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  1. 040 理学部
  2. 0401 学術論文

Synthesis of 2-Aminofurans by Sequential [2+2] Cycloaddition-Nucleophilic Addition of 2-Propyn-1-ols with Tetracyanoethylene and Amine-Induced Transformation into 6-Aminopentafulvenes

http://hdl.handle.net/10091/00020652
http://hdl.handle.net/10091/00020652
41887bce-3a2e-45e5-99a9-40cfe82a1b13
名前 / ファイル ライセンス アクション
Chem_Eur_J_2017_23_5126.pdf Chem_Eur_J_2017_23_5126.pdf (931.8 kB)
Item type 学術雑誌論文 / Journal Article(1)
公開日 2018-06-13
タイトル
言語 en
タイトル Synthesis of 2-Aminofurans by Sequential [2+2] Cycloaddition-Nucleophilic Addition of 2-Propyn-1-ols with Tetracyanoethylene and Amine-Induced Transformation into 6-Aminopentafulvenes
言語
言語 eng
キーワード
主題Scheme Other
主題 azulene
キーワード
主題Scheme Other
主題 cycloaddition
キーワード
主題Scheme Other
主題 nucleophilic addition
キーワード
主題Scheme Other
主題 oxygen heterocycles
キーワード
主題Scheme Other
主題 synthetic methods
資源タイプ
資源 http://purl.org/coar/resource_type/c_6501
タイプ journal article
著者 Shoji, Taku

× Shoji, Taku

WEKO 105769

Shoji, Taku

Search repository
Nagai, Daichi

× Nagai, Daichi

WEKO 105770

Nagai, Daichi

Search repository
Tanaka, Miwa

× Tanaka, Miwa

WEKO 105771

Tanaka, Miwa

Search repository
Araki, Takanori

× Araki, Takanori

WEKO 105772

Araki, Takanori

Search repository
Ohta, Akira

× Ohta, Akira

WEKO 105773

Ohta, Akira

Search repository
Sekiguchi, Ryuta

× Sekiguchi, Ryuta

WEKO 105774

Sekiguchi, Ryuta

Search repository
Ito, Shunji

× Ito, Shunji

WEKO 105775

Ito, Shunji

Search repository
Mori, Shigeki

× Mori, Shigeki

WEKO 105776

Mori, Shigeki

Search repository
Okujima, Tetsuo

× Okujima, Tetsuo

WEKO 105777

Okujima, Tetsuo

Search repository
信州大学研究者総覧へのリンク
氏名 Shoji, Taku
URL http://soar-rd.shinshu-u.ac.jp/profile/ja.gmShOakh.html
信州大学研究者総覧へのリンク
氏名 Ohta, Akira
URL http://soar-rd.shinshu-u.ac.jp/profile/ja.uaTeOUkh.html
出版者
出版者 WILEY-V C H VERLAG GMBH
引用
内容記述タイプ Other
内容記述 CHEMISTRY-A EUROPEAN JOURNAL. 23(21):5126-5136 (2017)
書誌情報 CHEMISTRY-A EUROPEAN JOURNAL

巻 23, 号 21, p. 5126-5136, 発行日 2017-04-11
抄録
内容記述タイプ Abstract
内容記述 Synthesis of 2-aminofuran derivatives with an azulene or N,N-dimethylanilino substituent was established by the formal [2+2] cycloaddition-retroelectrocyclization of 3-(1-azulenyl or N,N-dimethylanilino)-2-propyn-1-ols with tetracyanoethylene, followed by intramolecular nucleophilic addition to the initially formed tetracyanobutadiene moiety of the internal hydroxyl group that come from 2-propyn-1-ol. The reaction proceeds under mild conditions with short reaction period. The products of the reaction are readily available through a simple purification procedure. 2-Aminofuran derivatives obtained by this reaction could be converted into 6-aminofulvene derivatives upon reaction with various amines. The structures of 2-aminofuran and 6-aminopentafulvene with a N,N-dimethylanilino substituent were confirmed by single-crystal X-ray structural analysis.
資源タイプ(コンテンツの種類)
内容記述タイプ Other
内容記述 Article
ISSN
収録物識別子タイプ ISSN
収録物識別子 0947-6539
書誌レコードID
収録物識別子タイプ NCID
収録物識別子 AA11076269
PubMed
識別子タイプ PMID
関連識別子 http://www.ncbi.nlm.nih.gov/entrez/query.fcgi?CMD=search&DB=pubmed&term=28191692
関連名称 28191692
DOI
識別子タイプ DOI
関連識別子 https://doi.org/10.1002/chem.201700121
関連名称 10.1002/chem.201700121
権利
権利情報 This is the peer reviewed version of the following article: T. Shoji, D. Nagai, M. Tanaka, T. Araki, A. Ohta, R. Sekiguchi, S. Ito, S. Mori, T. Okujima, Chem. Eur. J. 2017, 23, 5126., which has been published in final form at https://doi.org/10.1002/chem.201700121 . This article may be used for non-commercial purposes in accordance with Wiley Terms and Conditions for Self-Archiving.
出版タイプ
出版タイプ AM
出版タイプResource http://purl.org/coar/version/c_ab4af688f83e57aa
WoS
表示名 Web of Science
URL http://gateway.isiknowledge.com/gateway/Gateway.cgi?&GWVersion=2&SrcAuth=ShinshuUniv&SrcApp=ShinshuUniv&DestLinkType=FullRecord&DestApp=WOS&KeyUT=000399327400023
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