{"_buckets": {"deposit": "82913620-607a-44da-93d8-662f6b070e52"}, "_deposit": {"id": "19211", "owners": [], "pid": {"revision_id": 0, "type": "depid", "value": "19211"}, "status": "published"}, "_oai": {"id": "oai:soar-ir.repo.nii.ac.jp:00019211", "sets": ["1310"]}, "author_link": ["104230", "104231", "104232"], "item_1628147817048": {"attribute_name": "出版タイプ", "attribute_value_mlt": [{"subitem_version_resource": "http://purl.org/coar/version/c_ab4af688f83e57aa", "subitem_version_type": "AM"}]}, "item_6_biblio_info_6": {"attribute_name": "書誌情報", "attribute_value_mlt": [{"bibliographicIssueDates": {"bibliographicIssueDate": "2016-12", "bibliographicIssueDateType": "Issued"}, "bibliographicIssueNumber": "12", "bibliographicPageEnd": "1456", "bibliographicPageStart": "1444", "bibliographicVolumeNumber": "20", "bibliographic_titles": [{"bibliographic_title": "JOURNAL OF PORPHYRINS AND PHTHALOCYANINES"}]}]}, "item_6_description_20": {"attribute_name": "抄録", "attribute_value_mlt": [{"subitem_description": "We have synthesized a novel liquid crystalline phthalocyanine(Pc)-fullerene(C-60) dyad (C14S)(6)PcCu-VAN-C-60 (3a) bridged by an inexpensive natural product of vanillin (VAN), instead of the previous long n-alkylene chain spacer. We have also synthesized a comparative dyad (C14S)(6)PcCu-OPh-C-60 (3b) bridged by p-hydroxybenzaldehyde (OPh), in order to investigate the influence of the methoxy group in the vanillin moiety on homeotropic alignment between two glass plates. Very interestingly, homeotropic alignment could be observed only for the dyad (C14S)(6)PcCu-VAN-C60 (3a) having a methoxy group in the vanillin moiety, whereas it could not be observed for the dyad (C14S)(6)PcCu-OPh-C-60 (3b) having no methoxy group at the phenoxy group. It is very noteworthy that such a slight difference in these molecular structures between 3a and 3b becomes a crucial point to show the homeotropic alignment. Each of the dyads, 3a and 3b, showed two hexagonal ordered columnar (Col(ho)) mesophases. Each of the Col(ho) mesophases in 3a and 3b gave an additional very strong reflection peak named as Peak H in a very low angle region of the SAXS (small angle X-ray scattering) pattern. Peak H could be established, from two different SAXS measurement methods, as one pitch in a helical structure of the fullerenes around the Pc column.", "subitem_description_type": "Abstract"}]}, "item_6_description_30": {"attribute_name": "資源タイプ（コンテンツの種類）", "attribute_value_mlt": [{"subitem_description": "Article", "subitem_description_type": "Other"}]}, "item_6_description_5": {"attribute_name": "引用", "attribute_value_mlt": [{"subitem_description": "JOURNAL OF PORPHYRINS AND PHTHALOCYANINES. 20(12):1444-1456 (2016)", "subitem_description_type": "Other"}]}, "item_6_link_3": {"attribute_name": "信州大学研究者総覧へのリンク", "attribute_value_mlt": [{"subitem_link_text": "Ohta, Kazuchika", "subitem_link_url": "http://soar-rd.shinshu-u.ac.jp/profile/ja.yVLFjekV.html"}]}, "item_6_link_67": {"attribute_name": "WoS", "attribute_value_mlt": [{"subitem_link_text": "Web of Science", "subitem_link_url": "http://gateway.isiknowledge.com/gateway/Gateway.cgi?\u0026GWVersion=2\u0026SrcAuth=ShinshuUniv\u0026SrcApp=ShinshuUniv\u0026DestLinkType=FullRecord\u0026DestApp=WOS\u0026KeyUT=000393046400005"}]}, "item_6_publisher_4": {"attribute_name": "出版者", "attribute_value_mlt": [{"subitem_publisher": "WORLD SCI PUBL CO INC"}]}, "item_6_relation_48": {"attribute_name": "DOI", "attribute_value_mlt": [{"subitem_relation_name": [{"subitem_relation_name_text": "10.1142/S1088424616501194"}], "subitem_relation_type_id": {"subitem_relation_type_id_text": "https://doi.org/10.1142/S1088424616501194", "subitem_relation_type_select": "DOI"}}]}, "item_6_rights_62": {"attribute_name": "権利", "attribute_value_mlt": [{"subitem_rights": "Electronic version of an article published as Journal of porphyrins and phthalocyanines, Volume: 20, Issues: 12(2016) pp. 1444-1456, DOI: 10.1142/S1088424616501194 © 2016 World Scientific Publishing Copmpany, http://www.worldscientific.com/worldscinet/jpp"}]}, "item_6_select_64": {"attribute_name": "著者版フラグ", "attribute_value_mlt": [{"subitem_select_item": "author"}]}, "item_6_source_id_35": {"attribute_name": "ISSN", "attribute_value_mlt": [{"subitem_source_identifier": "1088-4246", "subitem_source_identifier_type": "ISSN"}]}, "item_6_source_id_39": {"attribute_name": "NII ISSN", "attribute_value_mlt": [{"subitem_source_identifier": "1088-4246", "subitem_source_identifier_type": "ISSN"}]}, "item_6_source_id_40": {"attribute_name": "書誌レコードID", "attribute_value_mlt": [{"subitem_source_identifier": "AA11202421", "subitem_source_identifier_type": "NCID"}]}, "item_6_text_69": {"attribute_name": "wosonly authkey", "attribute_value_mlt": [{"subitem_text_value": "phthalocyanine; fullerene; vanillin; columnar mesophase; homeotropic alignment; helical structure"}]}, "item_6_text_70": {"attribute_name": "wosonly keywords", "attribute_value_mlt": [{"subitem_text_value": "LONG ALKYL CHAINS; FILM SOLAR-CELLS; MESOMORPHISM"}]}, "item_6_textarea_68": {"attribute_name": "wosonly abstract", "attribute_value_mlt": [{"subitem_textarea_value": "We have synthesized a novel liquid crystalline phthalocyanine(Pc)-fullerene(C-60) dyad (C14S)(6)PcCu-VAN-C-60 (3a) bridged by an inexpensive natural product of vanillin (VAN), instead of the previous long n-alkylene chain spacer. We have also synthesized a comparative dyad (C14S)(6)PcCu-OPh-C-60 (3b) bridged by p-hydroxybenzaldehyde (OPh), in order to investigate the influence of the methoxy group in the vanillin moiety on homeotropic alignment between two glass plates. Very interestingly, homeotropic alignment could be observed only for the dyad (C14S)(6)PcCu-VAN-C60 (3a) having a methoxy group in the vanillin moiety, whereas it could not be observed for the dyad (C14S)(6)PcCu-OPh-C-60 (3b) having no methoxy group at the phenoxy group. It is very noteworthy that such a slight difference in these molecular structures between 3a and 3b becomes a crucial point to show the homeotropic alignment. Each of the dyads, 3a and 3b, showed two hexagonal ordered columnar (Col(ho)) mesophases. Each of the Col(ho) mesophases in 3a and 3b gave an additional very strong reflection peak named as Peak H in a very low angle region of the SAXS (small angle X-ray scattering) pattern. 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