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  1. 080 繊維学部
  2. 0801 学術論文

Discotic liquid crystals of transition metal complexes, 53: synthesis and mesomorphism of phthalocyanines substituted by m-alkoxyphenylthio groups

http://hdl.handle.net/10091/00019976
http://hdl.handle.net/10091/00019976
f547e655-cdd7-429f-bd5c-35739798b60a
名前 / ファイル ライセンス アクション
Discotic_liquid_crystals_of_transition_metal_complexes_53.pdf Discotic_liquid_crystals_of_transition_metal_complexes_53.pdf (3.0 MB)
Item type 学術雑誌論文 / Journal Article(1)
公開日 2017-09-26
タイトル
言語 en
タイトル Discotic liquid crystals of transition metal complexes, 53: synthesis and mesomorphism of phthalocyanines substituted by m-alkoxyphenylthio groups
言語
言語 eng
キーワード
主題Scheme Other
主題 phthalocyanine
キーワード
主題Scheme Other
主題 metallomesogen
キーワード
主題Scheme Other
主題 columnar mesophase
キーワード
主題Scheme Other
主題 liquid crystals
資源タイプ
資源 http://purl.org/coar/resource_type/c_6501
タイプ journal article
著者 Chino, Yoshiaki

× Chino, Yoshiaki

WEKO 104239

Chino, Yoshiaki

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Ohta, Kazuchika

× Ohta, Kazuchika

WEKO 104240

Ohta, Kazuchika

Search repository
Kimura, Mutsumi

× Kimura, Mutsumi

WEKO 104241

Kimura, Mutsumi

Search repository
Yasutake, Mikio

× Yasutake, Mikio

WEKO 104242

Yasutake, Mikio

Search repository
信州大学研究者総覧へのリンク
氏名 Ohta, Kazuchika
URL http://soar-rd.shinshu-u.ac.jp/profile/ja.yVLFjekV.html
信州大学研究者総覧へのリンク
氏名 Kimura, Mutsumi
URL http://soar-rd.shinshu-u.ac.jp/profile/ja.HaDFjekV.html
出版者
出版者 WORLD SCI PUBL CO INC
引用
内容記述タイプ Other
内容記述 JOURNAL OF PORPHYRINS AND PHTHALOCYANINES. 21(3):159-178 (2017)
書誌情報 JOURNAL OF PORPHYRINS AND PHTHALOCYANINES

巻 21, 号 3, p. 159-178, 発行日 2017-03
抄録
内容記述タイプ Abstract
内容記述 We have successfully synthesized a series of novel octakis(m-alkoxyphenylthio) phthalocyaninato copper(II) complexes, (m-CnOPhS)(8)PcCu (n = 2, 4, 6, 8, 10, 12, 14, 16: 1b similar to 1i), by our developed method to reveal their mesomorphism. The phase transition behavior and mesophase structures have been established by using a polarizing optical microscope, a differential scanning calorimeter, and a temperature-dependent small angle X-ray diffractometer. Interestingly, the very short chain-substituted derivatives, (m-C1OPhS)(8)PcCu (1a) and (m-C2OPhS)(8)PCu (1b), show a hexagonal ordered columnar (Col(ho)) mesophase, whereas each of the other longer-chain-substituted derivatives, (m-CnOPhS)(8)PcCu (n = 4 similar to 16: 1c similar to 1i), shows only rectangular ordered columnar (Col(ro)) mesophase(s). In contrast to the present longer-chain-substituted phenylthio derivatives, each of the previous longer-chain-substituted phenoxy derivatives, (m-CnOPhO)(8)PcCu (n = 10-20), shows a different columnar mesophase of Colho. We discuss this difference of mesomorphism from the viewpoint of the different steric hindrance originated by the peripheral substituents, PhO and PhS groups. Moreover, we could estimate the optical band gaps of (m-C10OPhO)(8)PcCu and (m-C10OPhS)(8)PcCu (1f) from absorption edge of the Q-bands to be 1.79 eV and 1.70 eV, respectively. Therefore, the phenylthio-substituted derivative gave a narrower band gap by ca. 0.1 eV in comparison with the phenoxy-substituted derivative.
資源タイプ(コンテンツの種類)
内容記述タイプ Other
内容記述 Article
ISSN
収録物識別子タイプ ISSN
収録物識別子 1088-4246
書誌レコードID
収録物識別子タイプ NCID
収録物識別子 AA11202421
DOI
識別子タイプ DOI
関連識別子 https://doi.org/10.1142/S1088424617500389
関連名称 10.1142/S1088424617500389
権利
権利情報 Electronic version of an article published as Journal of porphyrins and phthalocyanines, Volume: 21, Issues: 3(2017) pp. 159-178, DOI: 10.1142/S1088424617500389 © 2017 World Scientific Publishing Copmpany, http://www.worldscientific.com/worldscinet/jpp
出版タイプ
出版タイプ AM
出版タイプResource http://purl.org/coar/version/c_ab4af688f83e57aa
WoS
表示名 Web of Science
URL http://gateway.isiknowledge.com/gateway/Gateway.cgi?&GWVersion=2&SrcAuth=ShinshuUniv&SrcApp=ShinshuUniv&DestLinkType=FullRecord&DestApp=WOS&KeyUT=000404984300001
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