331.8 similar to 386.8 degrees C, respectively. Very interestingly, each of the derivatives thus exhibits a columnar mesophase at very high temperatures. The mesomorphism is apparently originated from the novel bulky groups (i similar to k). 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Flying-seed-like liquid crystals 5: Liquid crystals based on octakisphenylthiophthalocyanine and their optical properties
http://hdl.handle.net/10091/00019971
http://hdl.handle.net/10091/000199718bf5944d-413e-48bc-9f3a-493df046e90c
名前 / ファイル | ライセンス | アクション |
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Flying-seed-like_liquid_crystals_5.pdf (723.5 kB)
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Item type | 学術雑誌論文 / Journal Article(1) | |||||
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公開日 | 2017-09-26 | |||||
タイトル | ||||||
言語 | en | |||||
タイトル | Flying-seed-like liquid crystals 5: Liquid crystals based on octakisphenylthiophthalocyanine and their optical properties | |||||
言語 | ||||||
言語 | eng | |||||
DOI | ||||||
識別子タイプ | DOI | |||||
関連識別子 | https://doi.org/10.1142/S1088424615500479 | |||||
関連名称 | 10.1142/S1088424615500479 | |||||
キーワード | ||||||
主題 | flying-seed-like liquid crystals, metallomesogen, phthalocyanine, columnar mesophase | |||||
資源タイプ | ||||||
資源 | http://purl.org/coar/resource_type/c_6501 | |||||
タイプ | journal article | |||||
著者 |
Ishikawa, Aya
× Ishikawa, Aya× Ohta, Kazuchika× Yasutake, Mikio |
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信州大学研究者総覧へのリンク | ||||||
氏名 | Ohta, Kazuchika | |||||
URL | http://soar-rd.shinshu-u.ac.jp/profile/ja.yVLFjekV.html | |||||
出版者 | ||||||
出版者 | WORLD SCI PUBL CO INC | |||||
引用 | ||||||
内容記述タイプ | Other | |||||
内容記述 | JOURNAL OF PORPHYRINS AND PHTHALOCYANINES. 19(5):639-650 (2015) | |||||
書誌情報 |
JOURNAL OF PORPHYRINS AND PHTHALOCYANINES 巻 19, 号 5, p. 639-650, 発行日 2015-05 |
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抄録 | ||||||
内容記述タイプ | Abstract | |||||
内容記述 | We have synthesized three novel flying-seed-like liquid crystals based on phthalocyaninato copper(II) (abbreviated as PcCu) substituted by bulky groups {(o-C-1)PhS (i), (m-C-1)PhS (j), [m, p(C-1)(2)]PhS (k)} instead of using long alkyl chains, in order to investigate their mesomorphism. Their phase transition behavior and the mesophase structures have been established by using a polarizing optical microscope, a differential scanning calorimeter, and a temperature-dependent small angle X-ray diffractometer. As the results, [(o-C-1)PhS](8)PcCu (8i), [(m-C-1)PhS](8)PcCu (8j) and {[m,p-(C-1)(2)]PhS}(8)PcCu (8k) show a Col tet. o mesophase at 314.9 similar to 362.9 degrees C, a Col(ro) (P2m) mesophase at 287.4 similar to 334.2 degrees C and a Col(ro) (P2m) mesophase at 331.8 similar to 386.8 degrees C, respectively. Very interestingly, each of the derivatives thus exhibits a columnar mesophase at very high temperatures. The mesomorphism is apparently originated from the novel bulky groups (i similar to k). It is also noteworthy that the Q-bands of the present PhScontaining Pc derivatives 8i similar to 8k in THF significantly red-shift by about 35 nm in comparison with those of the corresponding PhO-containing derivatives in THF. | |||||
資源タイプ(コンテンツの種類) | ||||||
内容記述タイプ | Other | |||||
内容記述 | Article | |||||
ISSN | ||||||
収録物識別子タイプ | ISSN | |||||
収録物識別子 | 1088-4246 | |||||
書誌レコードID | ||||||
収録物識別子タイプ | NCID | |||||
収録物識別子 | AA11202421 | |||||
権利 | ||||||
権利情報 | Electronic version of an article published as Journal of porphyrins and phthalocyanines, Volume: 19, Issues: 5(2015) pp. 639-650, DOI: 10.1142/S1088424615500479 © 2015 World Scientific Publishing Copmpany, http://www.worldscientific.com/worldscinet/jpp | |||||
出版タイプ | ||||||
出版タイプ | AM | |||||
出版タイプResource | http://purl.org/coar/version/c_ab4af688f83e57aa | |||||
WoS | ||||||
表示名 | Web of Science | |||||
URL | http://gateway.isiknowledge.com/gateway/Gateway.cgi?&GWVersion=2&SrcAuth=ShinshuUniv&SrcApp=ShinshuUniv&DestLinkType=FullRecord&DestApp=WOS&KeyUT=000355750500001 |