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Diastereoselective imino-pinacol coupling of chiral imines promoted by Mg(0) and a Grignard reagent
http://hdl.handle.net/10091/00018631
http://hdl.handle.net/10091/000186317d20ff46-97d8-453a-a2b1-ed98f6ab686a
名前 / ファイル | ライセンス | アクション |
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Item type | 学術雑誌論文 / Journal Article(1) | |||||
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公開日 | 2016-02-04 | |||||
タイトル | ||||||
言語 | en | |||||
タイトル | Diastereoselective imino-pinacol coupling of chiral imines promoted by Mg(0) and a Grignard reagent | |||||
言語 | ||||||
言語 | eng | |||||
キーワード | ||||||
主題Scheme | Other | |||||
主題 | Imino-pinacol coupling | |||||
キーワード | ||||||
主題Scheme | Other | |||||
主題 | Chiral 1,2-diamine | |||||
キーワード | ||||||
主題Scheme | Other | |||||
主題 | Grignard reagent | |||||
キーワード | ||||||
主題Scheme | Other | |||||
主題 | Magnesium | |||||
資源タイプ | ||||||
資源 | http://purl.org/coar/resource_type/c_6501 | |||||
タイプ | journal article | |||||
著者 |
Kitajima, Kai
× Kitajima, Kai× Nagatomo, Ryota× Fujimoto, Tetsuya |
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信州大学研究者総覧へのリンク | ||||||
氏名 | Fujimoto, Tetsuya | |||||
URL | http://soar-rd.shinshu-u.ac.jp/profile/ja.jVAmjekV.html | |||||
出版者 | ||||||
出版者 | PERGAMON-ELSEVIER SCIENCE LTD | |||||
引用 | ||||||
内容記述タイプ | Other | |||||
内容記述 | TETRAHEDRON. 71(6):977-981 (2015) | |||||
書誌情報 |
TETRAHEDRON 巻 71, 号 6, p. 977-981, 発行日 2015-02-11 |
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抄録 | ||||||
内容記述タイプ | Abstract | |||||
内容記述 | The reaction of chiral imines, derived from aromatic aldehydes and (S)-valinol, with a Grignard reagent in the presence of Mg(0) afforded imino-pinacol coupling products instead of alkylated amines, with a high level of diastereoselectivity. The chiral auxiliary in the product was successfully removed via dehydration followed by hydrolysis, and the corresponding (R,R)-ethylenediamine derivative was obtained as the N-Boc protected form. (C) 2014 Elsevier Ltd. All rights reserved. | |||||
資源タイプ(コンテンツの種類) | ||||||
内容記述タイプ | Other | |||||
内容記述 | Article | |||||
ISSN | ||||||
収録物識別子タイプ | ISSN | |||||
収録物識別子 | 0040-4020 | |||||
書誌レコードID | ||||||
収録物識別子タイプ | NCID | |||||
収録物識別子 | AA00861787 | |||||
DOI | ||||||
識別子タイプ | DOI | |||||
関連識別子 | https://doi.org/10.1016/j.tet.2014.12.034 | |||||
関連名称 | 10.1016/j.tet.2014.12.034 | |||||
権利 | ||||||
権利情報 | © 2015. This manuscript version is made available under the CC-BY-NC-ND 4.0 license http://creativecommons.org/licenses/by-nc-nd/4.0/ | |||||
出版タイプ | ||||||
出版タイプ | AM | |||||
出版タイプResource | http://purl.org/coar/version/c_ab4af688f83e57aa | |||||
WoS | ||||||
表示名 | Web of Science | |||||
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