| Item type |
学術雑誌論文 / Journal Article(1) |
| 公開日 |
2018-06-13 |
| タイトル |
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タイトル |
Synthesis, Properties, and Redox Behavior of 1,1,4,4-Tetracyano-2-ferrocenyl-1,3-butadienes Connected by Aryl, Biaryl, and Teraryl Spacers |
| 言語 |
|
|
言語 |
eng |
| DOI |
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関連識別子 |
https://doi.org/10.1002/chem.201405004 |
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関連名称 |
10.1002/chem.201405004 |
| キーワード |
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主題 |
chromophores, cycloaddition, donor-acceptor systems, ferrocene, redox chemistry |
| 資源タイプ |
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資源 |
http://purl.org/coar/resource_type/c_6501 |
|
タイプ |
journal article |
| 著者 |
Shoji, Taku
Maruyama, Akifumi
Yaku, Chisa
Kamata, Natsumi
Ito, Shunji
Okujima, Tetsuo
Toyota, Kozo
|
| 信州大学研究者総覧へのリンク |
|
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氏名 |
Shoji, Taku |
|
URL |
http://soar-rd.shinshu-u.ac.jp/profile/ja.gmShOakh.html |
| 出版者 |
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出版者 |
WILEY-V C H VERLAG GMBH |
| 引用 |
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内容記述 |
CHEMISTRY-A EUROPEAN JOURNAL. 23(21):402-409 (2015) |
| 書誌情報 |
CHEMISTRY-A EUROPEAN JOURNAL
巻 21,
号 1,
p. 402-409,
発行日 2015-01-02
|
| 抄録 |
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内容記述 |
Aryl-substituted 1,1,4,4-tetracyano-1,3-butadienes (FcTCBDs) and bis(1,1,4,4-tetracyanobutadiene)s (bisFcTCBDs), possessing a ferrocenyl group on each terminal, were prepared by the reaction of a variety of alkynes with tetracyanoethylene (TCNE) in a [2+2] cycloaddition reaction, followed by retro-electrocyclization of the initially formed [2+2] cycloadducts (i.e., cyclobutene derivatives). The characteristic intramolecular charge transfer (ICT) between the donor (ferrocene) and acceptor (TCBD) moieties were investigated by using UV/ Vis spectroscopy. The redox behaviors of FcTCBDs and bis-FcTCBDs were examined by cyclic voltammetry (CV) and differential pulse voltammetry (DPV), which revealed their properties of multi-electron transfer depending on the number of ferrocene and TCBD moieties. Moreover, significant color changes were observed by visible spectroscopy under the electrochemical reduction conditions. |
| 資源タイプ（コンテンツの種類） |
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| ISSN |
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収録物識別子タイプ |
ISSN |
|
収録物識別子 |
0947-6539 |
| 書誌レコードID |
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収録物識別子タイプ |
NCID |
|
収録物識別子 |
AA11076269 |
| PubMed |
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|
識別子タイプ |
PMID |
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関連識別子 |
http://www.ncbi.nlm.nih.gov/entrez/query.fcgi?CMD=search&DB=pubmed&term=25370830 |
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関連名称 |
25370830 |
| 権利 |
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権利情報 |
This is the peer reviewed version of the following article: Shoji, T. , Maruyama, A. , Yaku, C. , Kamata, N. , Ito, S. , Okujima, T. and Toyota, K. (2015), Synthesis, Properties, and Redox Behavior of 1,1,4,4‐Tetracyano‐2‐ferrocenyl‐1,3‐butadienes Connected by Aryl, Biaryl, and Teraryl Spacers. Chem. Eur. J., 21: 402-409. doi:10.1002/chem.201405004, which has been published in final form at https://doi.org/10.1002/chem.201405004 . This article may be used for non-commercial purposes in accordance with Wiley Terms and Conditions for Self-Archiving. |
| 出版タイプ |
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|
出版タイプ |
AM |
|
出版タイプResource |
http://purl.org/coar/version/c_ab4af688f83e57aa |
| WoS |
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|
URL |
http://gateway.isiknowledge.com/gateway/Gateway.cgi?&GWVersion=2&SrcAuth=ShinshuUniv&SrcApp=ShinshuUniv&DestLinkType=FullRecord&DestApp=WOS&KeyUT=000346735000043 |
Chem_Eur_J_21_402-409.pdf (478.3 kB)
