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The DDPC is a synthetic sphingomyelin analogue and has two amide bonds in its hydrophobic parts. This paper reports on metastable phase behavior of the hydrated DDPC sample. By cooling from a chain-melted state at the rates of greater than 4 degrees C min(-1), hydrated DDPC bilayers form a metastable gel phase. In the gel phase, the hydrophobic chains are tilted with respect to the bilayer normal, as like the gel phase of glycero-phosphatidylcholines. By heating, the metastable gel phase is transformed in to a stable phase associated with an exothermic heat event at 18.3 degrees C (Delta H= 14.6kJ mol(-1)) and then the stable phase is transformed into a liquid-crystalline phase at 25.6 degrees C (Delta H=42 kJ mol(-1)). The incubation at 17 degrees C for more than 1 h also induces the formation of the stable phase. In the stable phase, the hydrophobic chains are packed into highly ordered crystal-like structure. However, the X-ray diffraction pattern of the stable phase suggested that the entire DDPC molecules do not form a two-dimensional molecular ordered lattice, differing from normal subgel phase of glycero-phosphatidylcholines. The structure and phase behavior of DDPC revealed by the present study are discussed from the viewpoint of hydrogen bonds. (c) 2005 Elsevier B.V. All rights reserved."}]}, "item_creator": {"attribute_name": "\u8457\u8005", "attribute_type": "creator", "attribute_value_mlt": [{"creatorNames": [{"creatorName": "Takahashi,  H"}], "nameIdentifiers": [{"nameIdentifier": "39090", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Okumura,  Y"}], "nameIdentifiers": [{"nameIdentifier": "39091", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Sunamoto,  J"}], "nameIdentifiers": [{"nameIdentifier": "39092", "nameIdentifierScheme": "WEKO"}]}]}, "item_files": {"attribute_name": "\u30d5\u30a1\u30a4\u30eb\u60c5\u5831", "attribute_type": "file", "attribute_value_mlt": [{"accessrole": "open_date", "date": [{"dateType": "Available", "dateValue": "2015-09-28"}], "displaytype": "detail", "download_preview_message": "", "file_order": 0, "filename": "DDPC_final_ver.pdf", "filesize": [{"value": "480.5 kB"}], "format": "application/pdf", "future_date_message": "", "is_thumbnail": false, "licensetype": "license_note", "mimetype": "application/pdf", "size": 480500.0, "url": {"label": "DDPC_final_ver.pdf", "url": "https://soar-ir.repo.nii.ac.jp/record/12721/files/DDPC_final_ver.pdf"}, "version_id": "135ddbab-96c8-4ce5-af99-37b4f5800e97"}]}, "item_language": {"attribute_name": "\u8a00\u8a9e", "attribute_value_mlt": [{"subitem_language": "eng"}]}, "item_resource_type": {"attribute_name": "\u8cc7\u6e90\u30bf\u30a4\u30d7", "attribute_value_mlt": [{"resourcetype": "journal article", "resourceuri": "http://purl.org/coar/resource_type/c_6501"}]}, "item_title": "Structure and thermal history dependant phase behavior of hydrated synthetic sphingomyelin analogue: 1,2-Dimyristamido-1,2-deoxyphosphatidylcholine", "item_titles": {"attribute_name": "\u30bf\u30a4\u30c8\u30eb", "attribute_value_mlt": [{"subitem_title": "Structure and thermal history dependant phase behavior of hydrated synthetic sphingomyelin analogue: 1,2-Dimyristamido-1,2-deoxyphosphatidylcholine", "subitem_title_language": "en"}]}, "item_type_id": "6", "owner": "1", "path": ["1221/1222"], "permalink_uri": "http://hdl.handle.net/10091/144", "pubdate": {"attribute_name": "PubDate", "attribute_value": "2007-04-10"}, "publish_date": "2007-04-10", "publish_status": "0", "recid": "12721", "relation": {}, "relation_version_is_last": true, "title": ["Structure and thermal history dependant phase behavior of hydrated synthetic sphingomyelin analogue: 1,2-Dimyristamido-1,2-deoxyphosphatidylcholine"], "weko_shared_id": -1}