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Azulene-Based Donor-Acceptor Systems: Synthesis, Optical, and Electrochemical Properties
http://hdl.handle.net/10091/00020651
http://hdl.handle.net/10091/00020651db2f3977-1c2c-48d2-bd3a-8c7b3a7843c1
| 名前 / ファイル | ライセンス | アクション |
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Chem_Eur_J_2017_23_16696.pdf (1.3 MB)
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| Item type | 学術雑誌論文 / Journal Article(1) | |||||||||
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| 公開日 | 2018-06-13 | |||||||||
| タイトル | ||||||||||
| タイトル | Azulene-Based Donor-Acceptor Systems: Synthesis, Optical, and Electrochemical Properties | |||||||||
| 言語 | ||||||||||
| 言語 | eng | |||||||||
| DOI | ||||||||||
| 関連識別子 | https://doi.org/10.1002/chem.201702806 | |||||||||
| 関連名称 | 10.1002/chem.201702806 | |||||||||
| キーワード | ||||||||||
| 主題 | azulene, cycloaddition, donor-acceptor system, heteroazulene, redox chemistry | |||||||||
| 資源タイプ | ||||||||||
| 資源 | http://purl.org/coar/resource_type/c_6501 | |||||||||
| タイプ | journal article | |||||||||
| 著者 |
Shoji, Taku
× Shoji, Taku
× Ito, Shunji
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| 信州大学研究者総覧へのリンク | ||||||||||
| 氏名 | Shoji, Taku | |||||||||
| URL | http://soar-rd.shinshu-u.ac.jp/profile/ja.gmShOakh.html | |||||||||
| 出版者 | ||||||||||
| 出版者 | WILEY-V C H VERLAG GMBH | |||||||||
| 引用 | ||||||||||
| 内容記述 | CHEMISTRY-A EUROPEAN JOURNAL. 95(1):16696-16709 (2017) | |||||||||
| 書誌情報 |
CHEMISTRY-A EUROPEAN JOURNAL 巻 23, 号 66, p. 16696-16709, 発行日 2017-11-27 |
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| 内容記述 | ||||||||||
| 内容記述タイプ | Other | |||||||||
| 内容記述 | First published: 07 Aug 2017 | |||||||||
| 抄録 | ||||||||||
| 内容記述 | We describe the synthesis and properties of azulene-substituted 1,1,4,4-tetracyanobutadienes (AzTCBDs) and heteroazulenyl TCBDs. TCBD derivatives were prepared in good to excellent yields through reaction of the corresponding 1-ethynylazulenes with tetracyanoethylene (TCNE). In contrast, the reaction between propargyl alcohols and the 1-azulenyl group in TCNE generated 2-aminofuran derivatives, which were transformed into 6-aminofulvenes with a 1-azulenyl substituent upon treatment with several amines. The optical and electrochemical properties of the AzTCBDs were clarified by UV/Vis and voltammetry. The AzTCBD derivatives exhibited electrochromism, showing a multi-step color change under electrochemical redox conditions. The multistage redox properties of AzTCBDs could be useful for the development of novel organic electronic materials. | |||||||||
| 資源タイプ（コンテンツの種類） | ||||||||||
| ISSN | ||||||||||
| 収録物識別子タイプ | ISSN | |||||||||
| 収録物識別子 | 0947-6539 | |||||||||
| 書誌レコードID | ||||||||||
| 収録物識別子タイプ | NCID | |||||||||
| 収録物識別子 | AA11076269 | |||||||||
| PubMed | ||||||||||
| 識別子タイプ | PMID | |||||||||
| 関連識別子 | http://www.ncbi.nlm.nih.gov/entrez/query.fcgi?CMD=search&DB=pubmed&term=28786146 | |||||||||
| 関連名称 | 28786146 | |||||||||
| 権利 | ||||||||||
| 権利情報 | This is the peer reviewed version of the following article: T. Shoji, S. Ito, Chem. Eur. J. 2017, 23, 16696. , which has been published in final form at https://doi.org/10.1002/chem.201702806 . This article may be used for non-commercial purposes in accordance with Wiley Terms and Conditions for Self-Archiving. | |||||||||
| 出版タイプ | ||||||||||
| 出版タイプ | AM | |||||||||
| 出版タイプResource | http://purl.org/coar/version/c_ab4af688f83e57aa | |||||||||
| WoS | ||||||||||
| URL | http://gateway.isiknowledge.com/gateway/Gateway.cgi?&GWVersion=2&SrcAuth=ShinshuUniv&SrcApp=ShinshuUniv&DestLinkType=FullRecord&DestApp=WOS&KeyUT=000416549200001 | |||||||||
