ログイン
言語:

WEKO3

  • トップ
  • ランキング
To
lat lon distance
To

Field does not validate



インデックスリンク

インデックスツリー

メールアドレスを入力してください。

WEKO

One fine body…

WEKO

One fine body…

アイテム

{"_buckets": {"deposit": "83f2776b-857b-423f-90c8-e3a03926eed8"}, "_deposit": {"id": "19882", "owners": [], "pid": {"revision_id": 0, "type": "depid", "value": "19882"}, "status": "published"}, "_oai": {"id": "oai:soar-ir.repo.nii.ac.jp:00019882", "sets": ["1170"]}, "author_link": ["105709", "105710", "105711", "105712", "105713", "105714"], "item_1628147817048": {"attribute_name": "出版タイプ", "attribute_value_mlt": [{"subitem_version_resource": "http://purl.org/coar/version/c_ab4af688f83e57aa", "subitem_version_type": "AM"}]}, "item_6_biblio_info_6": {"attribute_name": "書誌情報", "attribute_value_mlt": [{"bibliographicIssueDates": {"bibliographicIssueDate": "2014-09-08", "bibliographicIssueDateType": "Issued"}, "bibliographicIssueNumber": "37", "bibliographicPageEnd": "11912", "bibliographicPageStart": "11903", "bibliographicVolumeNumber": "20", "bibliographic_titles": [{"bibliographic_title": "CHEMISTRY-A EUROPEAN JOURNAL"}]}]}, "item_6_description_20": {"attribute_name": "抄録", "attribute_value_mlt": [{"subitem_description": "1,3-Bis(azulenylethynyl)azulene derivatives 9-14 have been prepared by palladium-catalyzed alkynylation of 1-ethynylazulene 8 with 1,3-diiodoazulene 1 or 1,3-diethynylazulene 2 with the corresponding haloazulenes 3-7 under Sonogashira-Hagihara conditions. Bis(alkynes) 9-14 reacted with tetracyanoethylene (TCNE) in a formal [2+2] cycloaddition-retroelectrocyclization reaction to afford the corresponding new bis(tetracyanobutadiene)s (bis(TCBDs)) 15-20 in excellent yields. The redox behavior of bis(TCBD)s 15-20 was examined by using CV and differential pulse voltammetry (DPV), which revealed their reversible multistage reduction properties under the electrochemical conditions. Moreover, a significant color change of alkynes 9-14 and TCBDs 15-20 was observed by visible spectroscopy under the electrochemical reduction conditions.", "subitem_description_type": "Abstract"}]}, "item_6_description_30": {"attribute_name": "資源タイプ(コンテンツの種類)", "attribute_value_mlt": [{"subitem_description": "Article", "subitem_description_type": "Other"}]}, "item_6_description_5": {"attribute_name": "引用", "attribute_value_mlt": [{"subitem_description": "CHEMISTRY-A EUROPEAN JOURNAL. 15(18):11903-11912 (2014)", "subitem_description_type": "Other"}]}, "item_6_link_3": {"attribute_name": "信州大学研究者総覧へのリンク", "attribute_value_mlt": [{"subitem_link_text": "Shoji, Taku", "subitem_link_url": "http://soar-rd.shinshu-u.ac.jp/profile/ja.gmShOakh.html"}]}, "item_6_link_67": {"attribute_name": "WoS", "attribute_value_mlt": [{"subitem_link_text": "Web of Science", "subitem_link_url": "http://gateway.isiknowledge.com/gateway/Gateway.cgi?\u0026GWVersion=2\u0026SrcAuth=ShinshuUniv\u0026SrcApp=ShinshuUniv\u0026DestLinkType=FullRecord\u0026DestApp=WOS\u0026KeyUT=000341630500039"}]}, "item_6_publisher_4": {"attribute_name": "出版者", "attribute_value_mlt": [{"subitem_publisher": "WILEY-V C H VERLAG GMBH"}]}, "item_6_relation_47": {"attribute_name": "PubMed", "attribute_value_mlt": [{"subitem_relation_name": [{"subitem_relation_name_text": "25098400"}], "subitem_relation_type_id": {"subitem_relation_type_id_text": "http://www.ncbi.nlm.nih.gov/entrez/query.fcgi?CMD=search\u0026DB=pubmed\u0026term=25098400", "subitem_relation_type_select": "PMID"}}]}, "item_6_relation_48": {"attribute_name": "DOI", "attribute_value_mlt": [{"subitem_relation_name": [{"subitem_relation_name_text": "10.1002/chem.201402939"}], "subitem_relation_type_id": {"subitem_relation_type_id_text": "https://doi.org/10.1002/chem.201402939", "subitem_relation_type_select": "DOI"}}]}, "item_6_rights_62": {"attribute_name": "権利", "attribute_value_mlt": [{"subitem_rights": "This is the peer reviewed version of the following article: Shoji, T. , Maruyama, M. , Maruyama, A. , Ito, S. , Okujima, T. and Toyota, K. (2014), Synthesis of 1,3‐Bis(tetracyano‐2‐azulenyl‐3‐butadienyl)azulenes by the [2+2] Cycloaddition–Retroelectrocyclization of 1,3‐Bis(azulenylethynyl)azulenes with Tetracyanoethylene. Chem. Eur. J., 20: 11903-11912. doi:10.1002/chem.201402939, which has been published in final form at |https://doi.org/10.1002/chem.201402939 . This article may be used for non-commercial purposes in accordance with Wiley Terms and Conditions for Self-Archiving."}]}, "item_6_select_64": {"attribute_name": "著者版フラグ", "attribute_value_mlt": [{"subitem_select_item": "author"}]}, "item_6_source_id_35": {"attribute_name": "ISSN", "attribute_value_mlt": [{"subitem_source_identifier": "0947-6539", "subitem_source_identifier_type": "ISSN"}]}, "item_6_source_id_39": {"attribute_name": "NII ISSN", "attribute_value_mlt": [{"subitem_source_identifier": "0947-6539", "subitem_source_identifier_type": "ISSN"}]}, "item_6_source_id_40": {"attribute_name": "書誌レコードID", "attribute_value_mlt": [{"subitem_source_identifier": "AA11076269", "subitem_source_identifier_type": "NCID"}]}, "item_6_text_69": {"attribute_name": "wosonly authkey", "attribute_value_mlt": [{"subitem_text_value": "azulene; cycloadditions; donor-acceptor system; electrochemistry; redox chemistry"}]}, "item_6_text_70": {"attribute_name": "wosonly keywords", "attribute_value_mlt": [{"subitem_text_value": "CHARGE-TRANSFER INTERACTIONS; PUSH-PULL CHROMOPHORES; DONOR-ACCEPTOR CHROMOPHORES; N-CONTAINING HETEROCYCLES; REDOX BEHAVIOR; VIOLENE/CYANINE HYBRIDS; ELECTROPHILIC SUBSTITUTION; ELECTROCHROMIC SYSTEMS; CONVENIENT SYNTHESIS; GENERAL STRUCTURE"}]}, "item_6_textarea_68": {"attribute_name": "wosonly abstract", "attribute_value_mlt": [{"subitem_textarea_value": "1,3-Bis(azulenylethynyl)azulene derivatives 9-14 have been prepared by palladium-catalyzed alkynylation of 1-ethynylazulene 8 with 1,3-diiodoazulene 1 or 1,3-diethynylazulene 2 with the corresponding haloazulenes 3-7 under Sonogashira-Hagihara conditions. Bis(alkynes) 9-14 reacted with tetracyanoethylene (TCNE) in a formal [2+2] cycloaddition-retroelectrocyclization reaction to afford the corresponding new bis(tetracyanobutadiene)s (bis(TCBDs)) 15-20 in excellent yields. The redox behavior of bis(TCBD)s 15-20 was examined by using CV and differential pulse voltammetry (DPV), which revealed their reversible multistage reduction properties under the electrochemical conditions. Moreover, a significant color change of alkynes 9-14 and TCBDs 15-20 was observed by visible spectroscopy under the electrochemical reduction conditions."}]}, "item_creator": {"attribute_name": "著者", "attribute_type": "creator", "attribute_value_mlt": [{"creatorNames": [{"creatorName": "Shoji, Taku"}], "nameIdentifiers": [{"nameIdentifier": "105709", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Maruyama, Mitsuhisa"}], "nameIdentifiers": [{"nameIdentifier": "105710", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Maruyama, Akifumi"}], "nameIdentifiers": [{"nameIdentifier": "105711", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Ito, Shunji"}], "nameIdentifiers": [{"nameIdentifier": "105712", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Okujima, Tetsuo"}], "nameIdentifiers": [{"nameIdentifier": "105713", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Toyota, Kozo"}], "nameIdentifiers": [{"nameIdentifier": "105714", "nameIdentifierScheme": "WEKO"}]}]}, "item_files": {"attribute_name": "ファイル情報", "attribute_type": "file", "attribute_value_mlt": [{"accessrole": "open_date", "date": [{"dateType": "Available", "dateValue": "2018-06-13"}], "displaytype": "detail", "download_preview_message": "", "file_order": 0, "filename": "Chem_Eur_J_20_11903-11912.pdf", "filesize": [{"value": "461.2 kB"}], "format": "application/pdf", "future_date_message": "", "is_thumbnail": false, "licensefree": "This is the peer reviewed version of the following article: Shoji, T. , Maruyama, M. , Maruyama, A. , Ito, S. , Okujima, T. and Toyota, K. (2014), Synthesis of 1,3‐Bis(tetracyano‐2‐azulenyl‐3‐butadienyl)azulenes by the [2+2] Cycloaddition–Retroelectrocyclization of 1,3‐Bis(azulenylethynyl)azulenes with Tetracyanoethylene. Chem. Eur. J., 20: 11903-11912. doi:10.1002/chem.201402939, which has been published in final form at |https://doi.org/10.1002/chem.201402939 . This article may be used for non-commercial purposes in accordance with Wiley Terms and Conditions for Self-Archiving.", "licensetype": "license_note", "mimetype": "application/pdf", "size": 461200.0, "url": {"label": "Chem_Eur_J_20_11903-11912.pdf", "url": "https://soar-ir.repo.nii.ac.jp/record/19882/files/Chem_Eur_J_20_11903-11912.pdf"}, "version_id": "ebb211ac-3aa1-4281-a928-8b60d3e48348"}]}, "item_keyword": {"attribute_name": "キーワード", "attribute_value_mlt": [{"subitem_subject": "azulene", "subitem_subject_scheme": "Other"}, {"subitem_subject": "cycloadditions", "subitem_subject_scheme": "Other"}, {"subitem_subject": "donor-acceptor system", "subitem_subject_scheme": "Other"}, {"subitem_subject": "electrochemistry", "subitem_subject_scheme": "Other"}, {"subitem_subject": "redox chemistry", "subitem_subject_scheme": "Other"}]}, "item_language": {"attribute_name": "言語", "attribute_value_mlt": [{"subitem_language": "eng"}]}, "item_resource_type": {"attribute_name": "資源タイプ", "attribute_value_mlt": [{"resourcetype": "journal article", "resourceuri": "http://purl.org/coar/resource_type/c_6501"}]}, "item_title": "Synthesis of 1,3-Bis(tetracyano-2-azulenyl-3-butadienyl)azulenes by the [2+2] Cycloaddition-Retroelectrocyclization of 1,3-Bis(azulenylethynyl)azulenes with Tetracyanoethylene", "item_titles": {"attribute_name": "タイトル", "attribute_value_mlt": [{"subitem_title": "Synthesis of 1,3-Bis(tetracyano-2-azulenyl-3-butadienyl)azulenes by the [2+2] Cycloaddition-Retroelectrocyclization of 1,3-Bis(azulenylethynyl)azulenes with Tetracyanoethylene", "subitem_title_language": "en"}]}, "item_type_id": "6", "owner": "1", "path": ["1170"], "permalink_uri": "http://hdl.handle.net/10091/00020643", "pubdate": {"attribute_name": "PubDate", "attribute_value": "2018-06-13"}, "publish_date": "2018-06-13", "publish_status": "0", "recid": "19882", "relation": {}, "relation_version_is_last": true, "title": ["Synthesis of 1,3-Bis(tetracyano-2-azulenyl-3-butadienyl)azulenes by the [2+2] Cycloaddition-Retroelectrocyclization of 1,3-Bis(azulenylethynyl)azulenes with Tetracyanoethylene"], "weko_shared_id": -1}
  1. 040 理学部
  2. 0401 学術論文

Synthesis of 1,3-Bis(tetracyano-2-azulenyl-3-butadienyl)azulenes by the [2+2] Cycloaddition-Retroelectrocyclization of 1,3-Bis(azulenylethynyl)azulenes with Tetracyanoethylene

http://hdl.handle.net/10091/00020643
http://hdl.handle.net/10091/00020643
b8d2f17e-ff88-4ee7-a2f2-6f46a890646e
名前 / ファイル ライセンス アクション
Chem_Eur_J_20_11903-11912.pdf Chem_Eur_J_20_11903-11912.pdf (461.2 kB)
Item type 学術雑誌論文 / Journal Article(1)
公開日 2018-06-13
タイトル
言語 en
タイトル Synthesis of 1,3-Bis(tetracyano-2-azulenyl-3-butadienyl)azulenes by the [2+2] Cycloaddition-Retroelectrocyclization of 1,3-Bis(azulenylethynyl)azulenes with Tetracyanoethylene
言語
言語 eng
キーワード
主題Scheme Other
主題 azulene
キーワード
主題Scheme Other
主題 cycloadditions
キーワード
主題Scheme Other
主題 donor-acceptor system
キーワード
主題Scheme Other
主題 electrochemistry
キーワード
主題Scheme Other
主題 redox chemistry
資源タイプ
資源 http://purl.org/coar/resource_type/c_6501
タイプ journal article
著者 Shoji, Taku

× Shoji, Taku

WEKO 105709

Shoji, Taku

Search repository
Maruyama, Mitsuhisa

× Maruyama, Mitsuhisa

WEKO 105710

Maruyama, Mitsuhisa

Search repository
Maruyama, Akifumi

× Maruyama, Akifumi

WEKO 105711

Maruyama, Akifumi

Search repository
Ito, Shunji

× Ito, Shunji

WEKO 105712

Ito, Shunji

Search repository
Okujima, Tetsuo

× Okujima, Tetsuo

WEKO 105713

Okujima, Tetsuo

Search repository
Toyota, Kozo

× Toyota, Kozo

WEKO 105714

Toyota, Kozo

Search repository
信州大学研究者総覧へのリンク
氏名 Shoji, Taku
URL http://soar-rd.shinshu-u.ac.jp/profile/ja.gmShOakh.html
出版者
出版者 WILEY-V C H VERLAG GMBH
引用
内容記述タイプ Other
内容記述 CHEMISTRY-A EUROPEAN JOURNAL. 15(18):11903-11912 (2014)
書誌情報 CHEMISTRY-A EUROPEAN JOURNAL

巻 20, 号 37, p. 11903-11912, 発行日 2014-09-08
抄録
内容記述タイプ Abstract
内容記述 1,3-Bis(azulenylethynyl)azulene derivatives 9-14 have been prepared by palladium-catalyzed alkynylation of 1-ethynylazulene 8 with 1,3-diiodoazulene 1 or 1,3-diethynylazulene 2 with the corresponding haloazulenes 3-7 under Sonogashira-Hagihara conditions. Bis(alkynes) 9-14 reacted with tetracyanoethylene (TCNE) in a formal [2+2] cycloaddition-retroelectrocyclization reaction to afford the corresponding new bis(tetracyanobutadiene)s (bis(TCBDs)) 15-20 in excellent yields. The redox behavior of bis(TCBD)s 15-20 was examined by using CV and differential pulse voltammetry (DPV), which revealed their reversible multistage reduction properties under the electrochemical conditions. Moreover, a significant color change of alkynes 9-14 and TCBDs 15-20 was observed by visible spectroscopy under the electrochemical reduction conditions.
資源タイプ(コンテンツの種類)
内容記述タイプ Other
内容記述 Article
ISSN
収録物識別子タイプ ISSN
収録物識別子 0947-6539
書誌レコードID
収録物識別子タイプ NCID
収録物識別子 AA11076269
PubMed
識別子タイプ PMID
関連識別子 http://www.ncbi.nlm.nih.gov/entrez/query.fcgi?CMD=search&DB=pubmed&term=25098400
関連名称 25098400
DOI
識別子タイプ DOI
関連識別子 https://doi.org/10.1002/chem.201402939
関連名称 10.1002/chem.201402939
権利
権利情報 This is the peer reviewed version of the following article: Shoji, T. , Maruyama, M. , Maruyama, A. , Ito, S. , Okujima, T. and Toyota, K. (2014), Synthesis of 1,3‐Bis(tetracyano‐2‐azulenyl‐3‐butadienyl)azulenes by the [2+2] Cycloaddition–Retroelectrocyclization of 1,3‐Bis(azulenylethynyl)azulenes with Tetracyanoethylene. Chem. Eur. J., 20: 11903-11912. doi:10.1002/chem.201402939, which has been published in final form at |https://doi.org/10.1002/chem.201402939 . This article may be used for non-commercial purposes in accordance with Wiley Terms and Conditions for Self-Archiving.
出版タイプ
出版タイプ AM
出版タイプResource http://purl.org/coar/version/c_ab4af688f83e57aa
WoS
表示名 Web of Science
URL http://gateway.isiknowledge.com/gateway/Gateway.cgi?&GWVersion=2&SrcAuth=ShinshuUniv&SrcApp=ShinshuUniv&DestLinkType=FullRecord&DestApp=WOS&KeyUT=000341630500039
戻る
0
views
See details
Views

Versions

Ver.1 2021-03-01 08:23:48.362523
Show All versions

Share

Mendeley Twitter Facebook Print Addthis

Cite as

エクスポート

OAI-PMH
  • OAI-PMH JPCOAR
  • OAI-PMH DublinCore
  • OAI-PMH DDI
Other Formats
  • JSON
  • BIBTEX

Confirm


Powered by WEKO3


Powered by WEKO3