Item type |
学術雑誌論文 / Journal Article(1) |
公開日 |
2017-09-26 |
タイトル |
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タイトル |
Biaxial nematic phase of crank-like bis(beta-diketonato) copper(II) complexes established by X-ray diffraction and Z-value calculations |
言語 |
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言語 |
eng |
DOI |
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関連識別子 |
https://doi.org/10.1080/15421406.2017.1301922 |
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関連名称 |
10.1080/15421406.2017.1301922 |
キーワード |
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主題 |
Biaxial nematic phase, Bis(beta-diketonato)copper(II)complexes, Metallomesogen, Short title: Biaxial LC of 8-diketonato Cu complexes, X-ray diffraction, Z-value calculations |
資源タイプ |
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資源 |
http://purl.org/coar/resource_type/c_6501 |
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タイプ |
journal article |
著者 |
Kanai, Yoriko
Akimoto, Hajime
Ohta, Kazuchika
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信州大学研究者総覧へのリンク |
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氏名 |
Ohta, Kazuchika |
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URL |
http://soar-rd.shinshu-u.ac.jp/profile/ja.yVLFjekV.html |
出版者 |
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出版者 |
TAYLOR & FRANCIS LTD |
引用 |
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内容記述 |
MOLECULAR CRYSTALS AND LIQUID CRYSTALS. 648(1):130-147 (2017) |
書誌情報 |
MOLECULAR CRYSTALS AND LIQUID CRYSTALS
巻 648,
号 1,
p. 130-147,
発行日 2017
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内容記述 |
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内容記述 |
Published online: 28 Jun 2017 |
抄録 |
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内容記述 |
We have synthesized a series of six novel bis(beta-diketonate)copper (II) complexes, 1a, 1b, 2a, 2b, 3a, and 3b, substituted by two bulky substituents in the short molecular axis direction to investigate their mesomorphism. The m, p, m'-trimethoxylphenyl-substituted derivatives, 2a and 2b, and the m, p-dimethoxylphenyl-substituted derivatives, 3a and 3b, did not show mesomorphism, whereas each of the p-methoxyphenyl-substituted derivatives 1a and 1b only showed a nematic phase, which was revealed from polarizing microscopic observations. We established from X-ray diffraction and Z-value calculations that each of the crank-like derivatives 1a and 1b forms a rectangular parallelepiped dimer and shows a biaxial nematic phase. |
資源タイプ(コンテンツの種類) |
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内容記述 |
Article |
ISSN |
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収録物識別子タイプ |
ISSN |
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収録物識別子 |
1542-1406 |
書誌レコードID |
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収録物識別子タイプ |
NCID |
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収録物識別子 |
AA11836169 |
権利 |
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権利情報 |
This is an Accepted Manuscript of an article published by Taylor & Francis in Molecular Crystals and Liquid Crystals on 2017, available online: http://www.tandfonline.com/10.1080/15421406.2017.1301922 . |
出版タイプ |
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出版タイプ |
AM |
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出版タイプResource |
http://purl.org/coar/version/c_ab4af688f83e57aa |
WoS |
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URL |
http://gateway.isiknowledge.com/gateway/Gateway.cgi?&GWVersion=2&SrcAuth=ShinshuUniv&SrcApp=ShinshuUniv&DestLinkType=FullRecord&DestApp=WOS&KeyUT=000404578800011 |