{"_buckets": {"deposit": "2b064bfd-1476-4a75-99c1-f64c572c26c3"}, "_deposit": {"id": "19897", "owners": [], "pid": {"revision_id": 0, "type": "depid", "value": "19897"}, "status": "published"}, "_oai": {"id": "oai:soar-ir.repo.nii.ac.jp:00019897", "sets": ["1169:1170"]}, "author_link": ["105821", "105822", "105823", "105824", "105825", "105826", "105827", "105828"], "item_1628147817048": {"attribute_name": "\u51fa\u7248\u30bf\u30a4\u30d7", "attribute_value_mlt": [{"subitem_version_resource": "http://purl.org/coar/version/c_970fb48d4fbd8a85", "subitem_version_type": "VoR"}]}, "item_6_biblio_info_6": {"attribute_name": "\u66f8\u8a8c\u60c5\u5831", "attribute_value_mlt": [{"bibliographicIssueDates": {"bibliographicIssueDate": "2017", "bibliographicIssueDateType": "Issued"}, "bibliographicIssueNumber": "1", "bibliographicPageEnd": "369", "bibliographicPageStart": "353", "bibliographicVolumeNumber": "95", "bibliographic_titles": [{"bibliographic_title": "HETEROCYCLES"}]}]}, "item_6_description_20": {"attribute_name": "\u6284\u9332", "attribute_value_mlt": [{"subitem_description": "Azulene-substituted tetracyanobutadienes (AzTCBDs) and dicyanoquinodimethanes (AzDCNQs) connected with naphthalene cores were prepared by the reaction of 1-azulenylalkynes with tetracyanoethylene (TCNE) and 7,7,8,8-tetracyanoquinodimethane (TCNQ) in a formal [2 + 2] cycloaddition-retroelectrocyclization. The characteristic intramolecular charge transfer (ICT) characters were investigated by using UV/Vis spectroscopy and theoretical calculation. The redox behaviors of AzTCBDs and AzDCNQs were examined by cyclic voltammetry and differential pulse voltammetry, which revealed their properties of multi-electron transfer depending on the number of AzTCBD and AzDCNQ moieties. Moreover, significant color changes were observed by visible spectroscopy under the electrochemical reduction conditions.", "subitem_description_type": "Abstract"}]}, "item_6_description_30": {"attribute_name": "\u8cc7\u6e90\u30bf\u30a4\u30d7\uff08\u30b3\u30f3\u30c6\u30f3\u30c4\u306e\u7a2e\u985e\uff09", "attribute_value_mlt": [{"subitem_description": "Article", "subitem_description_type": "Other"}]}, "item_6_description_5": {"attribute_name": "\u5f15\u7528", "attribute_value_mlt": [{"subitem_description": "HETEROCYCLES. 95(1):353-369 (2017)", "subitem_description_type": "Other"}]}, "item_6_link_3": {"attribute_name": "\u4fe1\u5dde\u5927\u5b66\u7814\u7a76\u8005\u7dcf\u89a7\u3078\u306e\u30ea\u30f3\u30af", "attribute_value_mlt": [{"subitem_link_text": "Shoji, Taku", "subitem_link_url": "http://soar-rd.shinshu-u.ac.jp/profile/ja.gmShOakh.html"}]}, "item_6_link_67": {"attribute_name": "WoS", "attribute_value_mlt": [{"subitem_link_text": "Web of Science", "subitem_link_url": "http://gateway.isiknowledge.com/gateway/Gateway.cgi?\u0026GWVersion=2\u0026SrcAuth=ShinshuUniv\u0026SrcApp=ShinshuUniv\u0026DestLinkType=FullRecord\u0026DestApp=WOS\u0026KeyUT=000405885400029"}]}, "item_6_publisher_4": {"attribute_name": "\u51fa\u7248\u8005", "attribute_value_mlt": [{"subitem_publisher": "PERGAMON-ELSEVIER SCIENCE LTD"}]}, "item_6_relation_48": {"attribute_name": "DOI", "attribute_value_mlt": [{"subitem_relation_name": [{"subitem_relation_name_text": "10.3987/COM-16-S(S)25"}], "subitem_relation_type_id": {"subitem_relation_type_id_text": "https://doi.org/10.3987/COM-16-S(S)25", "subitem_relation_type_select": "DOI"}}]}, "item_6_rights_62": {"attribute_name": "\u6a29\u5229", "attribute_value_mlt": [{"subitem_rights": "\u00a9 2017 The Japan Institute of Heterocyclic Chemistry"}]}, "item_6_select_64": {"attribute_name": "\u8457\u8005\u7248\u30d5\u30e9\u30b0", "attribute_value_mlt": [{"subitem_select_item": "publisher"}]}, "item_6_source_id_35": {"attribute_name": "ISSN", "attribute_value_mlt": [{"subitem_source_identifier": "0385-5414", "subitem_source_identifier_type": "ISSN"}]}, "item_6_source_id_39": {"attribute_name": "NII ISSN", "attribute_value_mlt": [{"subitem_source_identifier": "0385-5414", "subitem_source_identifier_type": "ISSN"}]}, "item_6_source_id_40": {"attribute_name": "\u66f8\u8a8c\u30ec\u30b3\u30fc\u30c9ID", "attribute_value_mlt": [{"subitem_source_identifier": "AA00663739", "subitem_source_identifier_type": "NCID"}]}, "item_6_text_69": {"attribute_name": "wosonly authkey", "attribute_value_mlt": [{"subitem_text_value": "Azulene; Naphthalene; 2H-Cyclohepta[b]furan-2-one; Cycloaddition Reaction; Electrochemisty"}]}, "item_6_text_70": {"attribute_name": "wosonly keywords", "attribute_value_mlt": [{"subitem_text_value": "CHARGE-TRANSFER INTERACTIONS; PUSH-PULL CHROMOPHORES; 2+2 CYCLOADDITION-RETROELECTROCYCLIZATION; VIOLENE/CYANINE HYBRIDS; REDOX BEHAVIOR; ELECTROCHROMIC SYSTEMS; ELECTRON-ACCEPTORS; GENERAL STRUCTURE; TETRACYANOETHYLENE; BENZENE"}]}, "item_6_textarea_68": {"attribute_name": "wosonly abstract", "attribute_value_mlt": [{"subitem_textarea_value": "Azulene-substituted tetracyanobutadienes (AzTCBDs) and dicyanoquinodimethanes (AzDCNQs) connected with naphthalene cores were prepared by the reaction of 1-azulenylalkynes with tetracyanoethylene (TCNE) and 7,7,8,8-tetracyanoquinodimethane (TCNQ) in a formal [2 + 2] cycloaddition-retroelectrocyclization. The characteristic intramolecular charge transfer (ICT) characters were investigated by using UV/Vis spectroscopy and theoretical calculation. The redox behaviors of AzTCBDs and AzDCNQs were examined by cyclic voltammetry and differential pulse voltammetry, which revealed their properties of multi-electron transfer depending on the number of AzTCBD and AzDCNQ moieties. Moreover, significant color changes were observed by visible spectroscopy under the electrochemical reduction conditions."}]}, "item_creator": {"attribute_name": "\u8457\u8005", "attribute_type": "creator", "attribute_value_mlt": [{"creatorNames": [{"creatorName": "Shoji, Taku"}], "nameIdentifiers": [{"nameIdentifier": "105821", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Maruyama, Mitsuhisa"}], "nameIdentifiers": [{"nameIdentifier": "105822", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Maruyama, Akifumi"}], "nameIdentifiers": [{"nameIdentifier": "105823", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Nagai, Daichi"}], "nameIdentifiers": [{"nameIdentifier": "105824", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Tanaka, Miwa"}], "nameIdentifiers": [{"nameIdentifier": "105825", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Sekiguchi, Ryuta"}], "nameIdentifiers": [{"nameIdentifier": "105826", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Ito, Shunji"}], "nameIdentifiers": [{"nameIdentifier": "105827", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Okujima, Tetsuo"}], "nameIdentifiers": [{"nameIdentifier": "105828", "nameIdentifierScheme": "WEKO"}]}]}, "item_files": {"attribute_name": "\u30d5\u30a1\u30a4\u30eb\u60c5\u5831", "attribute_type": "file", "attribute_value_mlt": [{"accessrole": "open_date", "date": [{"dateType": "Available", "dateValue": "2018-06-13"}], "displaytype": "detail", "download_preview_message": "", "file_order": 0, "filename": "HETEROCYCLES_95_353-369.pdf", "filesize": [{"value": "1.6 MB"}], "format": "application/pdf", "future_date_message": "", "is_thumbnail": false, "licensefree": "\u00a9 2017 The Japan Institute of Heterocyclic Chemistry", "licensetype": "license_note", "mimetype": "application/pdf", "size": 1600000.0, "url": {"label": "HETEROCYCLES_95_353-369.pdf", "url": "https://soar-ir.repo.nii.ac.jp/record/19897/files/HETEROCYCLES_95_353-369.pdf"}, "version_id": "040a4992-2f2f-4026-b3ad-e65000914cee"}]}, "item_keyword": {"attribute_name": "\u30ad\u30fc\u30ef\u30fc\u30c9", "attribute_value_mlt": [{"subitem_subject": "Azulene", "subitem_subject_scheme": "Other"}, {"subitem_subject": "Naphthalene", "subitem_subject_scheme": "Other"}, {"subitem_subject": "2H-Cyclohepta[b]furan-2-one", "subitem_subject_scheme": "Other"}, {"subitem_subject": "Cycloaddition Reaction", "subitem_subject_scheme": "Other"}, {"subitem_subject": "Electrochemisty", "subitem_subject_scheme": "Other"}]}, "item_language": {"attribute_name": "\u8a00\u8a9e", "attribute_value_mlt": [{"subitem_language": "eng"}]}, "item_resource_type": {"attribute_name": "\u8cc7\u6e90\u30bf\u30a4\u30d7", "attribute_value_mlt": [{"resourcetype": "journal article", "resourceuri": "http://purl.org/coar/resource_type/c_6501"}]}, "item_title": "Synthesis and Electrochemical Properties of Azulene-Substituted Tetracyanobutadiene and Dicyanoquinodimethane Chromophores Connected with Naphthalene Cores", "item_titles": {"attribute_name": "\u30bf\u30a4\u30c8\u30eb", "attribute_value_mlt": [{"subitem_title": "Synthesis and Electrochemical Properties of Azulene-Substituted Tetracyanobutadiene and Dicyanoquinodimethane Chromophores Connected with Naphthalene Cores", "subitem_title_language": "en"}]}, "item_type_id": "6", "owner": "1", "path": ["1169/1170"], "permalink_uri": "http://hdl.handle.net/10091/00020658", "pubdate": {"attribute_name": "PubDate", "attribute_value": "2018-06-13"}, "publish_date": "2018-06-13", "publish_status": "0", "recid": "19897", "relation": {}, "relation_version_is_last": true, "title": ["Synthesis and Electrochemical Properties of Azulene-Substituted Tetracyanobutadiene and Dicyanoquinodimethane Chromophores Connected with Naphthalene Cores"], "weko_shared_id": -1}