{"_buckets": {"deposit": "58d3b5c5-121d-44d1-8853-102398770fca"}, "_deposit": {"id": "19580", "owners": [], "pid": {"revision_id": 0, "type": "depid", "value": "19580"}, "status": "published"}, "_oai": {"id": "oai:soar-ir.repo.nii.ac.jp:00019580", "sets": ["1222"]}, "author_link": ["105106", "105107", "105108", "105109", "105110"], "item_1628147817048": {"attribute_name": "出版タイプ", "attribute_value_mlt": [{"subitem_version_resource": "http://purl.org/coar/version/c_ab4af688f83e57aa", "subitem_version_type": "AM"}]}, "item_6_biblio_info_6": {"attribute_name": "書誌情報", "attribute_value_mlt": [{"bibliographicIssueDates": {"bibliographicIssueDate": "2015", "bibliographicIssueDateType": "Issued"}, "bibliographicIssueNumber": "6", "bibliographicPageEnd": "455", "bibliographicPageStart": "449", "bibliographicVolumeNumber": "47", "bibliographic_titles": [{"bibliographic_title": "POLYMER JOURNAL"}]}]}, "item_6_description_20": {"attribute_name": "抄録", "attribute_value_mlt": [{"subitem_description": "Porous thin-film polymethylsiloxane microparticles have been prepared successfully from octyltrichlorosilane and methyltrichlorosilane in (water/oil) W/O emulsion systems by using several oil phases and changing the amount of the silanes or of the surfactant Span 60. Hollow microspheres of various shell thicknesses (120-180 nm) and high surface area were prepared by using four types of nonpolar solvents as the oil phase of the W/O emulsion system. The diameter of the spheres can also be controlled (1-1.6 mu m) by using different oil phases. The results of thermal analysis, nitrogen adsorption isotherm, infrared spectra and X-ray diffraction data showed that hollow microspheres of amorphous polymethylsiloxane with high surface area (360-385 m(2)g(-1)) can be obtained by heating the spheres in air at 673 K; the polymethylsiloxane microspheres become nonporous silica particles after calcination at 873 K for 3 h. Cup-shape microparticles of polymethylsiloxane with nano-order thickness (20-120 nm) were prepared by reducing the amount of silanes in the mixture. Small hollow particles were prepared by replacing a portion of the octyltrichlorosilane with Span 60.", "subitem_description_type": "Abstract"}]}, "item_6_description_30": {"attribute_name": "資源タイプ（コンテンツの種類）", "attribute_value_mlt": [{"subitem_description": "Article", "subitem_description_type": "Other"}]}, "item_6_description_5": {"attribute_name": "引用", "attribute_value_mlt": [{"subitem_description": "POLYMER JOURNAL. 47(6): 449-455 (2015)", "subitem_description_type": "Other"}]}, "item_6_link_3": {"attribute_name": "信州大学研究者総覧へのリンク", "attribute_value_mlt": [{"subitem_link_text": "Okada, Tomohiko", "subitem_link_url": "http://soar-rd.shinshu-u.ac.jp/profile/ja.WpDFbpkh.html"}, {"subitem_link_text": "Sakai, Toshio", "subitem_link_url": "http://soar-rd.shinshu-u.ac.jp/profile/ja.OhkpjFkV.html"}, {"subitem_link_text": "Haeiwa, Tetsuji", "subitem_link_url": "http://soar-rd.shinshu-u.ac.jp/profile/ja.ZNkeZVkh.html"}]}, "item_6_link_67": {"attribute_name": "WoS", "attribute_value_mlt": [{"subitem_link_text": "Web of Science", "subitem_link_url": "http://gateway.isiknowledge.com/gateway/Gateway.cgi?\u0026GWVersion=2\u0026SrcAuth=ShinshuUniv\u0026SrcApp=ShinshuUniv\u0026DestLinkType=FullRecord\u0026DestApp=WOS\u0026KeyUT=000355744300007"}]}, "item_6_publisher_4": {"attribute_name": "出版者", "attribute_value_mlt": [{"subitem_publisher": "NATURE PUBLISHING GROUP"}]}, "item_6_relation_48": {"attribute_name": "DOI", "attribute_value_mlt": [{"subitem_relation_name": [{"subitem_relation_name_text": "10.1038/pj.2015.16"}], "subitem_relation_type_id": {"subitem_relation_type_id_text": "https://doi.org/10.1038/pj.2015.16", "subitem_relation_type_select": "DOI"}}]}, "item_6_rights_62": {"attribute_name": "権利", "attribute_value_mlt": [{"subitem_rights": "Copyright© 2015 The Society of Polymer Science, Japan"}]}, "item_6_select_64": {"attribute_name": "著者版フラグ", "attribute_value_mlt": [{"subitem_select_item": "author"}]}, "item_6_source_id_35": {"attribute_name": "ISSN", "attribute_value_mlt": [{"subitem_source_identifier": "0032-3896", "subitem_source_identifier_type": "ISSN"}]}, "item_6_source_id_39": {"attribute_name": "NII ISSN", "attribute_value_mlt": [{"subitem_source_identifier": "0032-3896", "subitem_source_identifier_type": "ISSN"}]}, "item_6_text_70": {"attribute_name": "wosonly keywords", "attribute_value_mlt": [{"subitem_text_value": "HOLLOW SILICA MICROSPHERES@@@SOLID ACID CATALYSIS@@@CORE-SHELL PARTICLES@@@MICROEMULSION SYSTEM@@@DENSE SILICA@@@SPHERES@@@FABRICATION@@@ADSORPTION@@@OXIDATION"}]}, "item_creator": {"attribute_name": "著者", "attribute_type": "creator", "attribute_value_mlt": [{"creatorNames": [{"creatorName": "Mishima, Shozi"}], "nameIdentifiers": [{"nameIdentifier": "105106", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Okada, Tomohiko"}], "nameIdentifiers": [{"nameIdentifier": "105107", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Sakai, Toshio"}], "nameIdentifiers": [{"nameIdentifier": "105108", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Kiyono, Ryutaro"}], "nameIdentifiers": [{"nameIdentifier": "105109", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Haeiwa, Tetsuji"}], "nameIdentifiers": [{"nameIdentifier": "105110", "nameIdentifierScheme": "WEKO"}]}]}, "item_files": {"attribute_name": "ファイル情報", "attribute_type": "file", "attribute_value_mlt": [{"accessrole": "open_date", "date": [{"dateType": "Available", "dateValue": "2018-03-09"}], "displaytype": "detail", "download_preview_message": "", "file_order": 0, "filename": "Preparation_of_porous_thin-film_polymethylsiloxane_microparticles_in_a_WO_emulsion_system.pdf", "filesize": [{"value": "219.6 kB"}], "format": "application/pdf", "future_date_message": "", "is_thumbnail": false, "licensefree": "Copyright© 2015 The Society of Polymer Science, Japan", "licensetype": "license_note", "mimetype": "application/pdf", "size": 219600.0, "url": {"label": 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"http://hdl.handle.net/10091/00020341", "pubdate": {"attribute_name": "PubDate", "attribute_value": "2018-03-09"}, "publish_date": "2018-03-09", "publish_status": "0", "recid": "19580", "relation": {}, "relation_version_is_last": true, "title": ["Preparation of porous thin-film polymethylsiloxane microparticles in a W/O emulsion system"], "weko_shared_id": -1}