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  1. 080 繊維学部
  2. 0801 学術論文

Termination of Living Anionic Polymerization of Butyl Acrylate with alpha-(Chloromethyl) acrylate for End-Functionalization and Application to the Evaluation of Monomer Reactivity

http://hdl.handle.net/10091/00018686
e1049ddb-b6ee-4087-b6e0-1de84cfaa80c
名前 / ファイル ライセンス アクション
Termination_of_Living_Anionic_Polymerization.pdf Termination_of_Living_Anionic_Polymerization.pdf (217.9 kB)
Item type 学術雑誌論文 / Journal Article(1)
公開日 2016-03-23
タイトル
言語 en
タイトル Termination of Living Anionic Polymerization of Butyl Acrylate with alpha-(Chloromethyl) acrylate for End-Functionalization and Application to the Evaluation of Monomer Reactivity
言語
言語 eng
キーワード
主題Scheme Other
主題 alpha-substituted acrylate
キーワード
主題Scheme Other
主題 anionic polymerization
キーワード
主題Scheme Other
主題 end-functional polymer
キーワード
主題Scheme Other
主題 relative reactivity
キーワード
主題Scheme Other
主題 terminator
資源タイプ
資源 http://purl.org/coar/resource_type/c_6501
タイプ journal article
著者 Kohsaka, Yasuhiro

× Kohsaka, Yasuhiro

WEKO 50031

Kohsaka, Yasuhiro

Search repository
Ishihara, Shoya

× Ishihara, Shoya

WEKO 50032

Ishihara, Shoya

Search repository
Kitayama, Tatsuki

× Kitayama, Tatsuki

WEKO 50033

Kitayama, Tatsuki

Search repository
信州大学研究者総覧へのリンク
氏名 Kohsaka, Yasuhiro
URL http://soar-rd.shinshu-u.ac.jp/profile/ja.WNTUPVca.html
出版者
出版者 WILEY-V C H VERLAG GMBH
引用
内容記述タイプ Other
内容記述 MACROMOLECULAR CHEMISTRY AND PHYSICS. 216(14):1534-1539 (2015)
書誌情報 MACROMOLECULAR CHEMISTRY AND PHYSICS

巻 216, 号 14, p. 1534-1539, 発行日 2015-07
内容記述
内容記述タイプ Other
内容記述 Article first published online: 11 JUN 2015
抄録
内容記述タイプ Abstract
内容記述 Anionic polymerization of n-butyl acrylate (nBA) in toluene initiated with a binary initiator, isopropyl α-lithioisobutyrate/ethylaluminum bis(2,6-di-tert-butylphenoxide) at −60 °C, is terminated with ethyl α-(chloromethyl)acrylate (ECMA) to afford a poly(nBA) possessing an acryloyl group at the terminal with 80% of termination efficiency. The reactivity of nBA against a polymer anion of methyl methacrylate formed under identical conditions is estimated relative to the termination with ECMA by reacting a mixture of nBA and ECMA followed by 1H NMR spectroscopic chain-end analysis; the relative reactivity of nBA is found 80 times or more higher than ECMA.
資源タイプ(コンテンツの種類)
内容記述タイプ Other
内容記述 Article
ISSN
収録物識別子タイプ ISSN
収録物識別子 1022-1352
書誌レコードID
収録物識別子タイプ NCID
収録物識別子 AA10984295
DOI
関連識別子
識別子タイプ DOI
関連識別子 https://doi.org/10.1002/macp.201500100
関連名称
関連名称 10.1002/macp.201500100
権利
権利情報 This is the peer reviewed version of the following article: MACROMOLECULAR CHEMISTRY AND PHYSICS. 216(14):1534-1539 (2015), which has been published in final form at https://doi.org/10.1002/macp.201500100 This article may be used for non-commercial purposes in accordance with Wiley Terms and Conditions for Self-Archiving.
出版タイプ
出版タイプ AM
出版タイプResource http://purl.org/coar/version/c_ab4af688f83e57aa
WoS
表示名 Web of Science
URL http://gateway.isiknowledge.com/gateway/Gateway.cgi?&GWVersion=2&SrcAuth=ShinshuUniv&SrcApp=ShinshuUniv&DestLinkType=FullRecord&DestApp=WOS&KeyUT=000358120700005
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