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  1. 040 理学部
  2. 0401 学術論文

Synthesis of 2-amino- and 2-arylazoazulenes via nucleophilic aromatic substitution of 2-chloroazulenes with amines and arylhydrazines

http://hdl.handle.net/10091/00020650
http://hdl.handle.net/10091/00020650
ef3e89a8-afed-4065-bede-2b3ea7a6a831
名前 / ファイル ライセンス アクション
Org_Biomol_Chem_15_3917-3923.pdf Org_Biomol_Chem_15_3917-3923.pdf (444.9 kB)
Item type 学術雑誌論文 / Journal Article(1)
公開日 2018-06-13
タイトル
言語 en
タイトル Synthesis of 2-amino- and 2-arylazoazulenes via nucleophilic aromatic substitution of 2-chloroazulenes with amines and arylhydrazines
言語
言語 eng
資源タイプ
資源 http://purl.org/coar/resource_type/c_6501
タイプ journal article
著者 Shoji, Taku

× Shoji, Taku

WEKO 105758

Shoji, Taku

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Sugiyama, Shuhei

× Sugiyama, Shuhei

WEKO 105759

Sugiyama, Shuhei

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Araki, Takanori

× Araki, Takanori

WEKO 105760

Araki, Takanori

Search repository
Ohta, Akira

× Ohta, Akira

WEKO 105761

Ohta, Akira

Search repository
Sekiguchi, Ryuta

× Sekiguchi, Ryuta

WEKO 105762

Sekiguchi, Ryuta

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Ito, Shunji

× Ito, Shunji

WEKO 105763

Ito, Shunji

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Mori, Shigeki

× Mori, Shigeki

WEKO 105764

Mori, Shigeki

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Okujima, Tetsuo

× Okujima, Tetsuo

WEKO 105765

Okujima, Tetsuo

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Yasunami, Masafumi

× Yasunami, Masafumi

WEKO 105766

Yasunami, Masafumi

Search repository
信州大学研究者総覧へのリンク
氏名 Shoji, Taku
URL http://soar-rd.shinshu-u.ac.jp/profile/ja.gmShOakh.html
信州大学研究者総覧へのリンク
氏名 Ohta, Akira
URL http://soar-rd.shinshu-u.ac.jp/profile/ja.uaTeOUkh.html
出版者
出版者 ROYAL SOC CHEMISTRY
引用
内容記述タイプ Other
内容記述 ORGANIC & BIOMOLECULAR CHEMISTRY. 94(10):3917-3923 (2017)
書誌情報 ORGANIC & BIOMOLECULAR CHEMISTRY

巻 15, 号 18, p. 3917-3923, 発行日 2017-05-14
抄録
内容記述タイプ Abstract
内容記述 The SNAr reaction of 2-chloroazulene derivative 1 with ethoxycarbonyl groups at the 1,3-positions of the azulene ring with several amines afforded the corresponding 2-aminoazulenes 3-9 in excellent yields. 2-Chloroazulene (2) without the electron-withdrawing groups reacted with highly nucleophilic cyclic amines (i.e., morpholine, piperidine and pyrrolidine) under the high-temperature conditions in a sealed tube to produce the corresponding 2-aminoazulenes 10-12 in good yields. 2-Aminoazulenes 10-14 without the electron-withdrawing groups were also obtained in good yields by the treatment of compounds 3-7 with 100% H3PO4, but in the cases of the reaction of 8 and 9 with a secondary amine function, the decomposition of the products resulted. The synthesis of 2-arylazoazulenes 15-18 was also established via the SNAr reaction of 1 with arylhydrazines. The optical and electrochemical properties of the 2-arylazoazulene derivatives were examined by UV/Vis spectroscopy, theoretical calculations and voltammetric experiments.
資源タイプ(コンテンツの種類)
内容記述タイプ Other
内容記述 Article
ISSN
収録物識別子タイプ ISSN
収録物識別子 1477-0520
書誌レコードID
収録物識別子タイプ NCID
収録物識別子 AA1168650X
PubMed
識別子タイプ PMID
関連識別子 http://www.ncbi.nlm.nih.gov/entrez/query.fcgi?CMD=search&DB=pubmed&term=28426084
関連名称 28426084
DOI
識別子タイプ DOI
関連識別子 https://doi.org/10.1039/c7ob00691h
関連名称 10.1039/c7ob00691h
権利
権利情報 © 2017 Royal Society of Chemistry
出版タイプ
出版タイプ AM
出版タイプResource http://purl.org/coar/version/c_ab4af688f83e57aa
WoS
表示名 Web of Science
URL http://gateway.isiknowledge.com/gateway/Gateway.cgi?&GWVersion=2&SrcAuth=ShinshuUniv&SrcApp=ShinshuUniv&DestLinkType=FullRecord&DestApp=WOS&KeyUT=000401147200015
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