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  1. 060 工学部
  2. 0601 学術論文

Characteristics and mechanism of low temperature dehydrochlorination of poly(vinyl chloride) in the presence of zinc(II) oxide

http://hdl.handle.net/10091/16074
http://hdl.handle.net/10091/16074
795cc163-10a3-4a29-a6f9-d49db268f7b4
名前 / ファイル ライセンス アクション
Characteristics_mechanism_low_temperature_dehydrochlorination.pdf Characteristics_mechanism_low_temperature_dehydrochlorination.pdf (714.3 kB)
Item type 学術雑誌論文 / Journal Article(1)
公開日 2012-11-20
タイトル
言語 en
タイトル Characteristics and mechanism of low temperature dehydrochlorination of poly(vinyl chloride) in the presence of zinc(II) oxide
言語
言語 eng
キーワード
主題Scheme Other
主題 Poly(vinyl chloride)
キーワード
主題Scheme Other
主題 Dehydrochlorination
キーワード
主題Scheme Other
主題 Zinc(II) oxide
キーワード
主題Scheme Other
主題 Cross-linking
資源タイプ
資源 http://purl.org/coar/resource_type/c_6501
タイプ journal article
著者 Kosuda, Takashi

× Kosuda, Takashi

WEKO 37732

Kosuda, Takashi

Search repository
Okada, Tomohiko

× Okada, Tomohiko

WEKO 37733

Okada, Tomohiko

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Nozaka, Shogo

× Nozaka, Shogo

WEKO 37734

Nozaka, Shogo

Search repository
Matsuzawa, Yukitaka

× Matsuzawa, Yukitaka

WEKO 37735

Matsuzawa, Yukitaka

Search repository
Shimizu, Takuya

× Shimizu, Takuya

WEKO 37736

Shimizu, Takuya

Search repository
Hamanaka, Senji

× Hamanaka, Senji

WEKO 37737

Hamanaka, Senji

Search repository
Mishima, Shozi

× Mishima, Shozi

WEKO 37738

Mishima, Shozi

Search repository
信州大学研究者総覧へのリンク
氏名 Okada, Tomohiko
URL http://soar-rd.shinshu-u.ac.jp/profile/ja.WpDFbpkh.html
出版者
出版者 ELSEVIER SCI LTD
引用
内容記述タイプ Other
内容記述 POLYMER DEGRADATION AND STABILITY. 97(4):584-591 (2012)
書誌情報 POLYMER DEGRADATION AND STABILITY

巻 97, 号 4, p. 584-591, 発行日 2012-04
抄録
内容記述タイプ Abstract
内容記述 Characteristics of low temperature (473 K) dehydrochlorination of PVC powder in the presence of ZnO were studied in nitrogen flow and a reaction mechanism was proposed. It was revealed that a large portion of chlorine (ca. 70%) in PVC powder reacts with ZnO accompanying evolution of water and a slight amount of HCl (ca. 0.5%) without any organic gas. Analysis of the solid product by SEM, XRD and IR suggested that an apparent solid-solid reaction proceeds at 473 K via formation of a liquid phase which acts as reaction promoter and that the solid product is abundant in aliphatic (CH)(n) polymer. It was concluded that the first step of the dehydrochlorination is cross-linking C-C single bond formation in a polymer chain or among polymer chains followed by isomerization to polyene and aromatics.
資源タイプ(コンテンツの種類)
内容記述タイプ Other
内容記述 Article
ISSN
収録物識別子タイプ ISSN
収録物識別子 0141-3910
書誌レコードID
収録物識別子タイプ NCID
収録物識別子 AA00362801
DOI
識別子タイプ DOI
関連識別子 https://doi.org/10.1016/j.polymdegradstab.2012.01.009
関連名称 10.1016/j.polymdegradstab.2012.01.009
出版タイプ
出版タイプ AM
出版タイプResource http://purl.org/coar/version/c_ab4af688f83e57aa
WoS
表示名 Web of Science
URL http://gateway.isiknowledge.com/gateway/Gateway.cgi?&GWVersion=2&SrcAuth=ShinshuUniv&SrcApp=ShinshuUniv&DestLinkType=FullRecord&DestApp=WOS&KeyUT=000301911300015
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