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Diastereoselective imino-pinacol coupling of chiral imines promoted by Mg(0) and a Grignard reagent
http://hdl.handle.net/10091/00018631
http://hdl.handle.net/10091/000186317d20ff46-97d8-453a-a2b1-ed98f6ab686a
名前 / ファイル | ライセンス | アクション |
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Item type | 学術雑誌論文 / Journal Article(1) | |||||||||||
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公開日 | 2016-02-04 | |||||||||||
タイトル | ||||||||||||
タイトル | Diastereoselective imino-pinacol coupling of chiral imines promoted by Mg(0) and a Grignard reagent | |||||||||||
言語 | ||||||||||||
言語 | eng | |||||||||||
DOI | ||||||||||||
関連識別子 | https://doi.org/10.1016/j.tet.2014.12.034 | |||||||||||
関連名称 | 10.1016/j.tet.2014.12.034 | |||||||||||
キーワード | ||||||||||||
主題 | Imino-pinacol coupling, Chiral 1,2-diamine, Grignard reagent, Magnesium | |||||||||||
資源タイプ | ||||||||||||
資源 | http://purl.org/coar/resource_type/c_6501 | |||||||||||
タイプ | journal article | |||||||||||
著者 |
Kitajima, Kai
× Kitajima, Kai
× Nagatomo, Ryota
× Fujimoto, Tetsuya
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信州大学研究者総覧へのリンク | ||||||||||||
氏名 | Fujimoto, Tetsuya | |||||||||||
URL | http://soar-rd.shinshu-u.ac.jp/profile/ja.jVAmjekV.html | |||||||||||
出版者 | ||||||||||||
出版者 | PERGAMON-ELSEVIER SCIENCE LTD | |||||||||||
引用 | ||||||||||||
内容記述 | TETRAHEDRON. 71(6):977-981 (2015) | |||||||||||
書誌情報 |
TETRAHEDRON 巻 71, 号 6, p. 977-981, 発行日 2015-02-11 |
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抄録 | ||||||||||||
内容記述 | The reaction of chiral imines, derived from aromatic aldehydes and (S)-valinol, with a Grignard reagent in the presence of Mg(0) afforded imino-pinacol coupling products instead of alkylated amines, with a high level of diastereoselectivity. The chiral auxiliary in the product was successfully removed via dehydration followed by hydrolysis, and the corresponding (R,R)-ethylenediamine derivative was obtained as the N-Boc protected form. (C) 2014 Elsevier Ltd. All rights reserved. | |||||||||||
資源タイプ(コンテンツの種類) | ||||||||||||
ISSN | ||||||||||||
収録物識別子タイプ | ISSN | |||||||||||
収録物識別子 | 0040-4020 | |||||||||||
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収録物識別子タイプ | NCID | |||||||||||
収録物識別子 | AA00861787 | |||||||||||
権利 | ||||||||||||
権利情報 | © 2015. This manuscript version is made available under the CC-BY-NC-ND 4.0 license http://creativecommons.org/licenses/by-nc-nd/4.0/ | |||||||||||
出版タイプ | ||||||||||||
出版タイプ | AM | |||||||||||
出版タイプResource | http://purl.org/coar/version/c_ab4af688f83e57aa | |||||||||||
WoS | ||||||||||||
URL | http://gateway.isiknowledge.com/gateway/Gateway.cgi?&GWVersion=2&SrcAuth=ShinshuUniv&SrcApp=ShinshuUniv&DestLinkType=FullRecord&DestApp=WOS&KeyUT=000348950300009 |
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Cite as
Kitajima, Kai, Nagatomo, Ryota, Fujimoto, Tetsuya, 2015, Diastereoselective imino-pinacol coupling of chiral imines promoted by Mg(0) and a Grignard reagent: PERGAMON-ELSEVIER SCIENCE LTD, 977–981 p.
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