{"_buckets": {"deposit": "1ed1bc84-607c-435c-beef-dab7806b9e6a"}, "_deposit": {"id": "17918", "owners": [], "pid": {"revision_id": 0, "type": "depid", "value": "17918"}, "status": "published"}, "_oai": {"id": "oai:soar-ir.repo.nii.ac.jp:00017918", "sets": ["1309:1310"]}, "item_6_biblio_info_6": {"attribute_name": "\u66f8\u8a8c\u60c5\u5831", "attribute_value_mlt": [{"bibliographicIssueDates": {"bibliographicIssueDate": "2015-07", "bibliographicIssueDateType": "Issued"}, "bibliographicIssueNumber": "14", "bibliographicPageEnd": "1539", "bibliographicPageStart": "1534", "bibliographicVolumeNumber": "216", "bibliographic_titles": [{"bibliographic_title": "MACROMOLECULAR CHEMISTRY AND PHYSICS"}]}]}, "item_6_description_19": {"attribute_name": "\u5185\u5bb9\u8a18\u8ff0", "attribute_value_mlt": [{"subitem_description": "Article first published online: 11 JUN 2015", "subitem_description_type": "Other"}]}, "item_6_description_20": {"attribute_name": "\u6284\u9332", "attribute_value_mlt": [{"subitem_description": "Anionic polymerization of n-butyl acrylate (nBA) in toluene initiated with a binary initiator, isopropyl \u03b1-lithioisobutyrate/ethylaluminum bis(2,6-di-tert-butylphenoxide) at \u221260 \u00b0C, is terminated with ethyl \u03b1-(chloromethyl)acrylate (ECMA) to afford a poly(nBA) possessing an acryloyl group at the terminal with 80% of termination efficiency. The reactivity of nBA against a polymer anion of methyl methacrylate formed under identical conditions is estimated relative to the termination with ECMA by reacting a mixture of nBA and ECMA followed by 1H NMR spectroscopic chain-end analysis; the relative reactivity of nBA is found 80 times or more higher than ECMA.", "subitem_description_type": "Abstract"}]}, "item_6_description_30": {"attribute_name": "\u8cc7\u6e90\u30bf\u30a4\u30d7\uff08\u30b3\u30f3\u30c6\u30f3\u30c4\u306e\u7a2e\u985e\uff09", "attribute_value_mlt": [{"subitem_description": "Article", "subitem_description_type": "Other"}]}, "item_6_description_5": {"attribute_name": "\u5f15\u7528", "attribute_value_mlt": [{"subitem_description": "MACROMOLECULAR CHEMISTRY AND PHYSICS. 216(14):1534-1539 (2015)", "subitem_description_type": "Other"}]}, "item_6_link_3": {"attribute_name": "\u4fe1\u5dde\u5927\u5b66\u7814\u7a76\u8005\u7dcf\u89a7\u3078\u306e\u30ea\u30f3\u30af", "attribute_value_mlt": [{"subitem_link_text": "Kohsaka, Yasuhiro", "subitem_link_url": "http://soar-rd.shinshu-u.ac.jp/profile/ja.WNTUPVca.html"}]}, "item_6_link_67": {"attribute_name": "WoS", "attribute_value_mlt": [{"subitem_link_text": "Web of Science", "subitem_link_url": "http://gateway.isiknowledge.com/gateway/Gateway.cgi?\u0026GWVersion=2\u0026SrcAuth=ShinshuUniv\u0026SrcApp=ShinshuUniv\u0026DestLinkType=FullRecord\u0026DestApp=WOS\u0026KeyUT=000358120700005"}]}, "item_6_publisher_4": {"attribute_name": "\u51fa\u7248\u8005", "attribute_value_mlt": [{"subitem_publisher": "WILEY-V C H VERLAG GMBH"}]}, "item_6_relation_48": {"attribute_name": "DOI", "attribute_value_mlt": [{"subitem_relation_name": [{"subitem_relation_name_text": "10.1002/macp.201500100"}], "subitem_relation_type_id": {"subitem_relation_type_id_text": "http://dx.doi.org/10.1002/macp.201500100", "subitem_relation_type_select": "DOI"}}]}, "item_6_rights_62": {"attribute_name": "\u6a29\u5229", "attribute_value_mlt": [{"subitem_rights": "This is the peer reviewed version of the following article: MACROMOLECULAR CHEMISTRY AND PHYSICS. 216(14):1534-1539 (2015), which has been published in final form at http://dx.doi.org/10.1002/macp.201500100 This article may be used for non-commercial purposes in accordance with Wiley Terms and Conditions for Self-Archiving."}]}, "item_6_select_64": {"attribute_name": "\u8457\u8005\u7248\u30d5\u30e9\u30b0", "attribute_value_mlt": [{"subitem_select_item": "author"}]}, "item_6_source_id_35": {"attribute_name": "ISSN", "attribute_value_mlt": [{"subitem_source_identifier": "1022-1352", "subitem_source_identifier_type": "ISSN"}]}, "item_6_source_id_39": {"attribute_name": "NII ISSN", "attribute_value_mlt": [{"subitem_source_identifier": "1022-1352", "subitem_source_identifier_type": "ISSN"}]}, "item_6_source_id_40": {"attribute_name": "\u66f8\u8a8c\u30ec\u30b3\u30fc\u30c9ID", "attribute_value_mlt": [{"subitem_source_identifier": "AA10984295", "subitem_source_identifier_type": "NCID"}]}, "item_6_text_69": {"attribute_name": "wosonly authkey", "attribute_value_mlt": [{"subitem_text_value": "alpha-substituted acrylate@@@anionic polymerization@@@end-functional polymer@@@relative reactivity@@@terminator"}]}, "item_6_text_70": {"attribute_name": "wosonly keywords", "attribute_value_mlt": [{"subitem_text_value": "POLY(METHYL METHACRYLATE)@@@VINYL MONOMERS@@@CATIONIC-POLYMERIZATION@@@RADICAL POLYMERIZATION@@@METHYL-METHACRYLATE@@@CLICK-CHEMISTRY@@@POLYMERS@@@COPOLYMERIZATION@@@DERIVATIVES@@@SPECTRA"}]}, "item_6_textarea_68": {"attribute_name": "wosonly abstract", "attribute_value_mlt": [{"subitem_textarea_value": "Anionic polymerization of n-butyl acrylate (nBA) in toluene initiated with a binary initiator, isopropyl alpha-lithioisobutyrate/ethylaluminum bis(2,6-di-tert-butylphenoxide) at -60 degrees C, is terminated with ethyl alpha-(chloromethyl) acrylate (ECMA) to afford a poly(nBA) possessing an acryloyl group at the terminal with 80% of termination efficiency. The reactivity of nBA against a polymer anion of methyl methacrylate formed under identical conditions is estimated relative to the termination with ECMA by reacting a mixture of nBA and ECMA followed by H-1 NMR spectroscopic chain-end analysis; the relative reactivity of nBA is found 80 times or more higher than ECMA."}]}, "item_creator": {"attribute_name": "\u8457\u8005", "attribute_type": "creator", "attribute_value_mlt": [{"creatorNames": [{"creatorName": "Kohsaka,  Yasuhiro"}], "nameIdentifiers": [{"nameIdentifier": "50031", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Ishihara,  Shoya"}], "nameIdentifiers": [{"nameIdentifier": "50032", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Kitayama,  Tatsuki"}], "nameIdentifiers": [{"nameIdentifier": "50033", "nameIdentifierScheme": "WEKO"}]}]}, "item_files": {"attribute_name": "\u30d5\u30a1\u30a4\u30eb\u60c5\u5831", "attribute_type": "file", "attribute_value_mlt": [{"accessrole": "open_date", "date": [{"dateType": "Available", "dateValue": "2016-06-11"}], "displaytype": "detail", "download_preview_message": "", "file_order": 0, "filename": "Termination_of_Living_Anionic_Polymerization.pdf", "filesize": [{"value": "217.9 kB"}], "format": "application/pdf", "future_date_message": "", "is_thumbnail": false, "licensefree": "This is the peer reviewed version of the following article: MACROMOLECULAR CHEMISTRY AND PHYSICS. 216(14):1534-1539 (2015), which has been published in final form at http://dx.doi.org/10.1002/macp.201500100 This article may be used for non-commercial purposes in accordance with Wiley Terms and Conditions for Self-Archiving.", "licensetype": "license_free", "mimetype": "application/pdf", "size": 217900.0, "url": {"label": "Termination_of_Living_Anionic_Polymerization.pdf", "url": "https://soar-ir.repo.nii.ac.jp/record/17918/files/Termination_of_Living_Anionic_Polymerization.pdf"}, "version_id": "5f5558af-dcf4-42cf-ad4a-b6497a1c7678"}]}, "item_keyword": {"attribute_name": "\u30ad\u30fc\u30ef\u30fc\u30c9", "attribute_value_mlt": [{"subitem_subject": "alpha-substituted acrylate", "subitem_subject_scheme": "Other"}, {"subitem_subject": "anionic polymerization", "subitem_subject_scheme": "Other"}, {"subitem_subject": "end-functional polymer", "subitem_subject_scheme": "Other"}, {"subitem_subject": "relative reactivity", "subitem_subject_scheme": "Other"}, {"subitem_subject": "terminator", "subitem_subject_scheme": "Other"}]}, "item_language": {"attribute_name": "\u8a00\u8a9e", "attribute_value_mlt": [{"subitem_language": "eng"}]}, "item_resource_type": {"attribute_name": "\u8cc7\u6e90\u30bf\u30a4\u30d7", "attribute_value_mlt": [{"resourcetype": "journal article", "resourceuri": "http://purl.org/coar/resource_type/c_6501"}]}, "item_title": "Termination of Living Anionic Polymerization of Butyl Acrylate with alpha-(Chloromethyl) acrylate for End-Functionalization and Application to the Evaluation of Monomer Reactivity", "item_titles": {"attribute_name": "\u30bf\u30a4\u30c8\u30eb", "attribute_value_mlt": [{"subitem_title": "Termination of Living Anionic Polymerization of Butyl Acrylate with alpha-(Chloromethyl) acrylate for End-Functionalization and Application to the Evaluation of Monomer Reactivity"}]}, "item_type_id": "6", "owner": "1", "path": ["1309/1310"], "permalink_uri": "http://hdl.handle.net/10091/00018686", "pubdate": {"attribute_name": "\u516c\u958b\u65e5", "attribute_value": "2016-03-23"}, "publish_date": "2016-03-23", "publish_status": "0", "recid": "17918", "relation": {}, "relation_version_is_last": true, "title": ["Termination of Living Anionic Polymerization of Butyl Acrylate with alpha-(Chloromethyl) acrylate for End-Functionalization and Application to the Evaluation of Monomer Reactivity"], "weko_shared_id": null}