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Synthesis, Properties, and Redox Behavior of 1,1,4,4-Tetracyano-2-ferrocenyl-1,3-butadienes Connected by Aryl, Biaryl, and Teraryl Spacers
http://hdl.handle.net/10091/00020645
http://hdl.handle.net/10091/00020645ec57d6bf-9cd7-4ad4-86c0-ebc561ddf56e
| 名前 / ファイル | ライセンス | アクション |
|---|---|---|
Chem_Eur_J_21_402-409.pdf (478.3 kB)
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| Item type | 学術雑誌論文 / Journal Article(1) | |||||
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| 公開日 | 2018-06-13 | |||||
| タイトル | ||||||
| タイトル | Synthesis, Properties, and Redox Behavior of 1,1,4,4-Tetracyano-2-ferrocenyl-1,3-butadienes Connected by Aryl, Biaryl, and Teraryl Spacers | |||||
| 言語 | en | |||||
| 言語 | ||||||
| 言語 | eng | |||||
| DOI | ||||||
| 識別子タイプ | DOI | |||||
| 関連識別子 | https://doi.org/10.1002/chem.201405004 | |||||
| 関連名称 | 10.1002/chem.201405004 | |||||
| キーワード | ||||||
| 主題Scheme | Other | |||||
| 主題 | chromophores | |||||
| キーワード | ||||||
| 主題Scheme | Other | |||||
| 主題 | cycloaddition | |||||
| キーワード | ||||||
| 主題Scheme | Other | |||||
| 主題 | donor-acceptor systems | |||||
| キーワード | ||||||
| 主題Scheme | Other | |||||
| 主題 | ferrocene | |||||
| キーワード | ||||||
| 主題Scheme | Other | |||||
| 主題 | redox chemistry | |||||
| 資源タイプ | ||||||
| 資源タイプ識別子 | http://purl.org/coar/resource_type/c_6501 | |||||
| 資源タイプ | journal article | |||||
| 著者 |
Shoji, Taku
× Shoji, Taku× Maruyama, Akifumi× Yaku, Chisa× Kamata, Natsumi× Ito, Shunji× Okujima, Tetsuo× Toyota, Kozo |
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| 信州大学研究者総覧へのリンク | ||||||
| 表示名 | Shoji, Taku | |||||
| URL | http://soar-rd.shinshu-u.ac.jp/profile/ja.gmShOakh.html | |||||
| 出版者 | ||||||
| 出版者 | WILEY-V C H VERLAG GMBH | |||||
| 引用 | ||||||
| 内容記述タイプ | Other | |||||
| 内容記述 | CHEMISTRY-A EUROPEAN JOURNAL. 23(21):402-409 (2015) | |||||
| 書誌情報 |
CHEMISTRY-A EUROPEAN JOURNAL 巻 21, 号 1, p. 402-409, 発行日 2015-01-02 |
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| 抄録 | ||||||
| 内容記述タイプ | Abstract | |||||
| 内容記述 | Aryl-substituted 1,1,4,4-tetracyano-1,3-butadienes (FcTCBDs) and bis(1,1,4,4-tetracyanobutadiene)s (bisFcTCBDs), possessing a ferrocenyl group on each terminal, were prepared by the reaction of a variety of alkynes with tetracyanoethylene (TCNE) in a [2+2] cycloaddition reaction, followed by retro-electrocyclization of the initially formed [2+2] cycloadducts (i.e., cyclobutene derivatives). The characteristic intramolecular charge transfer (ICT) between the donor (ferrocene) and acceptor (TCBD) moieties were investigated by using UV/ Vis spectroscopy. The redox behaviors of FcTCBDs and bis-FcTCBDs were examined by cyclic voltammetry (CV) and differential pulse voltammetry (DPV), which revealed their properties of multi-electron transfer depending on the number of ferrocene and TCBD moieties. Moreover, significant color changes were observed by visible spectroscopy under the electrochemical reduction conditions. | |||||
| 資源タイプ（コンテンツの種類） | ||||||
| 内容記述タイプ | Other | |||||
| 内容記述 | Article | |||||
| ISSN | ||||||
| 収録物識別子タイプ | ISSN | |||||
| 収録物識別子 | 0947-6539 | |||||
| 書誌レコードID | ||||||
| 収録物識別子タイプ | NCID | |||||
| 収録物識別子 | AA11076269 | |||||
| PubMed | ||||||
| 識別子タイプ | PMID | |||||
| 関連識別子 | http://www.ncbi.nlm.nih.gov/entrez/query.fcgi?CMD=search&DB=pubmed&term=25370830 | |||||
| 関連名称 | 25370830 | |||||
| 権利 | ||||||
| 権利情報 | This is the peer reviewed version of the following article: Shoji, T. , Maruyama, A. , Yaku, C. , Kamata, N. , Ito, S. , Okujima, T. and Toyota, K. (2015), Synthesis, Properties, and Redox Behavior of 1,1,4,4‐Tetracyano‐2‐ferrocenyl‐1,3‐butadienes Connected by Aryl, Biaryl, and Teraryl Spacers. Chem. Eur. J., 21: 402-409. doi:10.1002/chem.201405004, which has been published in final form at https://doi.org/10.1002/chem.201405004 . This article may be used for non-commercial purposes in accordance with Wiley Terms and Conditions for Self-Archiving. | |||||
| 出版タイプ | ||||||
| 出版タイプ | AM | |||||
| 出版タイプResource | http://purl.org/coar/version/c_ab4af688f83e57aa | |||||
| WoS | ||||||
| 表示名 | Web of Science | |||||
| URL | http://gateway.isiknowledge.com/gateway/Gateway.cgi?&GWVersion=2&SrcAuth=ShinshuUniv&SrcApp=ShinshuUniv&DestLinkType=FullRecord&DestApp=WOS&KeyUT=000346735000043 | |||||
