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  1. 040 理学部
  2. 0401 学術論文

Effect of Ultraviolet Irradiation on Proton Transfer Facilitated by 5,10,15,20-Tetraphenyl-21H,23H-porphine and Its Metal Complexes at a Water/1,2-Dichloroethane Interface

http://hdl.handle.net/10091/00020600
http://hdl.handle.net/10091/00020600
98eefd34-33d1-4059-abc9-93c3c1e4a047
名前 / ファイル ライセンス アクション
33_1407.pdf 33_1407.pdf (1.1 MB)
Item type 学術雑誌論文 / Journal Article(1)
公開日 2018-05-10
タイトル
タイトル Effect of Ultraviolet Irradiation on Proton Transfer Facilitated by 5,10,15,20-Tetraphenyl-21H,23H-porphine and Its Metal Complexes at a Water/1,2-Dichloroethane Interface
言語
言語 eng
DOI
関連識別子 https://doi.org/10.2116/analsci.33.1407
関連名称 10.2116/analsci.33.1407
キーワード
主題 5,10,15,20-Tetrapheny1-21H,23H-porphine, H2TPP, Co(II)TPP, Zn(II)TPP, Ni(II)TPP, water/1,2-dichloroethane interface, ion transfer voltammetry, facilitated proton transfer, ultraviolet light, photodecomposition
資源タイプ
資源 http://purl.org/coar/resource_type/c_6501
タイプ journal article
著者 Kubo, Tomoya

× Kubo, Tomoya

Kubo, Tomoya
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Ashida, Manaki

× Ashida, Manaki

Ashida, Manaki
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Otagiri, Shiori

× Otagiri, Shiori

Otagiri, Shiori
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Nozue, Haruka

× Nozue, Haruka

Nozue, Haruka
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Makigaki, Souma

× Makigaki, Souma

Makigaki, Souma
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Hinoue, Teruo

× Hinoue, Teruo

Hinoue, Teruo
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信州大学研究者総覧へのリンク
氏名 Hinoue, Teruo
URL http://soar-rd.shinshu-u.ac.jp/profile/ja.jmTajpnU.html
出版者
出版者 JAPAN SOC ANALYTICAL CHEMISTRY
引用
内容記述 ANALYTICAL SCIENCES. 33(12):1407-1413 (2017)
書誌情報 ANALYTICAL SCIENCES

巻 33, 号 12, p. 1407-1413, 発行日 2017-12
抄録
内容記述 We examined photochemical effects by ultraviolet irradiation on facilitated proton transfer at a water/1,2-dichloroethane (W/DCE) interface by ion-transfer voltammetry using a Xe flash lamp. 5,10,15,20-Tetrapheny1-21H,23H-porphine (H2TPP) or its metal complex, such as cobalt (Co(II)TPP), zinc (Zn(II)TPP), and nickel (Ni(II)TPP) complexes, was added into the DCE phase as an ionophore for the facilitated proton transfer. After we irradiated the W/DCE interface through the W phase, the voltammetric waves for proton transfer facilitated by H2TPP and Co(II)TPP were remarkably enhanced and shifted to the lower potential region, compared to those before irradiation. We confirmed from the pH and argentometric titrations that such enhancements and shifts of the waves were caused by hydrogen chloride (HCI) produced by photodecomposition of DCE. On the other hand, the waves for proton transfer facilitated by Zn(II)TPP and Ni(II)TPP were very small from the beginning, and showed neither enhancement nor any shift upon irradiation.
資源タイプ（コンテンツの種類）
ISSN
収録物識別子タイプ ISSN
収録物識別子 0910-6340
書誌レコードID
収録物識別子タイプ NCID
収録物識別子 AA10500785
PubMed
識別子タイプ PMID
関連識別子 http://www.ncbi.nlm.nih.gov/entrez/query.fcgi?CMD=search&DB=pubmed&term=29225232
関連名称 29225232
権利
権利情報 © The Japan Society for Analytical Chemistry 2017
出版タイプ
出版タイプ VoR
出版タイプResource http://purl.org/coar/version/c_970fb48d4fbd8a85
WoS
URL http://gateway.isiknowledge.com/gateway/Gateway.cgi?&GWVersion=2&SrcAuth=ShinshuUniv&SrcApp=ShinshuUniv&DestLinkType=FullRecord&DestApp=WOS&KeyUT=000418784800016
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Cite as

Kubo, Tomoya, Ashida, Manaki, Otagiri, Shiori, Nozue, Haruka, Makigaki, Souma, Hinoue, Teruo, 2017, Effect of Ultraviolet Irradiation on Proton Transfer Facilitated by 5,10,15,20-Tetraphenyl-21H,23H-porphine and Its Metal Complexes at a Water/1,2-Dichloroethane Interface: JAPAN SOC ANALYTICAL CHEMISTRY, 1407–1413 p.
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