| Item type |
学術雑誌論文 / Journal Article(1) |
| 公開日 |
2019-01-30 |
| タイトル |
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タイトル |
Direct Visualization of the Two-step Nucleation Model by Fluorescence Color Changes during Evaporative Crystallization from Solution |
| 言語 |
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言語 |
eng |
| DOI |
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関連識別子 |
https://doi.org/10.1038/srep22918 |
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関連名称 |
10.1038/srep22918 |
| 資源タイプ |
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資源 |
http://purl.org/coar/resource_type/c_6501 |
|
タイプ |
journal article |
| 著者 |
Ito, Fuyuki
Suzuki, Yukino
Fujimori, Jun-ichi
Sagawa, Takehiro
Hara, Mitsuo
Seki, Takahiro
Yasukuni, Ryohei
de, la Chapelle Marc Lamy
|
| 信州大学研究者総覧へのリンク |
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氏名 |
Ito, Fuyuki |
|
URL |
http://soar-rd.shinshu-u.ac.jp/profile/ja.yCAebCDV.html |
| 出版者 |
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出版者 |
Nature Research |
| 引用 |
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内容記述 |
Scientific Reports.6:22918(2016) |
| 書誌情報 |
Scientific Reports
巻 6,
p. 22918,
発行日 2016-03-08
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| 抄録 |
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内容記述 |
The two-step nucleation model for crystal nuclei formation explains several experimental and theoretical results better than the classical nucleation theory. We report here direct visualization of the two-step nucleation model for organic molecular crystallization. Evaporative crystallization from a solution of a dibenzoylmethane boron complex that displays mechanofluorochromism, a fluorescence color change induced by mechanical perturbation, was probed by fluorescence change. The dependence of fluorescence change on dispersion concentration of the complex in a polymer matrix was also investigated. We detected transitional emission from the amorphous cluster state prior to crystallization. This is the first demonstration of the two-step nucleation model based on fluorescence color changes. |
| 資源タイプ（コンテンツの種類） |
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| ISSN |
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収録物識別子タイプ |
ISSN |
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収録物識別子 |
2045-2322 |
| PubMed |
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識別子タイプ |
PMID |
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関連識別子 |
https://www.ncbi.nlm.nih.gov/pubmed/26953165 |
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関連名称 |
26953165 |
| 権利 |
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権利情報 |
This work is licensed under a Creative Commons Attribution 4.0 International License. The images or other third party material in this article are included in the article’s Creative Commons license, unless indicated otherwise in the credit line; if the material is not included under the Creative Commons license, users will need to obtain permission from the license holder to reproduce the material. To view a copy of this license, visit http://creativecommons.org/licenses/by/4.0/ |
| 出版タイプ |
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出版タイプ |
VoR |
|
出版タイプResource |
http://purl.org/coar/version/c_970fb48d4fbd8a85 |
| WoS |
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URL |
http://gateway.isiknowledge.com/gateway/Gateway.cgi?&GWVersion=2&SrcAuth=ShinshuUniv&SrcApp=ShinshuUniv&DestLinkType=FullRecord&DestApp=WOS&KeyUT=000371589900001 |
26410009_04.pdf (785.1 kB)
