{"_buckets": {"deposit": "cb223ad2-3b71-4bc8-b111-4c91a0b14438"}, "_deposit": {"id": "19212", "owners": [], "pid": {"revision_id": 0, "type": "depid", "value": "19212"}, "status": "published"}, "_oai": {"id": "oai:soar-ir.repo.nii.ac.jp:00019212", "sets": ["1310"]}, "author_link": ["104233", "104234", "104235"], "item_1628147817048": {"attribute_name": "出版タイプ", "attribute_value_mlt": [{"subitem_version_resource": "http://purl.org/coar/version/c_ab4af688f83e57aa", "subitem_version_type": "AM"}]}, "item_6_biblio_info_6": {"attribute_name": "書誌情報", "attribute_value_mlt": [{"bibliographicIssueDates": {"bibliographicIssueDate": "2017-01", "bibliographicIssueDateType": "Issued"}, "bibliographicIssueNumber": "1", "bibliographicPageEnd": "58", "bibliographicPageStart": "48", "bibliographicVolumeNumber": "21", "bibliographic_titles": [{"bibliographic_title": "JOURNAL OF PORPHYRINS AND PHTHALOCYANINES"}]}]}, "item_6_description_20": {"attribute_name": "抄録", "attribute_value_mlt": [{"subitem_description": "We have synthesized three novel octakis(m-chloropyridyloxy) phthalocyaninato copper(II) complexes, [x-PyO(m-Cl)](8)PcCu(x = 2, 3, 4: 2a-2c), keeping a chlorine atom at the meta position on the 2-, 3- and 4-pyridyloxy group, in which the nitrogen atom is located at the 2-, 3-and 4-positions, respectively. Their phase transition behavior and the mesophase structure have been established by using a polarizing optical microscope, a differential scanning calorimeter, and a temperature-dependent small angle X-ray diffractometer. Very interestingly, the mesomorphism appears with strong dependence of the position of nitrogen in m-chloropyridyloxy group. The derivative [3-PyO(m-Cl)](8)PcCu (2b) introduced a nitrogen atom at the 3-position is not mesogenic but crystalline. On the other hand, the derivative [2-PyO(m-Cl)](8)PcCu (2a) introduced a nitrogen atom at the 2-position shows columnar mesomorphism only at very high temperatures over 325 degrees C. The derivative [4-PyO(m-Cl)](8)PcCu (2c) introduced a nitrogen atom at the 4-position shows columnar mesomorphism in a very wide temperature region from rt to the decomposition temperature at 306 degrees C. From the viewpoint of N center dot center dot center dot Cl halogen bond, we have discussed about relationship between their mesomorphism and the position of nitrogen atom in m-chloropyridyloxy group.", "subitem_description_type": "Abstract"}]}, "item_6_description_30": {"attribute_name": "資源タイプ（コンテンツの種類）", "attribute_value_mlt": [{"subitem_description": "Article", "subitem_description_type": "Other"}]}, "item_6_description_5": {"attribute_name": "引用", "attribute_value_mlt": [{"subitem_description": "JOURNAL OF PORPHYRINS AND PHTHALOCYANINES. 21(1):48-58 (2017)", "subitem_description_type": "Other"}]}, "item_6_link_3": {"attribute_name": "信州大学研究者総覧へのリンク", "attribute_value_mlt": [{"subitem_link_text": "Ohta, Kazuchika", "subitem_link_url": "http://soar-rd.shinshu-u.ac.jp/profile/ja.yVLFjekV.html"}]}, "item_6_link_67": {"attribute_name": "WoS", "attribute_value_mlt": [{"subitem_link_text": "Web of Science", "subitem_link_url": "http://gateway.isiknowledge.com/gateway/Gateway.cgi?\u0026GWVersion=2\u0026SrcAuth=ShinshuUniv\u0026SrcApp=ShinshuUniv\u0026DestLinkType=FullRecord\u0026DestApp=WOS\u0026KeyUT=000396390700007"}]}, "item_6_publisher_4": {"attribute_name": "出版者", "attribute_value_mlt": [{"subitem_publisher": "WORLD SCI PUBL CO INC"}]}, "item_6_relation_48": {"attribute_name": "DOI", "attribute_value_mlt": [{"subitem_relation_name": [{"subitem_relation_name_text": "10.1142/S1088424617500043"}], "subitem_relation_type_id": {"subitem_relation_type_id_text": "https://doi.org/10.1142/S1088424617500043", "subitem_relation_type_select": "DOI"}}]}, "item_6_rights_62": {"attribute_name": "権利", "attribute_value_mlt": [{"subitem_rights": "Electronic version of an article published as Journal of porphyrins and phthalocyanines, Volume: 21, Issues: 1(2017) pp. 48-58, DOI: 10.1142/S1088424617500043 © 2017 World Scientific Publishing Copmpany, http://www.worldscientific.com/worldscinet/jpp"}]}, "item_6_select_64": {"attribute_name": "著者版フラグ", "attribute_value_mlt": [{"subitem_select_item": "author"}]}, "item_6_source_id_35": {"attribute_name": "ISSN", "attribute_value_mlt": [{"subitem_source_identifier": "1088-4246", "subitem_source_identifier_type": "ISSN"}]}, "item_6_source_id_39": {"attribute_name": "NII ISSN", "attribute_value_mlt": [{"subitem_source_identifier": "1088-4246", "subitem_source_identifier_type": "ISSN"}]}, "item_6_source_id_40": {"attribute_name": "書誌レコードID", "attribute_value_mlt": [{"subitem_source_identifier": "AA11202421", "subitem_source_identifier_type": "NCID"}]}, "item_6_text_69": {"attribute_name": "wosonly authkey", "attribute_value_mlt": [{"subitem_text_value": "flying-seed-like liquid crystals; metallomesogen; phthalocyanine; columnar mesophase"}]}, "item_6_text_70": {"attribute_name": "wosonly keywords", "attribute_value_mlt": [{"subitem_text_value": "HALOGEN-BONDED COMPLEXES; LONG ALKYL CHAINS; SUPRAMOLECULAR MATERIALS; 4-ALKOXYSTILBAZOLES; HYDROGEN"}]}, "item_6_textarea_68": {"attribute_name": "wosonly abstract", "attribute_value_mlt": [{"subitem_textarea_value": "We have synthesized three novel octakis(m-chloropyridyloxy) phthalocyaninato copper(II) complexes, [x-PyO(m-Cl)](8)PcCu(x = 2, 3, 4: 2a-2c), keeping a chlorine atom at the meta position on the 2-, 3- and 4-pyridyloxy group, in which the nitrogen atom is located at the 2-, 3-and 4-positions, respectively. Their phase transition behavior and the mesophase structure have been established by using a polarizing optical microscope, a differential scanning calorimeter, and a temperature-dependent small angle X-ray diffractometer. Very interestingly, the mesomorphism appears with strong dependence of the position of nitrogen in m-chloropyridyloxy group. The derivative [3-PyO(m-Cl)](8)PcCu (2b) introduced a nitrogen atom at the 3-position is not mesogenic but crystalline. On the other hand, the derivative [2-PyO(m-Cl)](8)PcCu (2a) introduced a nitrogen atom at the 2-position shows columnar mesomorphism only at very high temperatures over 325 degrees C. The derivative [4-PyO(m-Cl)](8)PcCu (2c) introduced a nitrogen atom at the 4-position shows columnar mesomorphism in a very wide temperature region from rt to the decomposition temperature at 306 degrees C. From the viewpoint of N center dot center dot center dot Cl halogen bond, we have discussed about relationship between their mesomorphism and the position of nitrogen atom in m-chloropyridyloxy group."}]}, "item_creator": {"attribute_name": "著者", "attribute_type": "creator", "attribute_value_mlt": [{"creatorNames": [{"creatorName": "Ohta, Kazuchika"}], "nameIdentifiers": [{"nameIdentifier": "104233", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Adachi, Kaori"}], "nameIdentifiers": [{"nameIdentifier": "104234", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Yasutake, Mikio"}], "nameIdentifiers": [{"nameIdentifier": "104235", "nameIdentifierScheme": "WEKO"}]}]}, "item_files": {"attribute_name": "ファイル情報", "attribute_type": "file", "attribute_value_mlt": [{"accessrole": "open_date", "date": [{"dateType": "Available", "dateValue": "2018-01-01"}], "displaytype": "detail", "download_preview_message": "", "file_order": 0, "filename": "Flying-seed-like_liquid_crystals_7.pdf", "filesize": [{"value": "1.2 MB"}], "format": "application/pdf", "future_date_message": "", "is_thumbnail": false, "licensefree": "Electronic version of an article published as Journal of porphyrins and phthalocyanines, Volume: 21, Issues: 1(2017) pp. 48-58, DOI: 10.1142/S1088424617500043 © 2017 World Scientific Publishing Copmpany, http://www.worldscientific.com/worldscinet/jpp", "licensetype": "license_note", "mimetype": "application/pdf", "size": 1200000.0, "url": {"label": "Flying-seed-like_liquid_crystals_7.pdf", "url": "https://soar-ir.repo.nii.ac.jp/record/19212/files/Flying-seed-like_liquid_crystals_7.pdf"}, "version_id": "94886a2e-4853-4324-a32a-f80ac162c163"}]}, "item_keyword": {"attribute_name": "キーワード", "attribute_value_mlt": [{"subitem_subject": "flying-seed-like liquid crystals", "subitem_subject_scheme": "Other"}, {"subitem_subject": "metallomesogen", "subitem_subject_scheme": "Other"}, {"subitem_subject": "phthalocyanine", "subitem_subject_scheme": "Other"}, {"subitem_subject": "columnar mesophase", "subitem_subject_scheme": "Other"}]}, "item_language": {"attribute_name": "言語", "attribute_value_mlt": [{"subitem_language": "eng"}]}, "item_resource_type": {"attribute_name": "資源タイプ", "attribute_value_mlt": [{"resourcetype": "journal article", "resourceuri": "http://purl.org/coar/resource_type/c_6501"}]}, "item_title": "Flying-seed-like liquid crystals 7(+): Synthesis and mesomorphism of novel octakis(m-chloropyridyloxy) phthalocyanato copper(II) complexes", "item_titles": {"attribute_name": "タイトル", "attribute_value_mlt": [{"subitem_title": "Flying-seed-like liquid crystals 7(+): Synthesis and mesomorphism of novel octakis(m-chloropyridyloxy) phthalocyanato copper(II) complexes", "subitem_title_language": "en"}]}, "item_type_id": "6", "owner": "1", "path": ["1310"], "permalink_uri": "http://hdl.handle.net/10091/00019974", "pubdate": {"attribute_name": "PubDate", "attribute_value": "2017-09-26"}, "publish_date": "2017-09-26", "publish_status": "0", "recid": "19212", "relation": {}, "relation_version_is_last": true, "title": ["Flying-seed-like liquid crystals 7(+): Synthesis and mesomorphism of novel octakis(m-chloropyridyloxy) phthalocyanato copper(II) complexes"], "weko_shared_id": -1}