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Termination of Living Anionic Polymerization of Butyl Acrylate with alpha-(Chloromethyl) acrylate for End-Functionalization and Application to the Evaluation of Monomer Reactivity
http://hdl.handle.net/10091/00018686
http://hdl.handle.net/10091/00018686e1049ddb-b6ee-4087-b6e0-1de84cfaa80c
| 名前 / ファイル | ライセンス | アクション |
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Termination_of_Living_Anionic_Polymerization.pdf (217.9 kB)
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| Item type | 学術雑誌論文 / Journal Article(1) | |||||||||||
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| 公開日 | 2016-03-23 | |||||||||||
| タイトル | ||||||||||||
| タイトル | Termination of Living Anionic Polymerization of Butyl Acrylate with alpha-(Chloromethyl) acrylate for End-Functionalization and Application to the Evaluation of Monomer Reactivity | |||||||||||
| 言語 | ||||||||||||
| 言語 | eng | |||||||||||
| DOI | ||||||||||||
| 関連識別子 | https://doi.org/10.1002/macp.201500100 | |||||||||||
| 関連名称 | 10.1002/macp.201500100 | |||||||||||
| キーワード | ||||||||||||
| 主題 | alpha-substituted acrylate, anionic polymerization, end-functional polymer, relative reactivity, terminator | |||||||||||
| 資源タイプ | ||||||||||||
| 資源 | http://purl.org/coar/resource_type/c_6501 | |||||||||||
| タイプ | journal article | |||||||||||
| 著者 |
Kohsaka, Yasuhiro
× Kohsaka, Yasuhiro
× Ishihara, Shoya
× Kitayama, Tatsuki
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| 信州大学研究者総覧へのリンク | ||||||||||||
| 氏名 | Kohsaka, Yasuhiro | |||||||||||
| URL | http://soar-rd.shinshu-u.ac.jp/profile/ja.WNTUPVca.html | |||||||||||
| 出版者 | ||||||||||||
| 出版者 | WILEY-V C H VERLAG GMBH | |||||||||||
| 引用 | ||||||||||||
| 内容記述 | MACROMOLECULAR CHEMISTRY AND PHYSICS. 216(14):1534-1539 (2015) | |||||||||||
| 書誌情報 |
MACROMOLECULAR CHEMISTRY AND PHYSICS 巻 216, 号 14, p. 1534-1539, 発行日 2015-07 |
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| 内容記述 | ||||||||||||
| 内容記述タイプ | Other | |||||||||||
| 内容記述 | Article first published online: 11 JUN 2015 | |||||||||||
| 抄録 | ||||||||||||
| 内容記述 | Anionic polymerization of n-butyl acrylate (nBA) in toluene initiated with a binary initiator, isopropyl α-lithioisobutyrate/ethylaluminum bis(2,6-di-tert-butylphenoxide) at −60 °C, is terminated with ethyl α-(chloromethyl)acrylate (ECMA) to afford a poly(nBA) possessing an acryloyl group at the terminal with 80% of termination efficiency. The reactivity of nBA against a polymer anion of methyl methacrylate formed under identical conditions is estimated relative to the termination with ECMA by reacting a mixture of nBA and ECMA followed by 1H NMR spectroscopic chain-end analysis; the relative reactivity of nBA is found 80 times or more higher than ECMA. | |||||||||||
| 資源タイプ（コンテンツの種類） | ||||||||||||
| ISSN | ||||||||||||
| 収録物識別子タイプ | ISSN | |||||||||||
| 収録物識別子 | 1022-1352 | |||||||||||
| 書誌レコードID | ||||||||||||
| 収録物識別子タイプ | NCID | |||||||||||
| 収録物識別子 | AA10984295 | |||||||||||
| 権利 | ||||||||||||
| 権利情報 | This is the peer reviewed version of the following article: MACROMOLECULAR CHEMISTRY AND PHYSICS. 216(14):1534-1539 (2015), which has been published in final form at https://doi.org/10.1002/macp.201500100 This article may be used for non-commercial purposes in accordance with Wiley Terms and Conditions for Self-Archiving. | |||||||||||
| 出版タイプ | ||||||||||||
| 出版タイプ | AM | |||||||||||
| 出版タイプResource | http://purl.org/coar/version/c_ab4af688f83e57aa | |||||||||||
| WoS | ||||||||||||
| URL | http://gateway.isiknowledge.com/gateway/Gateway.cgi?&GWVersion=2&SrcAuth=ShinshuUniv&SrcApp=ShinshuUniv&DestLinkType=FullRecord&DestApp=WOS&KeyUT=000358120700005 | |||||||||||
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Kohsaka, Yasuhiro, Ishihara, Shoya, Kitayama, Tatsuki, 2015, Termination of Living Anionic Polymerization of Butyl Acrylate with alpha-(Chloromethyl) acrylate for End-Functionalization and Application to the Evaluation of Monomer Reactivity: WILEY-V C H VERLAG GMBH, 1534–1539 p.
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