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Detection of Amine Vapors using Luminescent Xerogels from Supramolecular Metal-Containing
http://hdl.handle.net/10091/00021971
http://hdl.handle.net/10091/00021971ea26d927-d96c-49bc-a3b7-767d9dd1b74e
| 名前 / ファイル | ライセンス | アクション |
|---|---|---|
15K05623_03.pdf (1.5 MB)
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| Item type | 学術雑誌論文 / Journal Article(1) | |||||
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| 公開日 | 2020-03-12 | |||||
| タイトル | ||||||
| タイトル | Detection of Amine Vapors using Luminescent Xerogels from Supramolecular Metal-Containing | |||||
| 言語 | en | |||||
| 言語 | ||||||
| 言語 | eng | |||||
| DOI | ||||||
| 識別子タイプ | DOI | |||||
| 関連識別子 | https://doi.org/10.1246/bcsj.20170409 | |||||
| 関連名称 | 10.1246/bcsj.20170409 | |||||
| 資源タイプ | ||||||
| 資源タイプ識別子 | http://purl.org/coar/resource_type/c_6501 | |||||
| 資源タイプ | journal article | |||||
| 著者 |
Sasaki, Junpei
× Sasaki, Junpei× Suzuki, Masahiro× Hanabusa, Kenji |
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| 信州大学研究者総覧へのリンク | ||||||
| 表示名 | Suzuki, Masahiro | |||||
| URL | http://soar-rd.shinshu-u.ac.jp/profile/ja.WVnmjFkV.html | |||||
| 信州大学研究者総覧へのリンク | ||||||
| 表示名 | Hanabusa, Kenji | |||||
| URL | http://soar-rd.shinshu-u.ac.jp/profile/ja.WCyNjekV.html | |||||
| 出版者 | ||||||
| 出版者 | CHEMICAL SOC JAPAN | |||||
| 引用 | ||||||
| 内容記述タイプ | Other | |||||
| 内容記述 | BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN.91(4):538-547(2018) | |||||
| 書誌情報 |
BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN 巻 91, 号 4, p. 538-547, 発行日 2018-04 |
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| 抄録 | ||||||
| 内容記述タイプ | Abstract | |||||
| 内容記述 | Supramolecular fluorescent gelators containing a tris(beta-diketonato) complex are synthesized by using gelation-driving chelates, and their gelation abilities are studied with 15 solvents. Thin-layer films are prepared on quartz plates from the solutions and they are studied as chemosensors for amines. Fluorescence-quenching of the thin-layer films upon exposure to saturated primary and secondary amine vapors is monitored to evaluate the abilities of the chemosensors to detect amines. The morphologies of the thin-layer films are observed by transmission electron microscopy (TEM) and discussed in relation to their fluorescence-quenching. The fluorescence-quenching efficiencies upon exposure to saturated primary and secondary amines depend on the basicity and bulkiness of the amines rather than the vapor pressure. The fluorescence-quenching is caused by decomposition of a complex through nucleophilic addition of primary or secondary amines to its carbonyl group. The detection of tertiary amines is performed by monitoring the fluorescence emission from the thin-layer films, which are composed of a ligand and EuCl3. The emergence of fluorescence originates from the formation of fluorescent Eu3+-containing gelator, in which dehydrochloric acid by tertiary amines is a trigger for the complexation. | |||||
| 資源タイプ（コンテンツの種類） | ||||||
| 内容記述タイプ | Other | |||||
| 内容記述 | Article | |||||
| ISSN | ||||||
| 収録物識別子タイプ | ISSN | |||||
| 収録物識別子 | 0009-2673 | |||||
| 書誌レコードID | ||||||
| 収録物識別子タイプ | NCID | |||||
| 収録物識別子 | AA00580132 | |||||
| 権利 | ||||||
| 権利情報 | © 2018 The Chemical Society of Japan. | |||||
| 出版タイプ | ||||||
| 出版タイプ | AM | |||||
| 出版タイプResource | http://purl.org/coar/version/c_ab4af688f83e57aa | |||||
| WoS | ||||||
| 表示名 | Web of Science | |||||
| URL | http://gateway.isiknowledge.com/gateway/Gateway.cgi?&GWVersion=2&SrcAuth=ShinshuUniv&SrcApp=ShinshuUniv&DestLinkType=FullRecord&DestApp=WOS&KeyUT=000430096000005 | |||||
