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  1. 150 エキゾチック・ナノカーボンの創成と応用プロジェクト拠点
  2. 1501 学術論文

Sol-gel chemistry mediated Zn/Al-based complex dispersant for SWCNT in water without foam formation

http://hdl.handle.net/10091/00018616
http://hdl.handle.net/10091/00018616
b0e018d5-9b20-4dc0-bea1-fb7d4cd58663
名前 / ファイル ライセンス アクション
Sol-gel_chemistry_mediated_ZnAl-based_complex.pdf Sol-gel_chemistry_mediated_ZnAl-based_complex.pdf (840.5 kB)
Item type 学術雑誌論文 / Journal Article(1)
公開日 2016-02-03
タイトル
言語 en
タイトル Sol-gel chemistry mediated Zn/Al-based complex dispersant for SWCNT in water without foam formation
言語
言語 eng
資源タイプ
資源 http://purl.org/coar/resource_type/c_6501
タイプ journal article
著者 Kukobat, Radovan

× Kukobat, Radovan

WEKO 49882

en Kukobat, Radovan

Search repository
Minami, Daiki

× Minami, Daiki

WEKO 49883

en Minami, Daiki

Search repository
Hayashi, Takuya

× Hayashi, Takuya

WEKO 49884

en Hayashi, Takuya

Search repository
Hattori, Yoshiyuki

× Hattori, Yoshiyuki

WEKO 49885

en Hattori, Yoshiyuki

Search repository
Matsuda, Takafumi

× Matsuda, Takafumi

WEKO 49886

en Matsuda, Takafumi

Search repository
Sunaga, Motoo

× Sunaga, Motoo

WEKO 49887

en Sunaga, Motoo

Search repository
Bharti, Bhuvnesh

× Bharti, Bhuvnesh

WEKO 49888

en Bharti, Bhuvnesh

Search repository
Asakura, Kiyotaka

× Asakura, Kiyotaka

WEKO 49889

en Asakura, Kiyotaka

Search repository
Kaneko, Katsumi

× Kaneko, Katsumi

WEKO 49890

en Kaneko, Katsumi

Search repository
信州大学研究者総覧へのリンク
氏名 Hayashi, Takuya
URL http://soar-rd.shinshu-u.ac.jp/profile/ja.jmLUbpkh.html
信州大学研究者総覧へのリンク
氏名 Hattori, Yoshiyuki
URL http://soar-rd.shinshu-u.ac.jp/profile/ja.jmyejFkV.html
信州大学研究者総覧へのリンク
氏名 Kaneko, Katsumi
URL http://soar-rd.shinshu-u.ac.jp/profile/ja.HafNZVyC.html
出版者
出版者 PERGAMON-ELSEVIER SCIENCE LTD
引用
内容記述タイプ Other
内容記述 CARBON. 94:518-523 (2015)
書誌情報 CARBON

巻 94, p. 518-523, 発行日 2015-11
抄録
内容記述タイプ Abstract
内容記述 We report a bimetallic Zn/Al complex as an efficient inorganic dispersant for SWCNT, synthesized from Zn(CH3COO)(2) and Al(NO3)(3). The Zn/Al complex shows more than four times greater efficiency at dispersing SWCNT than widely used surfactants (CTAB and SDS). Besides remarkable dispersibility, the Zn/Al complex does not foam upon any shaking treatment and it can be used just after quick dissolution of the powdered form, which is a marked advantage over surfactants. The Zn/Al complex, containing amorphous Al(CH3COO)(3) and a complex of Zn2+ and NO3- ions, should have a unique dispersion mechanism, differing from the surfactants. Al(CH3COO)(3) has higher affinity for SWCNT than ions, adsorbing onto its surface in the first layer and attracting Zn2+ and NO3- ions. Charge transfer interactions between the Zn/Al complex and SWCNT, as evidenced by optical absorption spectroscopy, should induce a charge on SWCNT; the zeta potential of such coated SWCNT was +55 mV, indicating a high dispersion stability in aqueous media. Hence, the Zn/Al complex can widen the applications of SWCNT to various technologies such as the transparent and conductive films, as well as high performance composite polymers. (C) 2015 Elsevier Ltd. All rights reserved.
資源タイプ(コンテンツの種類)
内容記述タイプ Other
内容記述 Article
ISSN
収録物識別子タイプ PISSN
収録物識別子 0008-6223
書誌レコードID
収録物識別子タイプ NCID
収録物識別子 AA00598943
DOI
識別子タイプ DOI
関連識別子 https://doi.org/10.1016/j.carbon.2015.07.025
関連名称 10.1016/j.carbon.2015.07.025
権利
権利情報 © 2015. This manuscript version is made available under the CC-BY-NC-ND 4.0 license http://creativecommons.org/licenses/by-nc-nd/4.0/
出版タイプ
出版タイプ AM
出版タイプResource http://purl.org/coar/version/c_ab4af688f83e57aa
WoS
表示名 Web of Science
URL http://gateway.isiknowledge.com/gateway/Gateway.cgi?&GWVersion=2&SrcAuth=ShinshuUniv&SrcApp=ShinshuUniv&DestLinkType=FullRecord&DestApp=WOS&KeyUT=000360294900063
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