{"_buckets": {"deposit": "5aacd95b-899d-4c95-8e13-1ad8b4e9c07a"}, "_deposit": {"id": "19881", "owners": [], "pid": {"revision_id": 0, "type": "depid", "value": "19881"}, "status": "published"}, "_oai": {"id": "oai:soar-ir.repo.nii.ac.jp:00019881"}, "item_6_biblio_info_6": {"attribute_name": "\u66f8\u8a8c\u60c5\u5831", "attribute_value_mlt": [{"bibliographicIssueDates": {"bibliographicIssueDate": "2013-02", "bibliographicIssueDateType": "Issued"}, "bibliographicIssueNumber": "5", "bibliographicPageEnd": "964", "bibliographicPageStart": "957", "bibliographicVolumeNumber": "2013", "bibliographic_titles": [{"bibliographic_title": "EUROPEAN JOURNAL OF ORGANIC CHEMISTRY"}]}]}, "item_6_description_20": {"attribute_name": "\u6284\u9332", "attribute_value_mlt": [{"subitem_description": "Ene-diyne systems possessing 1- and 2-azulenyl groups at the periphery were prepared by palladium-catalyzed cross-coupling reaction of 1- and 2-ethynylazulenes with 9-di-bromomethylene-9H-fluorene and 9,10-bis(dibromomethylene)-9,10-dihydroanthracene or 2-iodoazulene with 9,10-bis(diethynylmethylene)-9,10-dihydroanthracene under Sonogashira-Hagihara conditions. The redox behavior of the ene-diyne compounds was examined by cyclic voltammetry (CV) and differential pulse voltammetry (DPV). Moreover, a significant color change of the ene-diyne derivatives was observed with visible spectroscopy under electrochemical reduction conditions.", "subitem_description_type": "Abstract"}]}, "item_6_description_30": {"attribute_name": "\u8cc7\u6e90\u30bf\u30a4\u30d7\uff08\u30b3\u30f3\u30c6\u30f3\u30c4\u306e\u7a2e\u985e\uff09", "attribute_value_mlt": [{"subitem_description": "Article", "subitem_description_type": "Other"}]}, "item_6_description_5": {"attribute_name": "\u5f15\u7528", "attribute_value_mlt": [{"subitem_description": "EUROPEAN JOURNAL OF ORGANIC CHEMISTRY. 2013(5):957-964 (2013)", "subitem_description_type": "Other"}]}, "item_6_link_3": {"attribute_name": "\u4fe1\u5dde\u5927\u5b66\u7814\u7a76\u8005\u7dcf\u89a7\u3078\u306e\u30ea\u30f3\u30af", "attribute_value_mlt": [{"subitem_link_text": "Shoji, Taku", "subitem_link_url": "http://soar-rd.shinshu-u.ac.jp/profile/ja.gmShOakh.html"}]}, "item_6_link_67": {"attribute_name": "WoS", "attribute_value_mlt": [{"subitem_link_text": "Web of Science", "subitem_link_url": "http://gateway.isiknowledge.com/gateway/Gateway.cgi?\u0026GWVersion=2\u0026SrcAuth=ShinshuUniv\u0026SrcApp=ShinshuUniv\u0026DestLinkType=FullRecord\u0026DestApp=WOS\u0026KeyUT=000316194800020"}]}, "item_6_publisher_4": {"attribute_name": "\u51fa\u7248\u8005", "attribute_value_mlt": [{"subitem_publisher": "WILEY-V C H VERLAG GMBH"}]}, "item_6_relation_48": {"attribute_name": "DOI", "attribute_value_mlt": [{"subitem_relation_name": [{"subitem_relation_name_text": "10.1002/ejoc.201201397"}], "subitem_relation_type_id": {"subitem_relation_type_id_text": "http://doi.org/10.1002/ejoc.201201397", "subitem_relation_type_select": "DOI"}}]}, "item_6_rights_62": {"attribute_name": "\u6a29\u5229", "attribute_value_mlt": [{"subitem_rights": "This is the peer reviewed version of the following article: Shoji, T. , Shimomura, E. , Maruyama, M. , Ito, S. , Okujima, T. and Morita, N. (2013), Synthesis, Properties and Redox Behavior of Ene\u2013Diyne Scaffolds Bearing 1\u2010 and 2\u2010Azulenyl Groups at the Periphery. Eur. J. Org. Chem., 2013: 957-964. doi:10.1002/ejoc.201201397, which has been published in final form at http://doi.org/10.1002/ejoc.201201397 . This article may be used for non-commercial purposes in accordance with Wiley Terms and Conditions for Self-Archiving."}]}, "item_6_select_64": {"attribute_name": "\u8457\u8005\u7248\u30d5\u30e9\u30b0", "attribute_value_mlt": [{"subitem_select_item": "author"}]}, "item_6_source_id_35": {"attribute_name": "ISSN", "attribute_value_mlt": [{"subitem_source_identifier": "1434-193X", "subitem_source_identifier_type": "ISSN"}]}, "item_6_source_id_39": {"attribute_name": "NII ISSN", "attribute_value_mlt": [{"subitem_source_identifier": "1434-193X", "subitem_source_identifier_type": "ISSN"}]}, "item_6_source_id_40": {"attribute_name": "\u66f8\u8a8c\u30ec\u30b3\u30fc\u30c9ID", "attribute_value_mlt": [{"subitem_source_identifier": "AA1118165X", "subitem_source_identifier_type": "NCID"}]}, "item_6_text_69": {"attribute_name": "wosonly authkey", "attribute_value_mlt": [{"subitem_text_value": "Azulene; Conjugation; Redox chemistry; Synthetic methods; Cyclic voltammetry"}]}, "item_6_text_70": {"attribute_name": "wosonly keywords", "attribute_value_mlt": [{"subitem_text_value": "LIQUID-CRYSTALLINE BEHAVIOR; PUSH-PULL CHROMOPHORES; VIOLENE/CYANINE HYBRIDS; ELECTROCHROMIC SYSTEMS; EXPANDED RADIALENES; GENERAL STRUCTURE; BENZENE-RING; DERIVATIVES; SPACERS; BIS"}]}, "item_6_textarea_68": {"attribute_name": "wosonly abstract", "attribute_value_mlt": [{"subitem_textarea_value": "Ene-diyne systems possessing 1- and 2-azulenyl groups at the periphery were prepared by palladium-catalyzed cross-coupling reaction of 1- and 2-ethynylazulenes with 9-di-bromomethylene-9H-fluorene and 9,10-bis(dibromomethylene)-9,10-dihydroanthracene or 2-iodoazulene with 9,10-bis(diethynylmethylene)-9,10-dihydroanthracene under Sonogashira-Hagihara conditions. The redox behavior of the ene-diyne compounds was examined by cyclic voltammetry (CV) and differential pulse voltammetry (DPV). Moreover, a significant color change of the ene-diyne derivatives was observed with visible spectroscopy under electrochemical reduction conditions."}]}, "item_creator": {"attribute_name": "\u8457\u8005", "attribute_type": "creator", "attribute_value_mlt": [{"creatorNames": [{"creatorName": "Shoji, Taku"}], "nameIdentifiers": [{"nameIdentifier": "105703", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Shimomura, Erika"}], "nameIdentifiers": [{"nameIdentifier": "105704", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Maruyama, Mitsuhisa"}], "nameIdentifiers": [{"nameIdentifier": "105705", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Ito, Shunji"}], "nameIdentifiers": [{"nameIdentifier": "105706", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Okujima, Tetsuo"}], "nameIdentifiers": [{"nameIdentifier": "105707", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Morita, Noboru"}], "nameIdentifiers": [{"nameIdentifier": "105708", "nameIdentifierScheme": "WEKO"}]}]}, "item_files": {"attribute_name": "\u30d5\u30a1\u30a4\u30eb\u60c5\u5831", "attribute_type": "file", "attribute_value_mlt": [{"accessrole": "open_date", "date": [{"dateType": "Available", "dateValue": "2018-06-13"}], "displaytype": "detail", "download_preview_message": "", "file_order": 0, "filename": "Eur_J_Org_Chem_2013_957-964.pdf", "filesize": [{"value": "747.9 kB"}], "format": "application/pdf", "future_date_message": "", "is_thumbnail": false, "licensefree": "This is the peer reviewed version of the following article: Shoji, T. , Shimomura, E. , Maruyama, M. , Ito, S. , Okujima, T. and Morita, N. (2013), Synthesis, Properties and Redox Behavior of Ene\u2013Diyne Scaffolds Bearing 1\u2010 and 2\u2010Azulenyl Groups at the Periphery. Eur. J. Org. Chem., 2013: 957-964. doi:10.1002/ejoc.201201397, which has been published in final form at http://doi.org/10.1002/ejoc.201201397 . This article may be used for non-commercial purposes in accordance with Wiley Terms and Conditions for Self-Archiving.", "licensetype": "license_free", "mimetype": "application/pdf", "size": 747900.0, "url": {"label": "Eur_J_Org_Chem_2013_957-964.pdf", "url": "https://soar-ir.repo.nii.ac.jp/record/19881/files/Eur_J_Org_Chem_2013_957-964.pdf"}, "version_id": "741d15f7-77ce-4deb-b72a-fd51d58b03a6"}]}, "item_keyword": {"attribute_name": "\u30ad\u30fc\u30ef\u30fc\u30c9", "attribute_value_mlt": [{"subitem_subject": "Azulene", "subitem_subject_scheme": "Other"}, {"subitem_subject": "Conjugation", "subitem_subject_scheme": "Other"}, {"subitem_subject": "Redox chemistry", "subitem_subject_scheme": "Other"}, {"subitem_subject": "Synthetic methods", "subitem_subject_scheme": "Other"}, {"subitem_subject": "Cyclic voltammetry", "subitem_subject_scheme": "Other"}]}, "item_language": {"attribute_name": "\u8a00\u8a9e", "attribute_value_mlt": [{"subitem_language": "eng"}]}, "item_resource_type": {"attribute_name": "\u8cc7\u6e90\u30bf\u30a4\u30d7", "attribute_value_mlt": [{"resourcetype": "journal article", "resourceuri": "http://purl.org/coar/resource_type/c_6501"}]}, "item_title": "Synthesis, Properties and Redox Behavior of Ene-Diyne Scaffolds Bearing 1- and 2-Azulenyl Groups at the Periphery", "item_titles": {"attribute_name": "\u30bf\u30a4\u30c8\u30eb", "attribute_value_mlt": [{"subitem_title": "Synthesis, Properties and Redox Behavior of Ene-Diyne Scaffolds Bearing 1- and 2-Azulenyl Groups at the Periphery"}]}, "item_type_id": "6", "owner": "1", "path": ["1169/1170"], "permalink_uri": "http://hdl.handle.net/10091/00020642", "pubdate": {"attribute_name": "\u516c\u958b\u65e5", "attribute_name_i18n": "\u516c\u958b\u65e5", "attribute_value": "2018-06-13"}, "publish_date": "2018-06-13", "publish_status": "0", "recid": "19881", "relation": {}, "relation_version_is_last": true, "title": ["Synthesis, Properties and Redox Behavior of Ene-Diyne Scaffolds Bearing 1- and 2-Azulenyl Groups at the Periphery"], "weko_shared_id": 3}