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Their phase transition behavior and the mesophase structure have been established by using a polarizing optical microscope, a differential scanning calorimeter, and a temperature-dependent small angle X-ray diffractometer. Very interestingly, the mesomorphism appears with strong dependence of the position of nitrogen in m-chloropyridyloxy group. The derivative [3-PyO(m-Cl)](8)PcCu (2b) introduced a nitrogen atom at the 3-position is not mesogenic but crystalline. On the other hand, the derivative [2-PyO(m-Cl)](8)PcCu (2a) introduced a nitrogen atom at the 2-position shows columnar mesomorphism only at very high temperatures over 325 degrees C. The derivative [4-PyO(m-Cl)](8)PcCu (2c) introduced a nitrogen atom at the 4-position shows columnar mesomorphism in a very wide temperature region from rt to the decomposition temperature at 306 degrees C. 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Flying-seed-like liquid crystals 7(+): Synthesis and mesomorphism of novel octakis(m-chloropyridyloxy) phthalocyanato copper(II) complexes
http://hdl.handle.net/10091/00019974
http://hdl.handle.net/10091/00019974526057d7-0ce0-4f8d-b7db-866c84c802a8
名前 / ファイル | ライセンス | アクション |
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Item type | 学術雑誌論文 / Journal Article(1) | |||||
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公開日 | 2017-09-26 | |||||
タイトル | ||||||
言語 | en | |||||
タイトル | Flying-seed-like liquid crystals 7(+): Synthesis and mesomorphism of novel octakis(m-chloropyridyloxy) phthalocyanato copper(II) complexes | |||||
言語 | ||||||
言語 | eng | |||||
キーワード | ||||||
主題Scheme | Other | |||||
主題 | flying-seed-like liquid crystals | |||||
キーワード | ||||||
主題Scheme | Other | |||||
主題 | metallomesogen | |||||
キーワード | ||||||
主題Scheme | Other | |||||
主題 | phthalocyanine | |||||
キーワード | ||||||
主題Scheme | Other | |||||
主題 | columnar mesophase | |||||
資源タイプ | ||||||
資源 | http://purl.org/coar/resource_type/c_6501 | |||||
タイプ | journal article | |||||
著者 |
Ohta, Kazuchika
× Ohta, Kazuchika× Adachi, Kaori× Yasutake, Mikio |
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信州大学研究者総覧へのリンク | ||||||
氏名 | Ohta, Kazuchika | |||||
URL | http://soar-rd.shinshu-u.ac.jp/profile/ja.yVLFjekV.html | |||||
出版者 | ||||||
出版者 | WORLD SCI PUBL CO INC | |||||
引用 | ||||||
内容記述タイプ | Other | |||||
内容記述 | JOURNAL OF PORPHYRINS AND PHTHALOCYANINES. 21(1):48-58 (2017) | |||||
書誌情報 |
JOURNAL OF PORPHYRINS AND PHTHALOCYANINES 巻 21, 号 1, p. 48-58, 発行日 2017-01 |
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抄録 | ||||||
内容記述タイプ | Abstract | |||||
内容記述 | We have synthesized three novel octakis(m-chloropyridyloxy) phthalocyaninato copper(II) complexes, [x-PyO(m-Cl)](8)PcCu(x = 2, 3, 4: 2a-2c), keeping a chlorine atom at the meta position on the 2-, 3- and 4-pyridyloxy group, in which the nitrogen atom is located at the 2-, 3-and 4-positions, respectively. Their phase transition behavior and the mesophase structure have been established by using a polarizing optical microscope, a differential scanning calorimeter, and a temperature-dependent small angle X-ray diffractometer. Very interestingly, the mesomorphism appears with strong dependence of the position of nitrogen in m-chloropyridyloxy group. The derivative [3-PyO(m-Cl)](8)PcCu (2b) introduced a nitrogen atom at the 3-position is not mesogenic but crystalline. On the other hand, the derivative [2-PyO(m-Cl)](8)PcCu (2a) introduced a nitrogen atom at the 2-position shows columnar mesomorphism only at very high temperatures over 325 degrees C. The derivative [4-PyO(m-Cl)](8)PcCu (2c) introduced a nitrogen atom at the 4-position shows columnar mesomorphism in a very wide temperature region from rt to the decomposition temperature at 306 degrees C. From the viewpoint of N center dot center dot center dot Cl halogen bond, we have discussed about relationship between their mesomorphism and the position of nitrogen atom in m-chloropyridyloxy group. | |||||
資源タイプ(コンテンツの種類) | ||||||
内容記述タイプ | Other | |||||
内容記述 | Article | |||||
ISSN | ||||||
収録物識別子タイプ | ISSN | |||||
収録物識別子 | 1088-4246 | |||||
書誌レコードID | ||||||
収録物識別子タイプ | NCID | |||||
収録物識別子 | AA11202421 | |||||
DOI | ||||||
識別子タイプ | DOI | |||||
関連識別子 | https://doi.org/10.1142/S1088424617500043 | |||||
関連名称 | 10.1142/S1088424617500043 | |||||
権利 | ||||||
権利情報 | Electronic version of an article published as Journal of porphyrins and phthalocyanines, Volume: 21, Issues: 1(2017) pp. 48-58, DOI: 10.1142/S1088424617500043 © 2017 World Scientific Publishing Copmpany, http://www.worldscientific.com/worldscinet/jpp | |||||
出版タイプ | ||||||
出版タイプ | AM | |||||
出版タイプResource | http://purl.org/coar/version/c_ab4af688f83e57aa | |||||
WoS | ||||||
表示名 | Web of Science | |||||
URL | http://gateway.isiknowledge.com/gateway/Gateway.cgi?&GWVersion=2&SrcAuth=ShinshuUniv&SrcApp=ShinshuUniv&DestLinkType=FullRecord&DestApp=WOS&KeyUT=000396390700007 |