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  1. 040 理学部
  2. 0401 学術論文

Synthesis and properties of bis(1,3-benzodithiole)-type redox systems containing a xylyl rotator unit: A new type of redox-responsive molecular rotor

http://hdl.handle.net/10091/1078
97e0fdfe-a4c0-4536-97d0-8de08f135a8c
名前 / ファイル ライセンス アクション
Heterocycles_74_251_2007.pdf Heterocycles_74_251_2007.pdf (496.2 kB)
Item type 学術雑誌論文 / Journal Article(1)
公開日 2008-06-05
タイトル
言語 en
タイトル Synthesis and properties of bis(1,3-benzodithiole)-type redox systems containing a xylyl rotator unit: A new type of redox-responsive molecular rotor
言語
言語 eng
資源タイプ
資源 http://purl.org/coar/resource_type/c_6501
タイプ journal article
著者 Uchiyama, Y

× Uchiyama, Y

WEKO 36686

Uchiyama, Y

Search repository
Ohta, A

× Ohta, A

WEKO 36687

Ohta, A

Search repository
Fujimori, K

× Fujimori, K

WEKO 36688

Fujimori, K

Search repository
信州大学研究者総覧へのリンク
氏名 Ohta, A
URL http://soar-rd.shinshu-u.ac.jp/profile/ja.uaTeOUkh.html
出版者
出版者 The Japan Institute of Heterocyclic Chemistry
引用
内容記述タイプ Other
内容記述 HETEROCYCLES. 74: 251-257 (2007)
書誌情報 HETEROCYCLES

巻 74, p. 251-257, 発行日 2007
抄録
内容記述タイプ Abstract
内容記述 A new type of redox-responsive molecular rotors (3(2+)/4) possessing a xylyl rotator unit have been designed and synthesized. Reduction of 3(2+) with zinc gave the corresponding cyclization products (4), from which dications (3 2,) were regenerated upon oxidation. Cyclic voltammetry also showed the interconversion between 3(2+) and 4. Variable-temperature (1)H NMR measurements revealed that the rotational barriers of the xylyl units in the neutral states (4) are higher than those in the dication states (3(2+)).
資源タイプ(コンテンツの種類)
内容記述タイプ Other
内容記述 Article
ISSN
収録物識別子タイプ ISSN
収録物識別子 0385-5414
書誌レコードID
収録物識別子タイプ NCID
収録物識別子 AA00663739
他の資源との関係:URI
関連識別子
識別子タイプ URI
関連識別子 http://www.heterocycles.jp/
関連名称
関連名称 http://www.heterocycles.jp/
DOI
関連識別子
識別子タイプ DOI
関連識別子 https://doi.org/10.3987/COM-07-S(W)80
関連名称
関連名称 10.3987/COM-07-S(W)80
権利
権利情報 Copyright© 2007 The Japan Institute of Heterocyclic Chemistry
出版タイプ
出版タイプ VoR
出版タイプResource http://purl.org/coar/version/c_970fb48d4fbd8a85
WoS
表示名 Web of Science
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