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  1. 080 繊維学部
  2. 0801 学術論文

メタクリル酸メチルの精密アニオン重合 -分子量,立体規則性,末端構造の三元同時制御-

http://hdl.handle.net/10091/00020195
02c4baca-e3b5-461a-a49e-3be982c24064
名前 / ファイル ライセンス アクション
26620105_05.pdf 26620105_05.pdf (804.4 kB)
Item type 学術雑誌論文 / Journal Article(1)
公開日 2018-01-22
タイトル
言語 ja
タイトル メタクリル酸メチルの精密アニオン重合 -分子量,立体規則性,末端構造の三元同時制御-
言語
言語 jpn
キーワード
主題Scheme Other
主題 Living Anionic Ploymerization
キーワード
主題Scheme Other
主題 Stereoregularity
キーワード
主題Scheme Other
主題 End-functionalization
キーワード
主題Scheme Other
主題 Stereospecific Polymerization
キーワード
主題Scheme Other
主題 Tacticity
キーワード
主題Scheme Other
主題 Click Chemistry
資源タイプ
資源 http://purl.org/coar/resource_type/c_6501
タイプ journal article
その他(別言語等)のタイトル
その他のタイトル Precise Anionic Polymerization of Methyl Methacrylate: Simultaneous Control of Molecular Weight, Stereoregularity, and End-Structure
著者 髙坂, 泰弘

× 髙坂, 泰弘

WEKO 104926

髙坂, 泰弘

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北山, 辰樹

× 北山, 辰樹

WEKO 104927

北山, 辰樹

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信州大学研究者総覧へのリンク
氏名 髙坂, 泰弘
URL http://soar-rd.shinshu-u.ac.jp/profile/ja.WNTUPVca.html
出版者
出版者 日本ゴム協会誌
引用
内容記述タイプ Other
内容記述 日本ゴム協会誌.88(3):80-85(2015)
書誌情報 日本ゴム協会誌

巻 88, 号 3, p. 80-85, 発行日 2015
抄録
内容記述タイプ Abstract
内容記述 Stereospecific living anionic polymerizations of methyl methacrylate are described with the focus on precise control of polymer structures such as molecular weight and its dispersity, tacticity and end-groups. In particular, recently developed efficient termination reaction with α-(chloromethyl) acrylates is discussed, which affords stereoregular poly(methyl methacrylate)s possessing α,β-unsaturated esters at the ω-ends. The subsequent thiol-ene click reaction resulted in a quantitative end-functionalization. The terminating reaction is also useful to evaluate reactivity of monomers and stereospecificity of propagating species in the presence of some additives.
資源タイプ(コンテンツの種類)
内容記述タイプ Other
内容記述 Article
ISSN
収録物識別子タイプ ISSN
収録物識別子 0029-022X
書誌レコードID
収録物識別子タイプ NCID
収録物識別子 AN00189720
他の資源との関係:URI
関連識別子
識別子タイプ URI
関連識別子 https://www.jstage.jst.go.jp/browse/gomu/-char/ja
関連名称
関連名称 https://www.jstage.jst.go.jp/browse/gomu/-char/ja
DOI
関連識別子
識別子タイプ DOI
関連識別子 https://doi.org/10.2324/gomu.88.80
関連名称
関連名称 10.2324/gomu.88.80
出版タイプ
出版タイプ VoR
出版タイプResource http://purl.org/coar/version/c_970fb48d4fbd8a85
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