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Termination of Living Anionic Polymerization of Butyl Acrylate with alpha-(Chloromethyl) acrylate for End-Functionalization and Application to the Evaluation of Monomer Reactivity
http://hdl.handle.net/10091/00018686
http://hdl.handle.net/10091/00018686e1049ddb-b6ee-4087-b6e0-1de84cfaa80c
名前 / ファイル | ライセンス | アクション |
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Item type | 学術雑誌論文 / Journal Article(1) | |||||
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公開日 | 2016-03-23 | |||||
タイトル | ||||||
言語 | en | |||||
タイトル | Termination of Living Anionic Polymerization of Butyl Acrylate with alpha-(Chloromethyl) acrylate for End-Functionalization and Application to the Evaluation of Monomer Reactivity | |||||
言語 | ||||||
言語 | eng | |||||
キーワード | ||||||
主題Scheme | Other | |||||
主題 | alpha-substituted acrylate | |||||
キーワード | ||||||
主題Scheme | Other | |||||
主題 | anionic polymerization | |||||
キーワード | ||||||
主題Scheme | Other | |||||
主題 | end-functional polymer | |||||
キーワード | ||||||
主題Scheme | Other | |||||
主題 | relative reactivity | |||||
キーワード | ||||||
主題Scheme | Other | |||||
主題 | terminator | |||||
資源タイプ | ||||||
資源 | http://purl.org/coar/resource_type/c_6501 | |||||
タイプ | journal article | |||||
著者 |
Kohsaka, Yasuhiro
× Kohsaka, Yasuhiro× Ishihara, Shoya× Kitayama, Tatsuki |
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信州大学研究者総覧へのリンク | ||||||
氏名 | Kohsaka, Yasuhiro | |||||
URL | http://soar-rd.shinshu-u.ac.jp/profile/ja.WNTUPVca.html | |||||
出版者 | ||||||
出版者 | WILEY-V C H VERLAG GMBH | |||||
引用 | ||||||
内容記述タイプ | Other | |||||
内容記述 | MACROMOLECULAR CHEMISTRY AND PHYSICS. 216(14):1534-1539 (2015) | |||||
書誌情報 |
MACROMOLECULAR CHEMISTRY AND PHYSICS 巻 216, 号 14, p. 1534-1539, 発行日 2015-07 |
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内容記述 | ||||||
内容記述タイプ | Other | |||||
内容記述 | Article first published online: 11 JUN 2015 | |||||
抄録 | ||||||
内容記述タイプ | Abstract | |||||
内容記述 | Anionic polymerization of n-butyl acrylate (nBA) in toluene initiated with a binary initiator, isopropyl α-lithioisobutyrate/ethylaluminum bis(2,6-di-tert-butylphenoxide) at −60 °C, is terminated with ethyl α-(chloromethyl)acrylate (ECMA) to afford a poly(nBA) possessing an acryloyl group at the terminal with 80% of termination efficiency. The reactivity of nBA against a polymer anion of methyl methacrylate formed under identical conditions is estimated relative to the termination with ECMA by reacting a mixture of nBA and ECMA followed by 1H NMR spectroscopic chain-end analysis; the relative reactivity of nBA is found 80 times or more higher than ECMA. | |||||
資源タイプ(コンテンツの種類) | ||||||
内容記述タイプ | Other | |||||
内容記述 | Article | |||||
ISSN | ||||||
収録物識別子タイプ | ISSN | |||||
収録物識別子 | 1022-1352 | |||||
書誌レコードID | ||||||
収録物識別子タイプ | NCID | |||||
収録物識別子 | AA10984295 | |||||
DOI | ||||||
識別子タイプ | DOI | |||||
関連識別子 | https://doi.org/10.1002/macp.201500100 | |||||
関連名称 | 10.1002/macp.201500100 | |||||
権利 | ||||||
権利情報 | This is the peer reviewed version of the following article: MACROMOLECULAR CHEMISTRY AND PHYSICS. 216(14):1534-1539 (2015), which has been published in final form at https://doi.org/10.1002/macp.201500100 This article may be used for non-commercial purposes in accordance with Wiley Terms and Conditions for Self-Archiving. | |||||
出版タイプ | ||||||
出版タイプ | AM | |||||
出版タイプResource | http://purl.org/coar/version/c_ab4af688f83e57aa | |||||
WoS | ||||||
表示名 | Web of Science | |||||
URL | http://gateway.isiknowledge.com/gateway/Gateway.cgi?&GWVersion=2&SrcAuth=ShinshuUniv&SrcApp=ShinshuUniv&DestLinkType=FullRecord&DestApp=WOS&KeyUT=000358120700005 |