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The DDPC is a synthetic sphingomyelin analogue and has two amide bonds in its hydrophobic parts. This paper reports on metastable phase behavior of the hydrated DDPC sample. By cooling from a chain-melted state at the rates of greater than 4 degrees C min(-1), hydrated DDPC bilayers form a metastable gel phase. In the gel phase, the hydrophobic chains are tilted with respect to the bilayer normal, as like the gel phase of glycero-phosphatidylcholines. By heating, the metastable gel phase is transformed in to a stable phase associated with an exothermic heat event at 18.3 degrees C (Delta H= 14.6kJ mol(-1)) and then the stable phase is transformed into a liquid-crystalline phase at 25.6 degrees C (Delta H=42 kJ mol(-1)). The incubation at 17 degrees C for more than 1 h also induces the formation of the stable phase. In the stable phase, the hydrophobic chains are packed into highly ordered crystal-like structure. However, the X-ray diffraction pattern of the stable phase suggested that the entire DDPC molecules do not form a two-dimensional molecular ordered lattice, differing from normal subgel phase of glycero-phosphatidylcholines. The structure and phase behavior of DDPC revealed by the present study are discussed from the viewpoint of hydrogen bonds. (c) 2005 Elsevier B.V. All rights reserved."}]}, "item_creator": {"attribute_name": "著者", "attribute_type": "creator", "attribute_value_mlt": [{"creatorNames": [{"creatorName": "Takahashi, H"}], "nameIdentifiers": [{"nameIdentifier": "39090", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Okumura, Y"}], "nameIdentifiers": [{"nameIdentifier": "39091", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Sunamoto, J"}], "nameIdentifiers": [{"nameIdentifier": "39092", "nameIdentifierScheme": "WEKO"}]}]}, "item_files": {"attribute_name": "ファイル情報", "attribute_type": "file", "attribute_value_mlt": [{"accessrole": "open_date", "date": [{"dateType": "Available", "dateValue": "2015-09-28"}], "displaytype": "detail", "download_preview_message": "", "file_order": 0, "filename": "DDPC_final_ver.pdf", "filesize": [{"value": "480.5 kB"}], "format": "application/pdf", "future_date_message": "", "is_thumbnail": false, "licensetype": "license_note", "mimetype": "application/pdf", "size": 480500.0, "url": {"label": "DDPC_final_ver.pdf", "url": "https://soar-ir.repo.nii.ac.jp/record/12721/files/DDPC_final_ver.pdf"}, "version_id": "135ddbab-96c8-4ce5-af99-37b4f5800e97"}]}, "item_language": {"attribute_name": "言語", "attribute_value_mlt": [{"subitem_language": "eng"}]}, "item_resource_type": {"attribute_name": "資源タイプ", "attribute_value_mlt": [{"resourcetype": "journal article", "resourceuri": "http://purl.org/coar/resource_type/c_6501"}]}, "item_title": "Structure and thermal history dependant phase behavior of hydrated synthetic sphingomyelin analogue: 1,2-Dimyristamido-1,2-deoxyphosphatidylcholine", "item_titles": {"attribute_name": "タイトル", "attribute_value_mlt": [{"subitem_title": "Structure and thermal history dependant phase behavior of hydrated synthetic sphingomyelin analogue: 1,2-Dimyristamido-1,2-deoxyphosphatidylcholine", "subitem_title_language": "en"}]}, "item_type_id": "6", "owner": "1", "path": ["1222"], "permalink_uri": "http://hdl.handle.net/10091/144", "pubdate": {"attribute_name": "PubDate", "attribute_value": "2007-04-10"}, "publish_date": "2007-04-10", "publish_status": "0", "recid": "12721", "relation": {}, "relation_version_is_last": true, "title": ["Structure and thermal history dependant phase behavior of hydrated synthetic sphingomyelin analogue: 1,2-Dimyristamido-1,2-deoxyphosphatidylcholine"], "weko_shared_id": -1}
Structure and thermal history dependant phase behavior of hydrated synthetic sphingomyelin analogue: 1,2-Dimyristamido-1,2-deoxyphosphatidylcholine
http://hdl.handle.net/10091/144
http://hdl.handle.net/10091/144a786a85a-de53-4f76-8600-04ca08cf45c3
名前 / ファイル | ライセンス | アクション |
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Item type | 学術雑誌論文 / Journal Article(1) | |||||
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公開日 | 2007-04-10 | |||||
タイトル | ||||||
言語 | en | |||||
タイトル | Structure and thermal history dependant phase behavior of hydrated synthetic sphingomyelin analogue: 1,2-Dimyristamido-1,2-deoxyphosphatidylcholine | |||||
言語 | ||||||
言語 | eng | |||||
資源タイプ | ||||||
資源 | http://purl.org/coar/resource_type/c_6501 | |||||
タイプ | journal article | |||||
著者 |
Takahashi, H
× Takahashi, H× Okumura, Y× Sunamoto, J |
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信州大学研究者総覧へのリンク | ||||||
氏名 | Okumura, Y | |||||
URL | http://soar-rd.shinshu-u.ac.jp/profile/ja.gNDVgpAF.html | |||||
出版者 | ||||||
出版者 | Elsevier Science BV | |||||
引用 | ||||||
内容記述タイプ | Other | |||||
内容記述 | Biochimica et Biophysica Acta - Biomembranes. 1713(1): 40-50 (2005) | |||||
書誌情報 |
Biochimica et biophysica acta. Biomembranes 巻 1713, 号 1, p. 40-50, 発行日 2005-07-15 |
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資源タイプ(コンテンツの種類) | ||||||
内容記述タイプ | Other | |||||
内容記述 | Article | |||||
ISSN | ||||||
収録物識別子タイプ | ISSN | |||||
収録物識別子 | 0005-2736 | |||||
書誌レコードID | ||||||
収録物識別子タイプ | NCID | |||||
収録物識別子 | AA00564657 | |||||
他の資源との関係:URI | ||||||
識別子タイプ | URI | |||||
関連識別子 | http://www.elsevier.com/locate/issn/00052736 | |||||
関連名称 | http://www.elsevier.com/locate/issn/00052736 | |||||
PubMed | ||||||
識別子タイプ | PMID | |||||
関連識別子 | http://www.ncbi.nlm.nih.gov/entrez/query.fcgi?CMD=search&DB=pubmed&term=15950928 | |||||
関連名称 | 15950928 | |||||
DOI | ||||||
識別子タイプ | DOI | |||||
関連識別子 | https://doi.org/10.1016/j.bbamem.2005.04.012 | |||||
関連名称 | 10.1016/j.bbamem.2005.04.012 | |||||
出版タイプ | ||||||
出版タイプ | AM | |||||
出版タイプResource | http://purl.org/coar/version/c_ab4af688f83e57aa | |||||
WoS | ||||||
表示名 | Web of Science | |||||
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