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  1. 040 理学部
  2. 0401 学術論文

Synthesis of 2-Azulenyl-1,1,4,4-tetracyano-3-ferrocenyl-1,3-butadienes by [2+2] Cycloaddition of (Ferrocenylethynyl)azulenes with Tetracyanoethylene

http://hdl.handle.net/10091/00020640
http://hdl.handle.net/10091/00020640
e9dd83c9-a041-4814-9380-340f2960525b
名前 / ファイル ライセンス アクション
Chem_Eur_J_19_5721-5730.pdf Chem_Eur_J_19_5721-5730.pdf (607.4 kB)
Item type 学術雑誌論文 / Journal Article(1)
公開日 2018-06-13
タイトル
言語 en
タイトル Synthesis of 2-Azulenyl-1,1,4,4-tetracyano-3-ferrocenyl-1,3-butadienes by [2+2] Cycloaddition of (Ferrocenylethynyl)azulenes with Tetracyanoethylene
言語
言語 eng
キーワード
主題Scheme Other
主題 azulene
キーワード
主題Scheme Other
主題 cycloaddition
キーワード
主題Scheme Other
主題 donoracceptor systems
キーワード
主題Scheme Other
主題 electrochemistry
キーワード
主題Scheme Other
主題 ferrocene
資源タイプ
資源 http://purl.org/coar/resource_type/c_6501
タイプ journal article
著者 Shoji, Taku

× Shoji, Taku

WEKO 105691

Shoji, Taku

Search repository
Ito, Shunji

× Ito, Shunji

WEKO 105692

Ito, Shunji

Search repository
Okujima, Tetsuo

× Okujima, Tetsuo

WEKO 105693

Okujima, Tetsuo

Search repository
Morita, Noboru

× Morita, Noboru

WEKO 105694

Morita, Noboru

Search repository
信州大学研究者総覧へのリンク
氏名 Shoji, Taku
URL http://soar-rd.shinshu-u.ac.jp/profile/ja.gmShOakh.html
出版者
出版者 WILEY-V C H VERLAG GMBH
引用
内容記述タイプ Other
内容記述 CHEMISTRY-A EUROPEAN JOURNAL. 19(18):5721-5730 (2013)
書誌情報 CHEMISTRY-A EUROPEAN JOURNAL

巻 19, 号 18, p. 5721-5730, 発行日 2013-04
抄録
内容記述タイプ Abstract
内容記述 1-, 2-, and 6-(Ferrocenylethynyl)azulene derivatives 1016 have been prepared by palladium-catalyzed alkynylation of ethynylferrocene with the corresponding haloazulenes under SonogashiraHagihara conditions. Compounds 1016 reacted with tetracyanoethylene (TCNE) in a [2+2] cycloadditioncycloreversion reaction to afford the corresponding 2-azulenyl-1,1,4,4,-tetracyano-3-ferrocenyl-1,3-butadiene chromophores 1723 in excellent yields. The redox behavior of the novel azulene chromophores 1723 was examined by using cyclic voltammetry (CV) and differential pulse voltammetry (DPV), which revealed their multistep electrochemical reduction properties. Moreover, a significant color change was observed by visible spectroscopy under electrochemical reduction conditions.
資源タイプ(コンテンツの種類)
内容記述タイプ Other
内容記述 Article
ISSN
収録物識別子タイプ ISSN
収録物識別子 0947-6539
書誌レコードID
収録物識別子タイプ NCID
収録物識別子 AA11076269
PubMed
識別子タイプ PMID
関連識別子 http://www.ncbi.nlm.nih.gov/entrez/query.fcgi?CMD=search&DB=pubmed&term=23447514
関連名称 23447514
DOI
識別子タイプ DOI
関連識別子 https://doi.org/10.1002/chem.201202257
関連名称 10.1002/chem.201202257
権利
権利情報 This is the peer reviewed version of the following article: Shoji, T. , Ito, S. , Okujima, T. and Morita, N. (2013), Synthesis of 2‐Azulenyl‐1,1,4,4‐tetracyano‐3‐ferrocenyl‐1,3‐butadienes by [2+2] Cycloaddition of (Ferrocenylethynyl)azulenes with Tetracyanoethylene. Chem. Eur. J., 19: 5721-5730. doi:10.1002/chem.201202257, which has been published in final form at |https://doi.org/10.1002/chem.201202257 . This article may be used for non-commercial purposes in accordance with Wiley Terms and Conditions for Self-Archiving.
出版タイプ
出版タイプ AM
出版タイプResource http://purl.org/coar/version/c_ab4af688f83e57aa
WoS
表示名 Web of Science
URL http://gateway.isiknowledge.com/gateway/Gateway.cgi?&GWVersion=2&SrcAuth=ShinshuUniv&SrcApp=ShinshuUniv&DestLinkType=FullRecord&DestApp=WOS&KeyUT=000318282200029
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