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  1. 060 工学部
  2. 0601 学術論文

Li-insertion/extraction properties of three-dimensional Sn electrode prepared by facile electrodeposition method

http://hdl.handle.net/10091/00021825
http://hdl.handle.net/10091/00021825
1ba9c352-7055-4242-bb56-ceed77235408
名前 / ファイル ライセンス アクション
16H06838_06.pdf 16H06838_06.pdf (2.1 MB)
16H06838_06_SupplementaryData.pdf 16H06838_06_SupplementaryData.pdf (764.9 kB)
Item type 学術雑誌論文 / Journal Article(1)
公開日 2020-01-30
タイトル
言語 en
タイトル Li-insertion/extraction properties of three-dimensional Sn electrode prepared by facile electrodeposition method
言語
言語 eng
キーワード
主題Scheme Other
主題 Electrodeposition
キーワード
主題Scheme Other
主題 Sn electrode
キーワード
主題Scheme Other
主題 Li-ion battery
キーワード
主題Scheme Other
主題 Three-dimensional structure
キーワード
主題Scheme Other
主題 Current collector
資源タイプ
資源 http://purl.org/coar/resource_type/c_6501
タイプ journal article
著者 Shimizu, Masahiro

× Shimizu, Masahiro

WEKO 108863

Shimizu, Masahiro

Search repository
Munkhbat, Mendsaikhan

× Munkhbat, Mendsaikhan

WEKO 108864

Munkhbat, Mendsaikhan

Search repository
Arai, Susumu

× Arai, Susumu

WEKO 108865

Arai, Susumu

Search repository
信州大学研究者総覧へのリンク
氏名 Shimizu, Masahiro
URL http://soar-rd.shinshu-u.ac.jp/profile/ja.gCkVbUkh.html
信州大学研究者総覧へのリンク
氏名 Arai, Susumu
URL http://soar-rd.shinshu-u.ac.jp/profile/ja.jUyhbpkh.html
出版者
出版者 SPRINGER
引用
内容記述タイプ Other
内容記述 JOURNAL OF APPLIED ELECTROCHEMISTRY.47(6):727-734(2017)
書誌情報 JOURNAL OF APPLIED ELECTROCHEMISTRY

巻 47, 号 6, p. 727-734, 発行日 2017-04-18
抄録
内容記述タイプ Abstract
内容記述 Toward the realization of reliable Li-ion batteries with high performance and safety, component materials such as those of the current collector and negative electrode require further innovation. Sn, one of the most promising negative-electrode materials, can be electrochemically fixed on a substrate without any binder or conductive additive. However, the pulverization of Sn-plated films on substrates caused by large volume changes during Li-Sn reactions is the main reason hindering the practical application of Sn-plated electrodes. In the present study, we developed an electrodeposited three-dimensional (3D) Cu substrate applied to underlayer of the electrode. The effect of substrate geometry on the charge-discharge performance of the Sn electrode was investigated. The 3D-Cu/Sn electrode exhibited superior cycling performance with a reversible capacity of 470 mA h g(-1) even at the 300th cycle, whereas the Sn-plated electrode prepared on a typical flat Cu substrate showed a capacity of only 20 mA h g(-1). The results demonstrated that the 3D structure played a key role in accommodating volumetric changes in the Sn to suppress electrode disintegration. The developed 3D-Cu substrate will be significantly useful as a current collector for alloy-based active materials. [GRAPHICS] .
資源タイプ(コンテンツの種類)
内容記述タイプ Other
内容記述 Article
ISSN
収録物識別子タイプ ISSN
収録物識別子 0021-891X
書誌レコードID
収録物識別子タイプ NCID
収録物識別子 AA11981601
DOI
識別子タイプ DOI
関連識別子 https://doi.org/10.1007/s10800-017-1075-0
関連名称 10.1007/s10800-017-1075-0
権利
権利情報 This is a post-peer-review, pre-copyedit version of an article published in JOURNAL OF APPLIED ELECTROCHEMISTRY. The final authenticated version is available online at: https://doi.org/10.1007/s10800-017-1075-0
出版タイプ
出版タイプ AM
出版タイプResource http://purl.org/coar/version/c_ab4af688f83e57aa
WoS
表示名 Web of Science
URL http://gateway.isiknowledge.com/gateway/Gateway.cgi?&GWVersion=2&SrcAuth=ShinshuUniv&SrcApp=ShinshuUniv&DestLinkType=FullRecord&DestApp=WOS&KeyUT=000400890300006
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