WEKO3
アイテム
{"_buckets": {"deposit": "326988da-9697-4744-9c09-2896799104a4"}, "_deposit": {"id": "14509", "owners": [], "pid": {"revision_id": 0, "type": "depid", "value": "14509"}, "status": "published"}, "_oai": {"id": "oai:soar-ir.repo.nii.ac.jp:00014509", "sets": ["1461"]}, "author_link": ["43675", "43676", "43677", "43678"], "item_11_alternative_title_1": {"attribute_name": "その他(別言語等)のタイトル", "attribute_value_mlt": [{"subitem_alternative_title": "テキスタイルの光電気化学的機能向上の研究"}]}, "item_11_biblio_info_6": {"attribute_name": "書誌情報", "attribute_value_mlt": [{"bibliographicIssueDates": {"bibliographicIssueDate": "2005-03-31", "bibliographicIssueDateType": "Issued"}, "bibliographicPageEnd": "109", "bibliographicPageStart": "108", "bibliographicVolumeNumber": "11", "bibliographic_titles": [{"bibliographic_title": "先進ファイバー工学研究教育拠点研究成果報告書"}]}]}, "item_11_description_20": {"attribute_name": "抄録", "attribute_value_mlt": [{"subitem_description": "It took extremely short reaction time only for 10min. to synthesize the long alkylthio-group-substituted metal-free compound, (C_8S)_8PcH_2(1), by the present microwave method giving significantly high yield(71 %), although it took very long reaction time for 20-24hrs to synthesize (C_8S)_8PcH_2(1), by the conventional oil bath method, It is noteworthy that this is the first example of syntheses of metal-free Pc derivatives in an organic solvent by microwave method. When the metal complexes. (C_8S)_8PcCu(2) and (C\u003c_12\u003eO)_8PcCu(6), were synthesized by microwave method, the optimal condition and the best yield depended very much on the kind of copper salts. Template effect of metal could not be seen in syntheses of the alkylthi0-group-substituted copper complex, (C_8S)_8PcCu(2), by microwave method. Oh the other hand, the template effect of metal could be seen in the cases of both (C_\u003c12\u003eO)_8PcCu(6) having alkoxy groups and the core complex PcCu. This difference may be attributed to difference of the intermediates. Further studies are necessary to clarify the hypothesis.", "subitem_description_type": "Abstract"}]}, "item_11_description_30": {"attribute_name": "資源タイプ(コンテンツの種類)", "attribute_value_mlt": [{"subitem_description": "Article", "subitem_description_type": "Other"}]}, "item_11_description_5": {"attribute_name": "引用", "attribute_value_mlt": [{"subitem_description": "先進ファイバー工学研究教育拠点研究成果報告書 11: 108-109(2005)", "subitem_description_type": "Other"}]}, "item_11_link_3": {"attribute_name": "信州大学研究者総覧へのリンク", "attribute_value_mlt": [{"subitem_link_text": "太田, 和親", "subitem_link_url": "http://soar-rd.shinshu-u.ac.jp/profile/ja.yVLFjekV.html"}, {"subitem_link_text": "木村, 睦", "subitem_link_url": "http://soar-rd.shinshu-u.ac.jp/profile/ja.HaDFjekV.html"}, {"subitem_link_text": "宇佐美, 久尚", "subitem_link_url": "http://soar-rd.shinshu-u.ac.jp/profile/ja.uacFjekV.html"}]}, "item_11_publisher_4": {"attribute_name": "出版者", "attribute_value_mlt": [{"subitem_publisher": "信州大学繊維学部"}]}, "item_11_select_64": {"attribute_name": "著者版フラグ", "attribute_value_mlt": [{"subitem_select_item": "publisher"}]}, "item_11_source_id_40": {"attribute_name": "書誌レコードID", "attribute_value_mlt": [{"subitem_source_identifier": "AA1200368X", "subitem_source_identifier_type": "NCID"}]}, "item_11_text_66": {"attribute_name": "sortkey", "attribute_value_mlt": [{"subitem_text_value": "059"}]}, "item_1627890728808": {"attribute_name": "出版タイプ", "attribute_value_mlt": [{"subitem_version_resource": "http://purl.org/coar/version/c_970fb48d4fbd8a85", "subitem_version_type": "VoR"}]}, "item_creator": {"attribute_name": "著者", "attribute_type": "creator", "attribute_value_mlt": [{"creatorNames": [{"creatorName": "太田, 和親"}], "nameIdentifiers": [{"nameIdentifier": "43675", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "松瀬, 丈浩"}], "nameIdentifiers": [{"nameIdentifier": "43676", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "木村, 睦"}], "nameIdentifiers": [{"nameIdentifier": "43677", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "宇佐美, 久尚"}], "nameIdentifiers": [{"nameIdentifier": "43678", "nameIdentifierScheme": "WEKO"}]}]}, "item_files": {"attribute_name": "ファイル情報", "attribute_type": "file", "attribute_value_mlt": [{"accessrole": "open_date", "date": [{"dateType": "Available", "dateValue": "2015-09-28"}], "displaytype": "detail", "download_preview_message": "", "file_order": 0, "filename": "AFSTT11-410.pdf", "filesize": [{"value": "954.3 kB"}], "format": "application/pdf", "future_date_message": "", "is_thumbnail": false, "licensetype": "license_note", "mimetype": "application/pdf", "size": 954300.0, "url": {"label": "AFSTT11-410.pdf", "url": "https://soar-ir.repo.nii.ac.jp/record/14509/files/AFSTT11-410.pdf"}, "version_id": "1e335b07-2d72-4256-89db-7a8bcf774edb"}]}, "item_language": {"attribute_name": "言語", "attribute_value_mlt": [{"subitem_language": "jpn"}]}, "item_resource_type": {"attribute_name": "資源タイプ", "attribute_value_mlt": [{"resourcetype": "research report", "resourceuri": "http://purl.org/coar/resource_type/c_18ws"}]}, "item_title": "16-4-10 : 光伝導性液晶半導体の高速合成と自発配向試料の開発", "item_titles": {"attribute_name": "タイトル", "attribute_value_mlt": [{"subitem_title": "16-4-10 : 光伝導性液晶半導体の高速合成と自発配向試料の開発", "subitem_title_language": "ja"}]}, "item_type_id": "11", "owner": "1", "path": ["1461"], "permalink_uri": "http://hdl.handle.net/10091/13484", "pubdate": {"attribute_name": "PubDate", "attribute_value": "2011-12-05"}, "publish_date": "2011-12-05", "publish_status": "0", "recid": "14509", "relation": {}, "relation_version_is_last": true, "title": ["16-4-10 : 光伝導性液晶半導体の高速合成と自発配向試料の開発"], "weko_shared_id": -1}
16-4-10 : 光伝導性液晶半導体の高速合成と自発配向試料の開発
http://hdl.handle.net/10091/13484
http://hdl.handle.net/10091/134840364a254-4495-46ec-9c90-cdc57ab124ab
名前 / ファイル | ライセンス | アクション |
---|---|---|
AFSTT11-410.pdf (954.3 kB)
|
|
Item type | 研究報告書 / Research Paper(1) | |||||
---|---|---|---|---|---|---|
公開日 | 2011-12-05 | |||||
タイトル | ||||||
言語 | ja | |||||
タイトル | 16-4-10 : 光伝導性液晶半導体の高速合成と自発配向試料の開発 | |||||
言語 | ||||||
言語 | jpn | |||||
資源タイプ | ||||||
資源 | http://purl.org/coar/resource_type/c_18ws | |||||
タイプ | research report | |||||
その他(別言語等)のタイトル | ||||||
その他のタイトル | テキスタイルの光電気化学的機能向上の研究 | |||||
著者 |
太田, 和親
× 太田, 和親× 松瀬, 丈浩× 木村, 睦× 宇佐美, 久尚 |
|||||
信州大学研究者総覧へのリンク | ||||||
氏名 | 太田, 和親 | |||||
URL | http://soar-rd.shinshu-u.ac.jp/profile/ja.yVLFjekV.html | |||||
信州大学研究者総覧へのリンク | ||||||
氏名 | 木村, 睦 | |||||
URL | http://soar-rd.shinshu-u.ac.jp/profile/ja.HaDFjekV.html | |||||
信州大学研究者総覧へのリンク | ||||||
氏名 | 宇佐美, 久尚 | |||||
URL | http://soar-rd.shinshu-u.ac.jp/profile/ja.uacFjekV.html | |||||
出版者 | ||||||
出版者 | 信州大学繊維学部 | |||||
引用 | ||||||
内容記述タイプ | Other | |||||
内容記述 | 先進ファイバー工学研究教育拠点研究成果報告書 11: 108-109(2005) | |||||
書誌情報 |
先進ファイバー工学研究教育拠点研究成果報告書 巻 11, p. 108-109, 発行日 2005-03-31 |
|||||
抄録 | ||||||
内容記述タイプ | Abstract | |||||
内容記述 | It took extremely short reaction time only for 10min. to synthesize the long alkylthio-group-substituted metal-free compound, (C_8S)_8PcH_2(1), by the present microwave method giving significantly high yield(71 %), although it took very long reaction time for 20-24hrs to synthesize (C_8S)_8PcH_2(1), by the conventional oil bath method, It is noteworthy that this is the first example of syntheses of metal-free Pc derivatives in an organic solvent by microwave method. When the metal complexes. (C_8S)_8PcCu(2) and (C<_12>O)_8PcCu(6), were synthesized by microwave method, the optimal condition and the best yield depended very much on the kind of copper salts. Template effect of metal could not be seen in syntheses of the alkylthi0-group-substituted copper complex, (C_8S)_8PcCu(2), by microwave method. Oh the other hand, the template effect of metal could be seen in the cases of both (C_<12>O)_8PcCu(6) having alkoxy groups and the core complex PcCu. This difference may be attributed to difference of the intermediates. Further studies are necessary to clarify the hypothesis. | |||||
資源タイプ(コンテンツの種類) | ||||||
内容記述タイプ | Other | |||||
内容記述 | Article | |||||
書誌レコードID | ||||||
収録物識別子タイプ | NCID | |||||
収録物識別子 | AA1200368X | |||||
出版タイプ | ||||||
出版タイプ | VoR | |||||
出版タイプResource | http://purl.org/coar/version/c_970fb48d4fbd8a85 |