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  1. 040 理学部
  2. 0401 学術論文

Synthesis of a Novel Non-Benzenoid Quinone, 3,10-Dihydro-2,4-dimethyl-7,13-methanocyclohepta[11]annulene-3,10-dione, from 8H-7,9-Bis(methoxycarbonyl)-5,11-methano[11]annuleno[c]furan-8-one

http://hdl.handle.net/10091/17269
http://hdl.handle.net/10091/17269
fef764b4-e8ba-4b78-be6b-5d773c284042
名前 / ファイル ライセンス アクション
COM-12-S(N)75.pdf COM-12-S(N)75.pdf (518.1 kB)
Item type 学術雑誌論文 / Journal Article(1)
公開日 2013-12-04
タイトル
言語 en
タイトル Synthesis of a Novel Non-Benzenoid Quinone, 3,10-Dihydro-2,4-dimethyl-7,13-methanocyclohepta[11]annulene-3,10-dione, from 8H-7,9-Bis(methoxycarbonyl)-5,11-methano[11]annuleno[c]furan-8-one
言語
言語 eng
キーワード
主題Scheme Other
主題 Methano[11]annulene
キーワード
主題Scheme Other
主題 Furan
キーワード
主題Scheme Other
主題 Dicationic Species
キーワード
主題Scheme Other
主題 [4+3] Cycloaddition
キーワード
主題Scheme Other
主題 Protonation
資源タイプ
資源 http://purl.org/coar/resource_type/c_6501
タイプ journal article
著者 Kuroda, Shigeyasu

× Kuroda, Shigeyasu

WEKO 35937

Kuroda, Shigeyasu

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Matsumoto, Naoko

× Matsumoto, Naoko

WEKO 35938

Matsumoto, Naoko

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Zhang, Yanmei

× Zhang, Yanmei

WEKO 35939

Zhang, Yanmei

Search repository
Miyatake, Ryuta

× Miyatake, Ryuta

WEKO 35940

Miyatake, Ryuta

Search repository
Fujiwara, Yurie

× Fujiwara, Yurie

WEKO 35941

Fujiwara, Yurie

Search repository
Oda, Mitsunori

× Oda, Mitsunori

WEKO 35942

Oda, Mitsunori

Search repository
信州大学研究者総覧へのリンク
氏名 Oda, Mitsunori
URL http://soar-rd.shinshu-u.ac.jp/profile/ja.gNAmbVkm.html
出版者
出版者 PERGAMON-ELSEVIER SCIENCE LTD
引用
内容記述タイプ Other
内容記述 HETEROCYCLES. 86(2):1541-1547 (2012)
書誌情報 HETEROCYCLES

巻 86, 号 2, p. 1541-1547, 発行日 2013
抄録
内容記述タイプ Abstract
内容記述 8H-7,9-Bis(methoxycarbonyl)-5,11-methano[11]anuleno[c]furan-8-one (3) undergoes [4+3] cycloaddition with an oxyallyl species generated from 2,4-dibromo-3-pentanone in the presence of KI and copper, followed by dehydration in fluorosulfuric acid to give cyclohepta[11]annulenedione diester 9. After hydrolysis of the ester groups, decarboxylation yielded the title quinone 6. The H-1 NMR spectrum of 6 in D2SO4 indicates generation of its protonated dicationic species.
資源タイプ(コンテンツの種類)
内容記述タイプ Other
内容記述 Article
ISSN
収録物識別子タイプ ISSN
収録物識別子 0385-5414
書誌レコードID
収録物識別子タイプ NCID
収録物識別子 AA00663739
DOI
識別子タイプ DOI
関連識別子 https://doi.org/10.3987/COM-12-S(N)75
関連名称 10.3987/COM-12-S(N)75
権利
権利情報 Copyright© 2013 The Japan Institute of Heterocyclic Chemistry
出版タイプ
出版タイプ AM
出版タイプResource http://purl.org/coar/version/c_ab4af688f83e57aa
WoS
表示名 Web of Science
URL http://gateway.isiknowledge.com/gateway/Gateway.cgi?&GWVersion=2&SrcAuth=ShinshuUniv&SrcApp=ShinshuUniv&DestLinkType=FullRecord&DestApp=WOS&KeyUT=000314390600056
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