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  1. 080 繊維学部
  2. 0801 学術論文

Physical gelation by amides derived from trans-1, 2-diaminocyclohexane and their tetrasiloxane-based gelators

http://hdl.handle.net/10091/00021968
http://hdl.handle.net/10091/00021968
2e868d7c-618b-4fda-b6b7-8382dc772f09
名前 / ファイル ライセンス アクション
15K05623_04.pdf 15K05623_04.pdf (1.0 MB)
Item type 学術雑誌論文 / Journal Article(1)
公開日 2020-03-12
タイトル
言語 en
タイトル Physical gelation by amides derived from trans-1, 2-diaminocyclohexane and their tetrasiloxane-based gelators
言語
言語 eng
資源タイプ
資源 http://purl.org/coar/resource_type/c_6501
タイプ journal article
著者 Nakagawa, Haruka

× Nakagawa, Haruka

WEKO 109146

Nakagawa, Haruka

Search repository
Suzuki, Masahiro

× Suzuki, Masahiro

WEKO 109147

Suzuki, Masahiro

Search repository
Hanabusa, Kenji

× Hanabusa, Kenji

WEKO 109148

Hanabusa, Kenji

Search repository
信州大学研究者総覧へのリンク
氏名 Suzuki, Masahiro
URL http://soar-rd.shinshu-u.ac.jp/profile/ja.WVnmjFkV.html
信州大学研究者総覧へのリンク
氏名 Hanabusa, Kenji
URL http://soar-rd.shinshu-u.ac.jp/profile/ja.WCyNjekV.html
出版者
出版者 NATURE PUBLISHING GROUP
引用
内容記述タイプ Other
内容記述 POLYMER JOURNAL.49(5):439-447(2017)
書誌情報 POLYMER JOURNAL

巻 49, 号 5, p. 439-447, 発行日 2017-02-08
抄録
内容記述タイプ Abstract
内容記述 Four compounds were prepared from trans-1,2-diaminocyclohexane and were subsequently studied as gelators. These two compounds were chiral trans-(1R,2R)-1-(2-heptylundecanoylamino)-2-(10-undecenoylamino) cyclohexane and the corresponding racemate. The other two compounds were 1,1,3,3,5,5,7,7-octamethyltetrasiloxane-containing chiral and racemic compounds prepared by a hydrosilylation reaction. Their gelation abilities were evaluated on the basis of the minimum gel concentration, using seven solvents. The thermal stability and transparency of the gels were investigated by UV-vis spectroscopy using three-component mixed solvents of hexadecyl 2-ethylhexanoate, liquid paraffin, and decamethylcyclopentasiloxane (66 combinations). The gel-to-sol phase-transition temperatures were also studied. The viscoelastic behavior of the gels was studied by rheology measurements in the strain sweep mode. Aggregates consisting of three-dimensional networks were studied by transmission electron microscopy. Circular dichroism spectroscopy was performed to verify the existence of helical aggregates in the gel.
資源タイプ(コンテンツの種類)
内容記述タイプ Other
内容記述 Article
ISSN
収録物識別子タイプ ISSN
収録物識別子 0032-3896
書誌レコードID
収録物識別子タイプ NCID
収録物識別子 AA00777013
DOI
識別子タイプ DOI
関連識別子 https://doi.org/10.1038/pj.2017.1
関連名称 10.1038/pj.2017.1
出版タイプ
出版タイプ AM
出版タイプResource http://purl.org/coar/version/c_ab4af688f83e57aa
WoS
表示名 Web of Science
URL http://gateway.isiknowledge.com/gateway/Gateway.cgi?&GWVersion=2&SrcAuth=ShinshuUniv&SrcApp=ShinshuUniv&DestLinkType=FullRecord&DestApp=WOS&KeyUT=000400928700005
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