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α-exomethylene lactone possessing acetal–ester linkage: Polymerization and postpolymerization modification for water-soluble polymer
http://hdl.handle.net/10091/00018687
http://hdl.handle.net/10091/0001868774a4b45f-5e5e-417f-a493-b11b2bbc8a58
名前 / ファイル | ライセンス | アクション |
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Item type | 学術雑誌論文 / Journal Article(1) | |||||
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公開日 | 2016-03-23 | |||||
タイトル | ||||||
言語 | en | |||||
タイトル | α-exomethylene lactone possessing acetal–ester linkage: Polymerization and postpolymerization modification for water-soluble polymer | |||||
言語 | ||||||
言語 | eng | |||||
資源タイプ | ||||||
資源 | http://purl.org/coar/resource_type/c_6501 | |||||
タイプ | journal article | |||||
著者 |
Kohsaka, Yasuhiro
× Kohsaka, Yasuhiro× Matsumoto, Yusuke× Zhang, Tianyi× Matsuhashi, Yosuke× Kitayama, Tatsuki |
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信州大学研究者総覧へのリンク | ||||||
氏名 | Kohsaka, Yasuhiro | |||||
URL | http://soar-rd.shinshu-u.ac.jp/profile/ja.WNTUPVca.html | |||||
出版者 | ||||||
出版者 | WILEY | |||||
引用 | ||||||
内容記述タイプ | Other | |||||
内容記述 | Journal of Polymer Science Part A: Polymer Chemistry. 54(7):955-961 (2016) | |||||
書誌情報 |
Journal of Polymer Science Part A: Polymer Chemistry 巻 54, 号 7, p. 955-961, 発行日 2016-04-01 |
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内容記述 | ||||||
内容記述タイプ | Other | |||||
内容記述 | First published: 16 October 2015 | |||||
抄録 | ||||||
内容記述タイプ | Abstract | |||||
内容記述 | 2,6-Dimethyl-5-methylene-1,3-dioxa-4-one (DMDO), a cyclic acrylate possessing acetal–ester linkage, was obtained as a mixture of cis- and trans-isomers (95:5) from Baylis–Hillman reaction of an aryl acrylate. The radical and anionic polymerizations of DMDO yielded the corresponding vinyl polymers without any side reactions such as cleavage of the acetal–ester linkage. The polymerization behaviors were significantly different from that of the acyclic acrylate, α-(hydroxymethyl)acrylic acid, which was expected inactive against polymerization due to the steric hindrance around the vinylidene group by the α-substituent. The acetal–ester linkage of the obtained polymer (P1) was completely cleaved via acid hydrolysis to afford a water soluble polymer, P2. © 2015 Wiley Periodicals, Inc. J. Polym. Sci., Part A: Polym. Chem. 2016, 54, 955–961 | |||||
資源タイプ(コンテンツの種類) | ||||||
内容記述タイプ | Other | |||||
内容記述 | Article | |||||
ISSN | ||||||
収録物識別子タイプ | ISSN | |||||
収録物識別子 | 0887-624X | |||||
書誌レコードID | ||||||
収録物識別子タイプ | NCID | |||||
収録物識別子 | AA1068915X | |||||
DOI | ||||||
識別子タイプ | DOI | |||||
関連識別子 | https://doi.org/10.1002/pola.27931 | |||||
関連名称 | 10.1002/pola.27931 | |||||
権利 | ||||||
権利情報 | This is the peer reviewed version of the following article: Journal of Polymer Science Part A: Polymer Chemistry. 54(7):955-961 (2016), which has been published in final form at https://doi.org/10.1002/pola.27931 This article may be used for non-commercial purposes in accordance with Wiley Terms and Conditions for Self-Archiving. | |||||
出版タイプ | ||||||
出版タイプ | AM | |||||
出版タイプResource | http://purl.org/coar/version/c_ab4af688f83e57aa | |||||
WoS | ||||||
表示名 | Web of Science | |||||
URL | http://gateway.isiknowledge.com/gateway/Gateway.cgi?&GWVersion=2&SrcAuth=ShinshuUniv&SrcApp=ShinshuUniv&DestLinkType=FullRecord&DestApp=WOS&KeyUT=000371610100009 |