{"_buckets": {"deposit": "b9ee86ef-8e2e-4645-b484-a086d64a5f27"}, "_deposit": {"id": "10469", "owners": [], "pid": {"revision_id": 0, "type": "depid", "value": "10469"}, "status": "published"}, "_oai": {"id": "oai:soar-ir.repo.nii.ac.jp:00010469", "sets": []}, "author_link": ["33142"], "item_10_biblio_info_6": {"attribute_name": "書誌情報", "attribute_value_mlt": [{"bibliographicIssueDates": {"bibliographicIssueDate": "2011-03-25", "bibliographicIssueDateType": "Issued"}, "bibliographicIssueNumber": "1-2", "bibliographicPageEnd": "15", "bibliographicPageStart": "5", "bibliographicVolumeNumber": "47", "bibliographic_titles": [{"bibliographic_title": "信州大学農学部紀要"}]}]}, "item_10_description_20": {"attribute_name": "抄録", "attribute_value_mlt": [{"subitem_description": "ヒドロゲナーゼは，プラチナなどの希少金属を用いることなく，常温常圧で効率よく水素分子の分解と生産を触媒することから，水素エネルギー社会の実現を望む人たちから熱い視線を注がれている。しかし，ヒドロゲナーゼは大気中の酸素分子によって活性を失うという問題を抱えている。ヒドロゲナーゼの応用には酸素耐性化が必要であり，そのような取り組みは，ヒドロゲナーゼによる生物学的水素生産や，バイオ燃料電池の開発のみならず，水素分子に関する触媒化学の発展にも貢献できるだろう。ここでは，ヒドロゲナーゼ酸素耐性化研究に関する動向や，我々の取り組みについても紹介したい。 Hydrogenase has received growing attentions by researchers who are planning to realize the Hydrogen-Society, because it enables the cleavage and the production of hydrogen gas in the mild condition without using rare and costly metals such as Pt. Hydrogenase, however, is inactivated quickly by oxygen molecules, which significantly limits its industrial applications. Therefore, researches for stabilization of hydrogenase against oxygen molecules should contribute not only to development of bio -hydrogen production system and bio-fuel cells, but also to evolution of catalytic chemistry involved in hydrogen molecule. We herein introduce latest reports about naturally-occurring robust hydrogenases and the mechanism of oxygen-inactivation, attempts for oxygen-stabilization.", "subitem_description_language": "ja", "subitem_description_type": "Abstract"}]}, "item_10_description_30": {"attribute_name": "資源タイプ（コンテンツの種類）", "attribute_value_mlt": [{"subitem_description": "Article", "subitem_description_type": "Other"}]}, "item_10_description_31": {"attribute_name": "フォーマット：mimeタイプ", "attribute_value_mlt": [{"subitem_description": "application/pdf", "subitem_description_type": "Other"}]}, "item_10_description_5": {"attribute_name": "引用", "attribute_value_mlt": [{"subitem_description": "信州大学農学部紀要 47（1-2）: 5-15(2011)", "subitem_description_type": "Other"}]}, "item_10_link_3": {"attribute_name": "信州大学研究者総覧へのリンク", "attribute_value_mlt": [{"subitem_link_text": "伊原, 正喜", "subitem_link_url": "http://soar-rd.shinshu-u.ac.jp/profile/ja.jpkaWUyV.html"}]}, "item_10_publisher_4": {"attribute_name": "出版者", "attribute_value_mlt": [{"subitem_publisher": "信州大学農学部"}]}, "item_10_select_64": {"attribute_name": "著者版フラグ", "attribute_value_mlt": [{"subitem_select_item": "publisher"}]}, "item_10_source_id_35": {"attribute_name": "ISSN", "attribute_value_mlt": [{"subitem_source_identifier": "0583-0621", "subitem_source_identifier_type": "ISSN"}]}, "item_10_source_id_39": {"attribute_name": "NII ISSN", "attribute_value_mlt": [{"subitem_source_identifier": "0583-0621", "subitem_source_identifier_type": "ISSN"}]}, "item_10_source_id_40": {"attribute_name": "書誌レコードID", "attribute_value_mlt": [{"subitem_source_identifier": "AN00121352", "subitem_source_identifier_type": "NCID"}]}, "item_10_text_66": {"attribute_name": "sortkey", "attribute_value_mlt": [{"subitem_text_value": "02"}]}, "item_1627890569677": {"attribute_name": "出版タイプ", "attribute_value_mlt": [{"subitem_version_resource": "http://purl.org/coar/version/c_970fb48d4fbd8a85", "subitem_version_type": "VoR"}]}, "item_creator": {"attribute_name": "著者", "attribute_type": "creator", "attribute_value_mlt": [{"creatorNames": [{"creatorName": "伊原,  正喜"}], "nameIdentifiers": [{"nameIdentifier": "33142", "nameIdentifierScheme": "WEKO"}]}]}, "item_files": {"attribute_name": "ファイル情報", "attribute_type": "file", "attribute_value_mlt": [{"accessrole": "open_date", "date": [{"dateType": "Available", "dateValue": "2015-09-25"}], "displaytype": "detail", "download_preview_message": "", "file_order": 0, "filename": "Agriculture47-02.pdf", "filesize": [{"value": "1.1 MB"}], "format": "application/pdf", "future_date_message": "", "is_thumbnail": false, "licensetype": "license_note", "mimetype": "application/pdf", "size": 1100000.0, "url": {"label": "Agriculture47-02.pdf", "url": "https://soar-ir.repo.nii.ac.jp/record/10469/files/Agriculture47-02.pdf"}, "version_id": "e4c31cbd-dc22-4d12-a351-4d9311b9b374"}]}, "item_keyword": {"attribute_name": "キーワード", "attribute_value_mlt": [{"subitem_subject": "ヒドロゲナーゼ", "subitem_subject_scheme": "Other"}, {"subitem_subject": "Hydrogenase", "subitem_subject_scheme": "Other"}, {"subitem_subject": "水素", "subitem_subject_scheme": "Other"}, {"subitem_subject": "Hydrogen", "subitem_subject_scheme": "Other"}, {"subitem_subject": "酸素耐性", "subitem_subject_scheme": "Other"}, {"subitem_subject": "O2-tolerance", "subitem_subject_scheme": "Other"}, {"subitem_subject": "蛋白質工学", "subitem_subject_scheme": "Other"}, {"subitem_subject": "Protein engineering", "subitem_subject_scheme": "Other"}]}, "item_language": {"attribute_name": "言語", "attribute_value_mlt": [{"subitem_language": "jpn"}]}, "item_resource_type": {"attribute_name": "資源タイプ", "attribute_value_mlt": [{"resourcetype": "departmental bulletin paper", "resourceuri": "http://purl.org/coar/resource_type/c_6501"}]}, "item_title": "ヒドロゲナーゼの安定化・酸素耐性化", "item_titles": {"attribute_name": "タイトル", "attribute_value_mlt": [{"subitem_title": "ヒドロゲナーゼの安定化・酸素耐性化", "subitem_title_language": "ja"}, {"subitem_title": "Attempts for stabilization of hydrogenase against O2 attack", "subitem_title_language": "en"}]}, "item_type_id": "10", "owner": "1", "path": ["1024"], "permalink_uri": "http://hdl.handle.net/10091/13146", "pubdate": {"attribute_name": "PubDate", "attribute_value": "2011-05-12"}, "publish_date": "2011-05-12", "publish_status": "0", "recid": "10469", "relation": {}, "relation_version_is_last": true, "title": ["ヒドロゲナーゼの安定化・酸素耐性化"], "weko_shared_id": -1}