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Physical gelation by amides derived from trans-1, 2-diaminocyclohexane and their tetrasiloxane-based gelators
http://hdl.handle.net/10091/00021968
http://hdl.handle.net/10091/000219682e868d7c-618b-4fda-b6b7-8382dc772f09
| 名前 / ファイル | ライセンス | アクション |
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15K05623_04.pdf (1.0 MB)
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| Item type | 学術雑誌論文 / Journal Article(1) | |||||||||||
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| 公開日 | 2020-03-12 | |||||||||||
| タイトル | ||||||||||||
| タイトル | Physical gelation by amides derived from trans-1, 2-diaminocyclohexane and their tetrasiloxane-based gelators | |||||||||||
| 言語 | ||||||||||||
| 言語 | eng | |||||||||||
| DOI | ||||||||||||
| 関連識別子 | https://doi.org/10.1038/pj.2017.1 | |||||||||||
| 関連名称 | 10.1038/pj.2017.1 | |||||||||||
| 資源タイプ | ||||||||||||
| 資源 | http://purl.org/coar/resource_type/c_6501 | |||||||||||
| タイプ | journal article | |||||||||||
| 著者 |
Nakagawa, Haruka
× Nakagawa, Haruka
× Suzuki, Masahiro
× Hanabusa, Kenji
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| 信州大学研究者総覧へのリンク | ||||||||||||
| 氏名 | Suzuki, Masahiro | |||||||||||
| URL | http://soar-rd.shinshu-u.ac.jp/profile/ja.WVnmjFkV.html | |||||||||||
| 信州大学研究者総覧へのリンク | ||||||||||||
| 氏名 | Hanabusa, Kenji | |||||||||||
| URL | http://soar-rd.shinshu-u.ac.jp/profile/ja.WCyNjekV.html | |||||||||||
| 出版者 | ||||||||||||
| 出版者 | NATURE PUBLISHING GROUP | |||||||||||
| 引用 | ||||||||||||
| 内容記述 | POLYMER JOURNAL.49(5):439-447(2017) | |||||||||||
| 書誌情報 |
POLYMER JOURNAL 巻 49, 号 5, p. 439-447, 発行日 2017-02-08 |
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| 抄録 | ||||||||||||
| 内容記述 | Four compounds were prepared from trans-1,2-diaminocyclohexane and were subsequently studied as gelators. These two compounds were chiral trans-(1R,2R)-1-(2-heptylundecanoylamino)-2-(10-undecenoylamino) cyclohexane and the corresponding racemate. The other two compounds were 1,1,3,3,5,5,7,7-octamethyltetrasiloxane-containing chiral and racemic compounds prepared by a hydrosilylation reaction. Their gelation abilities were evaluated on the basis of the minimum gel concentration, using seven solvents. The thermal stability and transparency of the gels were investigated by UV-vis spectroscopy using three-component mixed solvents of hexadecyl 2-ethylhexanoate, liquid paraffin, and decamethylcyclopentasiloxane (66 combinations). The gel-to-sol phase-transition temperatures were also studied. The viscoelastic behavior of the gels was studied by rheology measurements in the strain sweep mode. Aggregates consisting of three-dimensional networks were studied by transmission electron microscopy. Circular dichroism spectroscopy was performed to verify the existence of helical aggregates in the gel. | |||||||||||
| 資源タイプ（コンテンツの種類） | ||||||||||||
| ISSN | ||||||||||||
| 収録物識別子タイプ | ISSN | |||||||||||
| 収録物識別子 | 0032-3896 | |||||||||||
| 書誌レコードID | ||||||||||||
| 収録物識別子タイプ | NCID | |||||||||||
| 収録物識別子 | AA00777013 | |||||||||||
| 出版タイプ | ||||||||||||
| 出版タイプ | AM | |||||||||||
| 出版タイプResource | http://purl.org/coar/version/c_ab4af688f83e57aa | |||||||||||
| WoS | ||||||||||||
| URL | http://gateway.isiknowledge.com/gateway/Gateway.cgi?&GWVersion=2&SrcAuth=ShinshuUniv&SrcApp=ShinshuUniv&DestLinkType=FullRecord&DestApp=WOS&KeyUT=000400928700005 | |||||||||||
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Cite as
Nakagawa, Haruka, Suzuki, Masahiro, Hanabusa, Kenji, 2017, Physical gelation by amides derived from trans-1, 2-diaminocyclohexane and their tetrasiloxane-based gelators: NATURE PUBLISHING GROUP, 439–447 p.
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