Item type |
学術雑誌論文 / Journal Article(1) |
公開日 |
2018-06-13 |
タイトル |
|
|
タイトル |
Synthesis and Properties of Azulene-Substituted Donor-Acceptor Chromophores Connected by Arylamine Cores |
言語 |
|
|
言語 |
eng |
DOI |
|
|
|
関連識別子 |
https://doi.org/10.1002/ejoc.201301006 |
|
|
関連名称 |
10.1002/ejoc.201301006 |
キーワード |
|
|
主題 |
Arenes, Chromophores, Cycloaddition, Redox chemistry, Cyclic voltammetry |
資源タイプ |
|
|
資源 |
http://purl.org/coar/resource_type/c_6501 |
|
タイプ |
journal article |
著者 |
Shoji, Taku
Shimomura, Erika
Maruyama, Mitsuhisa
Maruyama, Akifumi
Ito, Shunji
Okujima, Tetsuo
Toyota, Kozo
Morita, Noboru
|
信州大学研究者総覧へのリンク |
|
|
氏名 |
Shoji, Taku |
|
URL |
http://soar-rd.shinshu-u.ac.jp/profile/ja.gmShOakh.html |
出版者 |
|
|
出版者 |
WILEY-V C H VERLAG GMBH |
引用 |
|
|
内容記述 |
EUROPEAN JOURNAL OF ORGANIC CHEMISTRY. 2013(34):7785-7799 (2013) |
書誌情報 |
EUROPEAN JOURNAL OF ORGANIC CHEMISTRY
巻 2013,
号 34,
p. 7785-7799,
発行日 2013-12
|
抄録 |
|
|
内容記述 |
1-Ethynylazulenes connected by several arylamine cores reacted with tetracyanoethylene (TCNE) and 7,7,8,8-tetracyanoquinodimethane (TCNQ) in a formal [2+2] cycloaddition-cycloreversion reaction to afford the corresponding tetracyanobutadiene (TCBD) and dicyanoquinodimethane (DCNQ) chromophores, respectively, in excellent yields. The intramolecular charge-transfer (ICT) characters between the donor (azulene and arylamine cores) and acceptor (TCBD and DCNQ units) moieties were investigated by UV/Vis spectroscopy and theoretical calculations. The redox behavior of the new TCBD and DCNQ derivatives was examined by cyclic voltammetry (CV) and differential pulse voltammetry (DPV), which revealed their multistep electrochemical reduction properties. Moreover, significant color changes were observed by visible spectroscopy under the electrochemical reduction conditions. |
資源タイプ(コンテンツの種類) |
|
|
内容記述 |
Article |
ISSN |
|
|
収録物識別子タイプ |
ISSN |
|
収録物識別子 |
1434-193X |
書誌レコードID |
|
|
収録物識別子タイプ |
NCID |
|
収録物識別子 |
AA1118165X |
権利 |
|
|
権利情報 |
This is the peer reviewed version of the following article: Shoji, T. , Shimomura, E. , Maruyama, M. , Maruyama, A. , Ito, S. , Okujima, T. , Toyota, K. and Morita, N. (2013), Synthesis and Properties of Azulene‐Substituted Donor–Acceptor Chromophores Connected by Arylamine Cores. Eur. J. Org. Chem., 2013: 7785-7799. doi:10.1002/ejoc.201301006, which has been published in final form at https://doi.org/10.1002/ejoc.201301006 . This article may be used for non-commercial purposes in accordance with Wiley Terms and Conditions for Self-Archiving. |
出版タイプ |
|
|
出版タイプ |
AM |
|
出版タイプResource |
http://purl.org/coar/version/c_ab4af688f83e57aa |
WoS |
|
|
URL |
http://gateway.isiknowledge.com/gateway/Gateway.cgi?&GWVersion=2&SrcAuth=ShinshuUniv&SrcApp=ShinshuUniv&DestLinkType=FullRecord&DestApp=WOS&KeyUT=000332831100005 |