Item type |
学術雑誌論文 / Journal Article(1) |
公開日 |
2018-06-13 |
タイトル |
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タイトル |
Synthesis of 2-Azulenyl-1,1,4,4-tetracyano-3-ferrocenyl-1,3-butadienes by [2+2] Cycloaddition of (Ferrocenylethynyl)azulenes with Tetracyanoethylene |
言語 |
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言語 |
eng |
DOI |
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関連識別子 |
https://doi.org/10.1002/chem.201202257 |
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関連名称 |
10.1002/chem.201202257 |
キーワード |
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主題 |
azulene, cycloaddition, donoracceptor systems, electrochemistry, ferrocene |
資源タイプ |
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資源 |
http://purl.org/coar/resource_type/c_6501 |
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タイプ |
journal article |
著者 |
Shoji, Taku
Ito, Shunji
Okujima, Tetsuo
Morita, Noboru
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信州大学研究者総覧へのリンク |
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氏名 |
Shoji, Taku |
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URL |
http://soar-rd.shinshu-u.ac.jp/profile/ja.gmShOakh.html |
出版者 |
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出版者 |
WILEY-V C H VERLAG GMBH |
引用 |
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内容記述 |
CHEMISTRY-A EUROPEAN JOURNAL. 19(18):5721-5730 (2013) |
書誌情報 |
CHEMISTRY-A EUROPEAN JOURNAL
巻 19,
号 18,
p. 5721-5730,
発行日 2013-04
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抄録 |
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内容記述 |
1-, 2-, and 6-(Ferrocenylethynyl)azulene derivatives 1016 have been prepared by palladium-catalyzed alkynylation of ethynylferrocene with the corresponding haloazulenes under SonogashiraHagihara conditions. Compounds 1016 reacted with tetracyanoethylene (TCNE) in a [2+2] cycloadditioncycloreversion reaction to afford the corresponding 2-azulenyl-1,1,4,4,-tetracyano-3-ferrocenyl-1,3-butadiene chromophores 1723 in excellent yields. The redox behavior of the novel azulene chromophores 1723 was examined by using cyclic voltammetry (CV) and differential pulse voltammetry (DPV), which revealed their multistep electrochemical reduction properties. Moreover, a significant color change was observed by visible spectroscopy under electrochemical reduction conditions. |
資源タイプ(コンテンツの種類) |
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内容記述 |
Article |
ISSN |
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収録物識別子タイプ |
ISSN |
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収録物識別子 |
0947-6539 |
書誌レコードID |
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収録物識別子タイプ |
NCID |
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収録物識別子 |
AA11076269 |
PubMed |
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関連識別子 |
http://www.ncbi.nlm.nih.gov/entrez/query.fcgi?CMD=search&DB=pubmed&term=23447514 |
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関連名称 |
23447514 |
権利 |
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権利情報 |
This is the peer reviewed version of the following article: Shoji, T. , Ito, S. , Okujima, T. and Morita, N. (2013), Synthesis of 2‐Azulenyl‐1,1,4,4‐tetracyano‐3‐ferrocenyl‐1,3‐butadienes by [2+2] Cycloaddition of (Ferrocenylethynyl)azulenes with Tetracyanoethylene. Chem. Eur. J., 19: 5721-5730. doi:10.1002/chem.201202257, which has been published in final form at |https://doi.org/10.1002/chem.201202257 . This article may be used for non-commercial purposes in accordance with Wiley Terms and Conditions for Self-Archiving. |
出版タイプ |
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出版タイプ |
AM |
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出版タイプResource |
http://purl.org/coar/version/c_ab4af688f83e57aa |
WoS |
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URL |
http://gateway.isiknowledge.com/gateway/Gateway.cgi?&GWVersion=2&SrcAuth=ShinshuUniv&SrcApp=ShinshuUniv&DestLinkType=FullRecord&DestApp=WOS&KeyUT=000318282200029 |