Item type |
学術雑誌論文 / Journal Article(1) |
公開日 |
2018-06-13 |
タイトル |
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タイトル |
Synthesis of 2-Aminofurans by Sequential [2+2] Cycloaddition-Nucleophilic Addition of 2-Propyn-1-ols with Tetracyanoethylene and Amine-Induced Transformation into 6-Aminopentafulvenes |
言語 |
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言語 |
eng |
DOI |
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関連識別子 |
https://doi.org/10.1002/chem.201700121 |
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関連名称 |
10.1002/chem.201700121 |
キーワード |
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主題 |
azulene, cycloaddition, nucleophilic addition, oxygen heterocycles, synthetic methods |
資源タイプ |
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資源 |
http://purl.org/coar/resource_type/c_6501 |
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タイプ |
journal article |
著者 |
Shoji, Taku
Nagai, Daichi
Tanaka, Miwa
Araki, Takanori
Ohta, Akira
Sekiguchi, Ryuta
Ito, Shunji
Mori, Shigeki
Okujima, Tetsuo
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信州大学研究者総覧へのリンク |
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氏名 |
Shoji, Taku |
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URL |
http://soar-rd.shinshu-u.ac.jp/profile/ja.gmShOakh.html |
信州大学研究者総覧へのリンク |
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氏名 |
Ohta, Akira |
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URL |
http://soar-rd.shinshu-u.ac.jp/profile/ja.uaTeOUkh.html |
出版者 |
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出版者 |
WILEY-V C H VERLAG GMBH |
引用 |
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内容記述 |
CHEMISTRY-A EUROPEAN JOURNAL. 23(21):5126-5136 (2017) |
書誌情報 |
CHEMISTRY-A EUROPEAN JOURNAL
巻 23,
号 21,
p. 5126-5136,
発行日 2017-04-11
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抄録 |
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内容記述 |
Synthesis of 2-aminofuran derivatives with an azulene or N,N-dimethylanilino substituent was established by the formal [2+2] cycloaddition-retroelectrocyclization of 3-(1-azulenyl or N,N-dimethylanilino)-2-propyn-1-ols with tetracyanoethylene, followed by intramolecular nucleophilic addition to the initially formed tetracyanobutadiene moiety of the internal hydroxyl group that come from 2-propyn-1-ol. The reaction proceeds under mild conditions with short reaction period. The products of the reaction are readily available through a simple purification procedure. 2-Aminofuran derivatives obtained by this reaction could be converted into 6-aminofulvene derivatives upon reaction with various amines. The structures of 2-aminofuran and 6-aminopentafulvene with a N,N-dimethylanilino substituent were confirmed by single-crystal X-ray structural analysis. |
資源タイプ(コンテンツの種類) |
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内容記述 |
Article |
ISSN |
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収録物識別子タイプ |
ISSN |
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収録物識別子 |
0947-6539 |
書誌レコードID |
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収録物識別子タイプ |
NCID |
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収録物識別子 |
AA11076269 |
PubMed |
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関連識別子 |
http://www.ncbi.nlm.nih.gov/entrez/query.fcgi?CMD=search&DB=pubmed&term=28191692 |
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関連名称 |
28191692 |
権利 |
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権利情報 |
This is the peer reviewed version of the following article: T. Shoji, D. Nagai, M. Tanaka, T. Araki, A. Ohta, R. Sekiguchi, S. Ito, S. Mori, T. Okujima, Chem. Eur. J. 2017, 23, 5126., which has been published in final form at https://doi.org/10.1002/chem.201700121 . This article may be used for non-commercial purposes in accordance with Wiley Terms and Conditions for Self-Archiving. |
出版タイプ |
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出版タイプ |
AM |
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出版タイプResource |
http://purl.org/coar/version/c_ab4af688f83e57aa |
WoS |
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URL |
http://gateway.isiknowledge.com/gateway/Gateway.cgi?&GWVersion=2&SrcAuth=ShinshuUniv&SrcApp=ShinshuUniv&DestLinkType=FullRecord&DestApp=WOS&KeyUT=000399327400023 |