Item type |
学術雑誌論文 / Journal Article(1) |
公開日 |
2018-06-13 |
タイトル |
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タイトル |
Synthesis and Electrochemical Properties of Azulene-Substituted Tetracyanobutadiene and Dicyanoquinodimethane Chromophores Connected with Naphthalene Cores |
言語 |
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言語 |
eng |
DOI |
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関連識別子 |
https://doi.org/10.3987/COM-16-S(S)25 |
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関連名称 |
10.3987/COM-16-S(S)25 |
キーワード |
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主題 |
Azulene, Naphthalene, 2H-Cyclohepta[b]furan-2-one, Cycloaddition Reaction, Electrochemisty |
資源タイプ |
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資源 |
http://purl.org/coar/resource_type/c_6501 |
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タイプ |
journal article |
著者 |
Shoji, Taku
Maruyama, Mitsuhisa
Maruyama, Akifumi
Nagai, Daichi
Tanaka, Miwa
Sekiguchi, Ryuta
Ito, Shunji
Okujima, Tetsuo
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信州大学研究者総覧へのリンク |
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氏名 |
Shoji, Taku |
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URL |
http://soar-rd.shinshu-u.ac.jp/profile/ja.gmShOakh.html |
出版者 |
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出版者 |
PERGAMON-ELSEVIER SCIENCE LTD |
引用 |
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内容記述 |
HETEROCYCLES. 95(1):353-369 (2017) |
書誌情報 |
HETEROCYCLES
巻 95,
号 1,
p. 353-369,
発行日 2017
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抄録 |
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内容記述 |
Azulene-substituted tetracyanobutadienes (AzTCBDs) and dicyanoquinodimethanes (AzDCNQs) connected with naphthalene cores were prepared by the reaction of 1-azulenylalkynes with tetracyanoethylene (TCNE) and 7,7,8,8-tetracyanoquinodimethane (TCNQ) in a formal [2 + 2] cycloaddition-retroelectrocyclization. The characteristic intramolecular charge transfer (ICT) characters were investigated by using UV/Vis spectroscopy and theoretical calculation. The redox behaviors of AzTCBDs and AzDCNQs were examined by cyclic voltammetry and differential pulse voltammetry, which revealed their properties of multi-electron transfer depending on the number of AzTCBD and AzDCNQ moieties. Moreover, significant color changes were observed by visible spectroscopy under the electrochemical reduction conditions. |
資源タイプ(コンテンツの種類) |
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内容記述 |
Article |
ISSN |
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収録物識別子タイプ |
ISSN |
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収録物識別子 |
0385-5414 |
書誌レコードID |
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収録物識別子タイプ |
NCID |
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収録物識別子 |
AA00663739 |
権利 |
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権利情報 |
© 2017 The Japan Institute of Heterocyclic Chemistry |
出版タイプ |
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出版タイプ |
VoR |
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出版タイプResource |
http://purl.org/coar/version/c_970fb48d4fbd8a85 |
WoS |
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URL |
http://gateway.isiknowledge.com/gateway/Gateway.cgi?&GWVersion=2&SrcAuth=ShinshuUniv&SrcApp=ShinshuUniv&DestLinkType=FullRecord&DestApp=WOS&KeyUT=000405885400029 |