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Li-insertion/extraction properties of three-dimensional Sn electrode prepared by facile electrodeposition method
http://hdl.handle.net/10091/00021825
http://hdl.handle.net/10091/000218251ba9c352-7055-4242-bb56-ceed77235408
名前 / ファイル | ライセンス | アクション |
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Item type | 学術雑誌論文 / Journal Article(1) | |||||
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公開日 | 2020-01-30 | |||||
タイトル | ||||||
言語 | en | |||||
タイトル | Li-insertion/extraction properties of three-dimensional Sn electrode prepared by facile electrodeposition method | |||||
言語 | ||||||
言語 | eng | |||||
キーワード | ||||||
主題Scheme | Other | |||||
主題 | Electrodeposition | |||||
キーワード | ||||||
主題Scheme | Other | |||||
主題 | Sn electrode | |||||
キーワード | ||||||
主題Scheme | Other | |||||
主題 | Li-ion battery | |||||
キーワード | ||||||
主題Scheme | Other | |||||
主題 | Three-dimensional structure | |||||
キーワード | ||||||
主題Scheme | Other | |||||
主題 | Current collector | |||||
資源タイプ | ||||||
資源 | http://purl.org/coar/resource_type/c_6501 | |||||
タイプ | journal article | |||||
著者 |
Shimizu, Masahiro
× Shimizu, Masahiro× Munkhbat, Mendsaikhan× Arai, Susumu |
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信州大学研究者総覧へのリンク | ||||||
氏名 | Shimizu, Masahiro | |||||
URL | http://soar-rd.shinshu-u.ac.jp/profile/ja.gCkVbUkh.html | |||||
信州大学研究者総覧へのリンク | ||||||
氏名 | Arai, Susumu | |||||
URL | http://soar-rd.shinshu-u.ac.jp/profile/ja.jUyhbpkh.html | |||||
出版者 | ||||||
出版者 | SPRINGER | |||||
引用 | ||||||
内容記述タイプ | Other | |||||
内容記述 | JOURNAL OF APPLIED ELECTROCHEMISTRY.47(6):727-734(2017) | |||||
書誌情報 |
JOURNAL OF APPLIED ELECTROCHEMISTRY 巻 47, 号 6, p. 727-734, 発行日 2017-04-18 |
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抄録 | ||||||
内容記述タイプ | Abstract | |||||
内容記述 | Toward the realization of reliable Li-ion batteries with high performance and safety, component materials such as those of the current collector and negative electrode require further innovation. Sn, one of the most promising negative-electrode materials, can be electrochemically fixed on a substrate without any binder or conductive additive. However, the pulverization of Sn-plated films on substrates caused by large volume changes during Li-Sn reactions is the main reason hindering the practical application of Sn-plated electrodes. In the present study, we developed an electrodeposited three-dimensional (3D) Cu substrate applied to underlayer of the electrode. The effect of substrate geometry on the charge-discharge performance of the Sn electrode was investigated. The 3D-Cu/Sn electrode exhibited superior cycling performance with a reversible capacity of 470 mA h g(-1) even at the 300th cycle, whereas the Sn-plated electrode prepared on a typical flat Cu substrate showed a capacity of only 20 mA h g(-1). The results demonstrated that the 3D structure played a key role in accommodating volumetric changes in the Sn to suppress electrode disintegration. The developed 3D-Cu substrate will be significantly useful as a current collector for alloy-based active materials. [GRAPHICS] . | |||||
資源タイプ(コンテンツの種類) | ||||||
内容記述タイプ | Other | |||||
内容記述 | Article | |||||
ISSN | ||||||
収録物識別子タイプ | ISSN | |||||
収録物識別子 | 0021-891X | |||||
書誌レコードID | ||||||
収録物識別子タイプ | NCID | |||||
収録物識別子 | AA11981601 | |||||
DOI | ||||||
識別子タイプ | DOI | |||||
関連識別子 | https://doi.org/10.1007/s10800-017-1075-0 | |||||
関連名称 | 10.1007/s10800-017-1075-0 | |||||
権利 | ||||||
権利情報 | This is a post-peer-review, pre-copyedit version of an article published in JOURNAL OF APPLIED ELECTROCHEMISTRY. The final authenticated version is available online at: https://doi.org/10.1007/s10800-017-1075-0 | |||||
出版タイプ | ||||||
出版タイプ | AM | |||||
出版タイプResource | http://purl.org/coar/version/c_ab4af688f83e57aa | |||||
WoS | ||||||
表示名 | Web of Science | |||||
URL | http://gateway.isiknowledge.com/gateway/Gateway.cgi?&GWVersion=2&SrcAuth=ShinshuUniv&SrcApp=ShinshuUniv&DestLinkType=FullRecord&DestApp=WOS&KeyUT=000400890300006 |